Coppin State University

Abstract The dyes extracted from pomegranate and berry fruits were successfully used in the fabrication of natural dye sensitized solar cells (NDSSC). The morphology, porosity, surface roughness, thickness, absorption and emission characteristics of the pomegranate dye sensitized photo-anode were studied using various analytical techniques including FESEM, EDS, TEM, AFM, FTIR, Raman, Fluorescence and Absorption Spectroscopy. Pomegranate dye extract has been shown to contain anthocyanin which is an excellent light harvesting pigment needed for the generation of charge carriers for the production of electricity. The solar cell’s photovoltic performance in terms of efficiency, voltage, and current was tested with a standard illumination of air-mass 1.5 global (AM 1.5 G) having an irradiance of 100 mW/cm 2 . After optimization of the photo-anode and counter electrode, a photoelectric conversion efficiency ( η ) of 2%, an open-circuit voltage ( Voc ) of 0.39 mV, and a short-circuit current density ( Isc ) of 12.2 mA/cm 2 were obtained. Impedance determination showed a relatively low charge-transfer resistance (17.44 Ω) and a long lifetime, signifying a reduction in recombination losses. The relatively enhanced efficiency is attributable in part to the use of a highly concentrated pomegranate dye, graphite counter electrode and TiCl 4 treatment of the photo-anode.

Personality researchers have recently converged on the five-factor model as an adequate representation of the structure of personality traits. This article introduces the factors and the NEO Personality Inventory (NEO-PI), a questionnaire designed to measure the factors and some of the traits that define them. Data on the comprehensiveness of the model and on the reliability, validity, and stability of measures of the factors are reviewed, and correlations between scales from the NEO-PI and two instruments widely used in clinical practice (the Minnesota Multiphasic Personality Inventory [MMPI] and the Millon Clinical Multiaxial Inventory [MCMI]) are used to illustrate similarities and differences between normal and clinical assessment. Some issues regarding the clinical use of the five-factor model are discussed.

Threats emerging from microplastic pollution in the marine environment have received much global attention. This review assessed sources, fate, and impacts of microplastics in marine ecosystems and identified gaps. Most studies document the ubiquity of microplastics and associated environmental effects. Effects include impacts to marine ecosystems, risks to biodiversity, and threats to human health. Microplastic leakage into marine ecosystems arises from plastic waste mismanagement and a lack of effective mitigative strategies. This review identified a scarcity of microplastics’ mitigation strategies from different stakeholders. Lack of community involvement in microplastic monitoring or ecosystem conservation exists due to limited existence of citizen science and stakeholder co-management initiatives. Although some management strategies exist for controlling effects of microplastics (often implemented by local and global environmental groups), a standardized management strategy to mitigate microplastics in coastal areas is urgently required. There is a need to review policy interventions aimed at plastic reduction in or near coastal ecosystems and evaluate their effectiveness. There is also a need to identify focal causes of microplastic pollution in the marine environment through further environmental research and governance approaches. These would extend to creating more effective policies as well as harmonized and extended efforts of educational campaigns and incentives for plastic waste reduction while mandating stringent penalties to help reduce microplastic leakage into the marine environment