China Geological Survey

Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences, 2003.

This volume, "The Geology of the Arabian Peninsula," is a logical consequence of the geographic and geologic mapping project of the Arabian Peninsula, a cooperative venture between the Kingdom of Saudi Arabia and the Government of the United States. The Arabian-American Oil Co. and the U.S. Geological Survey did the fieldwork within the Kingdom of Saudi Arabia, and, with the approval of the governments of neighboring countries, a number of other oil companies contributed additional mapping to complete the coverage of the whole of the Arabian Peninsula. So far as we are aware, this is a unique experiment in geological cooperation among several governments, petroleum companies, and individuals.

Clayey silt reservoirs bearing natural gas hydrates (NGH) are considered to be the hydrate-bearing reservoirs that boast the highest reserves but tend to be the most difficult to exploit. They are proved to be exploitable by the first NGH production test conducted in the South China Sea in 2017. Based on the understanding of the first production test, the China Geological Survey determined the optimal target NGH reservoirs for production test and conducted a detailed assessment, numerical and experimental simulation, and onshore testing of the reservoirs. After that, it conducted the second offshore NGH production test in 1225 m deep Shenhu Area, South China Sea (also referred to as the second production test) from October 2019 to April 2020. During the second production test, a series of technical challenges of drilling horizontal wells in shallow soft strata in deep sea were met, including wellhead stability, directional drilling of a horizontal well, reservoir stimulation and sand control, and accurate depressurization. As a result, 30 days of continuous gas production was achieved, with a cumulative gas production of 86.14 ×10⁴ m³. Thus, the average daily gas production is 2.87 ×10⁴ m³, which is 5.57 times as much as that obtained in the first production test. Therefore, both the cumulative gas production and the daily gas production were highly improved compared to the first production test. As indicated by the monitoring results of the second production test, there was no anomaly in methane content in the seafloor, seawater, and atmosphere throughout the whole production test. This successful production test further indicates that safe and effective NGH exploitation is feasible in clayey silt NGH reservoirs. The industrialization of hydrates consists of five stages in general, namely theoretical research and simulation experiments, exploratory production test, experimental production test, productive production test, and commercial production. The second production test serves as an important step from the exploratory production test to experimental production test.

© 2015 Society of Economic Geologists, Inc. Magmatic-hydrothermal ore deposits in collisional orogens are new targets for modern mineral exploration, yet it is unclear why they preferentially occur in some specific tectonic environments within these orogenic belts. We integrate geologic and geochemical data (especially zircon U-Pb dating and Lu-Hf isotope data) for Mesozoic-Cenozoic magmatic rocks and associated ore deposits in the Lhasa terrane, a highly endowed tectonic unit within the Himalayan-Tibetan orogen, and provide the first example in a continental collision terrane of the application of zircon Hf isotope data to image the lithospheric architecture and its relationship with ore deposits. Three crustal blocks are identified within the Lhasa terrane by the Hf isotope mapping method. They include a central long-lived Precambrian microcontinent with local reworking and two surrounding juvenile Phanerozoic crustal blocks with significant mantle contributions to constituent magmatic rocks. The three crustal blocks are bounded by two E-W-trending terrane-boundary faults, and each block is cut by two N-S-striking concealed faults. Isotopic signatures of zircons from the juvenile crustal blocks indicate that the Phanerozoic continental crust grew from several Mesozoic volcanic-plutonic arcs and by underplating of mantle-derived magmas generated during Mesozoic accretion and Cenozoic collision. Mesozoic subduction-related porphyry Cu-Au deposits and Cenozoic collision-related Cu-Mo deposits are exclusively located in regions with high εHf (>5) juvenile crust. Cu enrichment during differentiation of high fO2 arc magmas is the key for the formation of Mesozoic subduction-related porphyry Cu-Au. By contrast, remelting of the lower crustal Cu sulfide-rich magmatic cumulates within the juvenile crust is interpreted to have played a key role in the formation of Cenozoic collision-related Cu-Mo deposits. Granite-related Pb-Zn deposits cluster in the oldest crustal regions or developed along the margin of the old crustal block bounded by lithospheric faults. The porphyry Mo deposits are localized along the reworked margins of the old crustal block. It is suggested that crustal reworking released Mo from the old crust to form porphyry Mo deposits, whereas leaching of Pb and Zn from the Paleozoic carbonate cover strata by felsic intrusion-driven fluids is critical to the formation of Pb-Zn ore deposits. Skarn Fe-Cu ore deposits are typically localized along a terrane boundary fault, i.e., lithospheric discontinuity, through which crust-derived felsic melt mixed with Cu-rich mantle-derived mafic magmas ascending upward. Associated granitoid rocks usually bear microgranular mafic enclaves and show a zircon Hf isotope array from negative to positive εHf values (-7.3 to +6.7), supporting mixing of juvenile mantle and evolved crustal sources. The Hf isotope maps show temporal-spatial relationships between crustal structure and the location of ore deposits, demonstrating that the structure, nature, and composition of the crust controlled the localization of ore deposits and the migration of ore-forming metals in the terrane. This study shows that the lithospheric architecture of an orogenic terrane can be imaged by Hf isotope mapping to provide mappable units which can be used to explore for ore deposits at the terrane scale.

Plants respond to environmental pollutants such as heavy metal(s) by triggering the expression of genes that encode proteins involved in stress response. Toxic metal ions profoundly affect the cellular protein homeostasis by interfering with the folding process and aggregation of nascent or non-native proteins leading to decreased cell viability. However, plants possess a range of ubiquitous cellular surveillance systems that enable them to efficiently detoxify heavy metals toward enhanced tolerance to metal stress. As proteins constitute the major workhorses of living cells, the chelation of metal ions in cytosol with phytochelatins and metallothioneins followed by compartmentalization of metals in the vacuoles as well as the repair of stress-damaged proteins or removal and degradation of proteins that fail to achieve their native conformations are critical for plant tolerance to heavy metal stress. In this review, we provide a broad overview of recent advances in cellular protein research with regards to heavy metal tolerance in plants. We also discuss how plants maintain functional and healthy proteomes for survival under such capricious surroundings.

2D carbides and nitrides of transition metals, also known as MXenes, are an emerging class of 2D nanomaterials that have shown excellent performances and broad application prospects in the fields of energy storage, catalysis, sensing, electromagnetic shielding, electronics and photonics, and life sciences. This unusual diversity of applications is due to their superior hydrophilicity and conductivity, high carrier concentration, ultra-high volumetric capacitance, rich surface chemistry, and large specific surface area. However, it is difficult to make MXenes with the desired surface functional groups that deliver high reactivity and high stability, because most MXenes are extracted from ceramics (MAX phase) by an etching process, where a large number of metal atoms are inevitably exposed on the surface, with other anions and cations embedded uncontrollably. The exposed metal atoms and implanted ions are thermodynamically unstable and readily react with trace oxygen or oxygen-containing groups to form the corresponding metal oxides or degrade chemically, resulting in a sharp decline in activity and loss of excellent physicochemical properties. The addition of certain synergistic additives during the intercalation and chemical modification of surface functional groups under non-hazardous conditions can result in stable and efficient MXene-based materials with exceptional optical, electrical, and magnetic properties. This review discusses several such methods, mainly additive-mediated intercalation and chemical modification of the surface functional groups of MXene-based materials, followed by their potential applications. Finally, perspectives are given to discuss the future challenges and promising opportunities of this exciting field.

A 2650‐year (BC665‐AD1985) warm season (MJJA: May, June, July, August) temperature reconstruction is derived from a correlation between thickness variations in annual layers of a stalagmite from Shihua Cave, Beijing, China and instrumental meteorological records. Observations of soil CO 2 and drip water suggest that the temperature signal is amplified by the soil‐organism‐CO 2 system and recorded by the annual layer series. Our reconstruction reveals that centennial‐scale rapid warming occurred repeatedly following multicentenial cooling trends during the last millennia. These results correlate with different records from the Northern Hemisphere, indicating that the periodic alternation between cool and warm periods on a sub‐millennial scale had a sub‐hemispherical influence.

In recent years, increasing attention has been given to the potential supply risks of critical battery materials, such as cobalt, for electric mobility transitions. While battery technology and recycling advancement are two widely acknowledged strategies for addressing such supply risks, the extent to which they will relieve global and regional cobalt demand-supply imbalance remains poorly understood. Here, we address this gap by simulating historical (1998-2019) and future (2020-2050) global cobalt cycles covering both traditional and emerging end uses with regional resolution (China, the U.S., Japan, the EU, and the rest of the world). We show that cobalt-free batteries and recycling progress can indeed significantly alleviate long-term cobalt supply risks. However, the cobalt supply shortage appears inevitable in the short- to medium-term (during 2028-2033), even under the most technologically optimistic scenario. Our results reveal varying cobalt supply security levels by region and indicate the urgency of boosting primary cobalt supply to ensure global e-mobility ambitions.

Abstract The Jiaodong gold province, the largest gold producer in China, formed in a setting dominated by a 30-m.y. episode of Izanagi plate rollback and widespread extension, concomitant with late Mesozoic craton destruction. This study presents new high precision in situ sensitive high-resolution ion microprobe (SHRIMP) U-Th-Pb and laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) U-Pb ages for hydrothermal monazite from the largest of the Jiaodong gold deposits, which were previously dated as indicating ore formation over a few tens of millions of years when applying sericite Ar-Ar, zircon U-Pb, and less robust analytical techniques. Our U-Pb dating on monazite from the Jiaojia and Linglong deposits in western Jiaodong yielded consistent ages at ca. 120 Ma. The new geochronologic results, coupled with recently reported in situ monazite dates from smaller deposits in western Jiaodong, reveal that the deposits that host most of the ≥4,000-t Au resource formed during a relatively brief period at ca. 120 Ma. In eastern Jiaodong, the much smaller resource may have formed about 5 m.y. later, recorded by 114.2 ± 1.5 Ma gold mineralization at the Rushan deposit. The postsubduction opening of a slab gap at ca. 120 Ma is the most likely cause of the extensive gold mineralization in Jiaodong. The gap induced a local and rapid devolatilization of the hydrated mantle wedge at submelt temperatures. The transient event included release of a major volume of gold-transporting aqueous-carbonic fluid that was stored in the wedge into major NNE-trending structures in the overlying lithosphere.

The Three Gorges region in China was basically a geohazard-prone area prior to construction of the Three Gorges Reservoir (TGR). After construction of the TGR, the water level was raised from 70 m to 175 m above sea level (ASL), and annual reservoir regulation has caused a 30-m water level difference after impoundment of the TGR since September 2008. This paper first presents the spatiotemporal distribution of landslides in six periods of 175 m ASL trial impoundments from 2008 to 2014. The results show that the number of landslides sharply decreased from 273 at the initial stage to less than ten at the second stage of impoundment. Based on this, the reservoir-induced landslides in the TGR region can be roughly classified into five failure patterns, i.e. accumulation landslide, dip-slope landslide, reversed bedding landslide, rockfall, and karst breccia landslide. The accumulation landslides and dip-slope landslides account for more than 90%. Taking the Shuping accumulation landslide (a sliding mass volume of 20.7 × 106 m3) in Zigui County and the Outang dip-slope landslide (a sliding mass volume of about 90 × 106 m3) in Fengjie County as two typical cases, the mechanisms of reactivation of the two landslides are analyzed. The monitoring data and factor of safety (FOS) calculation show that the accumulation landslide is dominated by water level variation in the reservoir as most part of the mass body is under 175 m ASL, and the dip-slope landslide is controlled by the coupling effect of reservoir water level variation and precipitation as an extensive recharge area of rainfall from the rear and the front mass is below 175 m ASL. The characteristics of landslide-induced impulsive wave hazards after and before reservoir impoundment are studied, and the probability of occurrence of a landslide-induced impulsive wave hazard has increased in the reservoir region. Simulation results of the Ganjingzi landslide in Wushan County indicate the strong relationship between landslide-induced surge and water variation with high potential risk to shipping and residential areas. Regarding reservoir regulation in TGR when using a single index, i.e. 1-d water level variation, water resources are not well utilized, and there is also potential risk of disasters since 2008. In addition, various indices such as 1-d, 5-d, and 10-d water level variations are proposed for reservoir regulation. Finally, taking reservoir-induced landslides in June 2015 for example, the feasibility of the optimizing indices of water level variations is verified.

The purpose of this article was to quantitatively investigate the pore structure and fractal characteristics of different lithofacies in the upper Permian Dalong Formation marine shale. Shale samples in this study were collected from well GD1 in the Lower Yangtze region for mineral composition, X-ray diffraction (XRD), and nitrogen adsorption–desorption analysis, as well as broad-ion beam scanning electron microscopy (BIB-SEM) observation. Experimental results showed that the TOC (total organic carbon) content and vitrinite reflectance (Ro) of the investigated shale samples were in the ranges 1.18–6.45% and 1.15–1.29%, respectively, showing that the Dalong Formation shale was in the mature stage. XRD results showed that the Dalong Formation shale was dominated by quartz ranging from 38.4% to 54.3%, followed by clay minerals in the range 31.7–37.5%, along with carbonate minerals (calcite and dolomite), with an average value of 9.6%. Based on the mineral compositions of the studied samples, the Dalong Formation shale can be divided into two types of lithofacies, namely siliceous shale facies and clay–siliceous mixed shale facies. In siliceous shale facies, which were mainly composed of organic pores, the surface area (SA) and pore volume (PV) were in the range of 5.20–10.91 m2/g and 0.035–0.046 cm3/g, respectively. Meanwhile, the pore size distribution (PSD) and fractal dimensions were in the range 14.2–26.1 nm and 2.511–2.609, respectively. I/S (illite-smectite mixed clay) was positively correlated with SA, PV, and fractal dimensions, while illite had a negative relationship with SA, PV, and fractal dimensions. I/S had a strong catalytic effect on organic matter for hydrocarbon generation, which was beneficial to the development of organic micropores, so I/S was conducive to pore structure complexity and the increase in SA and PV, while illite easily filled organic pores, which was not beneficial to the improvement of pore space. In clay–siliceous mixed shale facies, which mainly develop inorganic pores such as intergranular pores, SA and PV were in the range of 6.71–11.38 m2/g and 0.030–0.041 cm3/g, respectively. Meanwhile, PSD and fractal dimensions were in the range of 14.3–18.9 nm and 2.563–2.619, respectively. Quartz and I/S showed weak positive correlations with SA, PV, and fractal dimensions. The various compact modes between quartz particles and the disorder of I/S were conducive to the complexity of pore structure and the improvement of SA and PV. The research findings can provide a reference for the optimization and evaluation of shale gas favorable area of the Lower Yangtze Platform.

Melatonin regulates broad aspects of plant responses to various biotic and abiotic stresses, but the upstream regulation of melatonin biosynthesis by these stresses remains largely unknown. Herein, we demonstrate that transcription factor heat-shock factor A1a (HsfA1a) conferred cadmium (Cd) tolerance to tomato plants, in part through its positive role in inducing melatonin biosynthesis under Cd stress. Analysis of leaf phenotype, chlorophyll content, and photosynthetic efficiency revealed that silencing of the HsfA1a gene decreased Cd tolerance, whereas its overexpression enhanced plant tolerance to Cd. HsfA1a-silenced plants exhibited reduced melatonin levels, and HsfA1a overexpression stimulated melatonin accumulation and the expression of the melatonin biosynthetic gene caffeic acid O-methyltransferase 1 (COMT1) under Cd stress. Both an in vitro electrophoretic mobility shift assay and in vivo chromatin immunoprecipitation coupled with qPCR analysis revealed that HsfA1a binds to the COMT1 gene promoter. Meanwhile, Cd stress induced the expression of heat-shock proteins (HSPs), which was compromised in HsfA1a-silenced plants and more robustly induced in HsfA1a-overexpressing plants under Cd stress. COMT1 silencing reduced HsfA1a-induced Cd tolerance and melatonin accumulation in HsfA1a-overexpressing plants. Additionally, the HsfA1a-induced expression of HSPs was partially compromised in COMT1-silenced wild-type or HsfA1a-overexpressing plants under Cd stress. These results demonstrate that HsfA1a confers Cd tolerance by activating transcription of the COMT1 gene and inducing accumulation of melatonin that partially upregulates expression of HSPs.

Arsenicosis and fluorosis, two endemic diseases known to result from exposure to their elevated concentrations in groundwater of north China used by many rural households for drinking, have been major public health concerns for several decades. Over the last decade, a large number of investigations have been carried out to delineate the spatial distribution and to characterize the chemical compositions of high As and F groundwaters with a focus on several inland basins in north China. Findings from these studies, including improved understanding of the hydrogeological and geochemical factors resulting in their enrichments, have been applied to guide development of clean and safe groundwater in these endemic disease areas. Survey efforts have led to the recognition of iodine in groundwater as an emerging public health concern. This paper reviews the new understandings gained through these studies, including those published in this special issue, and points out the direction for future research that will shed light on safe guarding a long-term supply of low As and F groundwater in these water scarce semi-arid and arid inland basins of north China.

Both selenium (Se) and melatonin reduce cadmium (Cd) uptake and mitigate Cd toxicity in plants. However, the relationship between Se and melatonin in Cd detoxification remains unclear. In this study, we investigated the influence of three forms of Se (selenocysteine, sodium selenite, and sodium selenate) on the biosynthesis of melatonin and the tolerance against Cd in tomato plants. Pretreatment with different forms of Se significantly induced the biosynthesis of melatonin and its precursors (tryptophan, tryptamine, and serotonin); selenocysteine had the most marked effect on melatonin biosynthesis. Furthermore, Se and melatonin supplements significantly increased plant Cd tolerance as evidenced by decreased growth inhibition, photoinhibition, and electrolyte leakage (EL). Se-induced Cd tolerance was compromised in melatonin-deficient plants following tryptophan decarboxylase (TDC) gene silencing. Se treatment increased the levels of glutathione (GSH) and phytochelatins (PCs), as well as the expression of GSH and PC biosynthetic genes in nonsilenced plants, but the effects of Se were compromised in TDC-silenced plants under Cd stress. In addition, Se and melatonin supplements reduced Cd content in leaves of nonsilenced plants, but Se-induced reduction in Cd content was compromised in leaves of TDC-silenced plants. Taken together, our results indicate that melatonin is involved in Se-induced Cd tolerance via the regulation of Cd detoxification.

In this work, we present a methodology for improving persistent scatterer interferometry (PSI) data analysis for landslide studies. This methodology is a revision of previously described procedures with several improved and newly proposed aspects. To both evaluate and validate the results from this methodology, we used various persistent scatterer (PS) datasets from different satellites (ERS – ENVISAT, Radarsat, TerraSAR-X, and ALOS PALSAR) that were processed using three PSI techniques (stable point network – SPN, permanent scatterer interferometry – PSInSAR™, and SqueeSAR™) to map and monitor landslides in various mountainous environments in Spain and Italy. This methodology consists of a preprocessing model that predicts the presence of a PS over a certain area and a post-processing method used to determine the stability threshold, project the line of sight (LOS) velocity along the slope, estimate the E–W and vertical components of the velocity, and identify anomalous areas.

Due to their superior hydrophilicity and conductivity, ultra-high volumetric capacitance, and rich surface-chemistry properties, MXenes exhibit unique and excellent performance in catalysis, energy storage, electromagnetic shielding, and life sciences. Since they are derived from ceramics (MAX phase) through etching, one of the challenges in MXenes preparation is the inevitable exposure of metal atoms on their surface and embedding of anions and cations. Because the as-obtained MXenes are always in a thermodynamically metastable state, they tend to react with trace oxygen or oxygen-containing groups to form metal oxides or degrade, leading to sharply declined activity and impaired performance. Therefore, improving the stability of MXenes-based materials is of practical significance in relevant applications. Unfortunately, there lacks a comprehensive review in the literature on relevant topics. To help promote the wide applications of MXenes, we review from the following aspects: (i) insights into the factors affecting the stability of MXenes-based materials, including oxidation of MXenes flakes, stability of MXenes colloidal solutions, and swelling and degradation of MXenes thin-film, (ii) strategies for enhancing the stability of MXenes-based materials by optimizing MAX phase synthesis and modifying the MXenes preparation, and (iii) techniques for further increasing the stability of freshly prepared MXenes-based materials via controlling the storage conditions, and forming shielding on the surface and/or edge of MXenes flakes. Finally, some outlooks are proposed on the future developments and challenges of highly active and stable MXenes. We aim to provide guidance for the design, preparation, and applications of MXenes-based materials with excellent stability and activity.

This paper presents findings from an investigation of the large-scale construction solid waste (CSW) landslide that occurred at a landfill at Shenzhen, Guangdong, China, on December 20, 2015, and which killed 77 people and destroyed 33 houses. The landslide involved 2.73×106 m3 of CSW and affected an area about 1100 m in length and 630 m in maximum width, making it the largest landfill landslide in the world. The investigation of this disaster used a combination of unmanned aerial vehicle surveillance and multistage remote-sensing images to reveal the increasing volume of waste in the landfill and the shifting shape of the landfill slope for nearly two years before the landslide took place, beginning with the creation of the CSW landfill in March, 2014, that resulted in the uncertain conditions of the landfill's boundaries and the unstable state of the hydrologic performance. As a result, applying conventional stability analysis methods used for natural landslides to this case would be difficult. In order to analyze this disaster, we took a multistage modeling technique to analyze the varied characteristics of the landfill slope's structure at various stages of CSW dumping and used the non-steady flow theory to explain the groundwater seepage problem. The investigation showed that the landfill could be divided into two units based on the moisture in the land: a front uint, consisted of the landfill slope, which had low water content; and a rear unit, consisted of fresh waste, which had a high water content. This structure caused two effects—surface-water infiltration and consolidation seepage that triggered the landslide in the landfill. Surface-water infiltration induced a gradual increase in pore water pressure head, or piezometric head, in the front slope because the infiltrating position rose as the volume of waste placement increased. Consolidation seepage led to higher excess pore water pressures as the loading of waste increased. We also investigated the post-failure soil dynamics parameters of the landslide deposit using cone penetration, triaxial, and ring-shear tests in order to simulate the characteristics of a flowing slide with a long run-out due to the liquefaction effect. Finally, we conclude the paper with lessons from the tens of catastrophic landslides of municipal solid waste around the world and discuss how to better manage the geotechnical risks of urbanization.

This overview provides an up-to-date assessment of the trace metal contamination (As, Cd, Cr, Cu. Hg, Ni, Pb, Sb, Se, and Zn) in urban soils of 31 metropolises in China. This systematic soil geochemical survey summarizes the characteristics of trace metals in Chinese urban soils, including concentration, accumulation, spatial distribution, and major sources. Mercury was ranked first followed by Cd and Se in geo-accumulation among all of the contaminant metals in urban soils in China; this finding is likely due to the Hg and Se emissions from fossil fuels. However, the lack of studies on Se contamination in urban soils, not only in China but also in the rest of the world, implies that Se contamination may have been unobserved for a long time. Shanghai, Kunming, Shenyang, and Changsha may be some of the most heavily contaminated Chinese cities based on the concentrations, spatial dimensions, and associations among the contaminant metals. Numerous hotspots with high concentrations of metals were found in Changsha, Shanghai, and Shenyang, clearly indicating a significant contribution from both the metallurgical industry and smelt mining to the contamination of urban soils. Conversely, the levels of Sb, Cu, and Cd in Kunming originated from their naturally high geochemical background in soils. Heavy Se contamination was found in Guiyang and Taiyuan. The natural source of Se may be important in defining the pattern of pollution in Guiyang, whereas anthropogenic sources are likely more accurate than is the natural background in Taiyuan city. We review the existing limits and types of pollutants in the current soil guidelines and find that an international agreement on the range of the limits and the types of pollutants contained in the soil guidelines is urgently needed.

Deep-sea sediments contain high concentrations of rare earth element (REE) which have been regarded as a huge potential resource. Understanding the marine REE cycle is important to reveal the mechanism of REE enrichment. In order to determine the geochemistry characteristics and migration processes of REE, seawater, porewater and sediment samples were systematically collected from the western Pacific for REE analysis. The results show a relatively flat REE pattern and the HREE (Heavy REE) enrichment in surface and deep seawater respectively. The HREE enrichment distribution patterns, low concentrations of Mn and Fe and negative Ce anomaly occur in the porewater, and high Mn/Al ratios and low U concentrations were observed in sediment, indicating oxic condition. LREE (Light REE) and MREE (Middle REE) enrichment in upper layer and depletion of MREE in deeper layer were shown in porewater profile. This study suggests that porewater flux in the western Pacific basin is a minor source of REEs to seawater, and abundant REEs are enriched in sediments, which is mainly caused by the extensive oxic condition, low sedimentation rate and strong adsorption capacity of sediments. Hence, the removal of REEs of porewater may result in widespread REE-rich sediments in the western Pacific basin.

The poorly studied Douling Complex is a crystalline basement that developed in the Neoproterozoic-Paleozoic weakly metamorphosed to non-metamorphosed strata at the South Qinling tectonic belt. Five banded dioritic-granitic gneiss samples from the Douling Complex were chosen for LA-MC-ICPMS U-Pb zircon dating, which yielded protolith emplacement ages of 2469 ± 22 Ma, 2479 ± 12 Ma, 2497 ± 21 Ma, 2501 ± 17 Ma and 2509 ± 14 Ma, respectively. An important peak age of ∼2.48 Ga was also obtained for a metasedimentary rock in the same region. These discoveries suggest the occurrence of magmatic activity of 2.51–2.47 Ga at the northern margin of the Yangtze craton. The age-corrected ɛ Hf(t) values obtained from in situ zircon Hf isotopic analysis are mainly between −5.5 and +0.3, and the two-stage zircon Hf model ages range from 3.30 to 2.95 Ga. Considering two important periods of ∼3.3–3.2 Ga and ∼2.95–2.90 Ga for the continental crustal growth in the Yangtze craton, we infer that the dioritic-granitic gneisses from the Douling Complex are the products of reworking of Paleo- to Mesoarchean crust at the northern margin of the Yangtze craton at ∼2.5 Ga. In addition, metamorphic ages of 837 ± 8 Ma and 818 ± 10 Ma were obtained for zircon overgrowth rims from a dioritic gneiss and a metasedimentary rock, indicating that the main phase amphibolite facies metamorphism of the Doulng Complex occurred during the Neoproterozoic, although its geological meaning remains ambiguous.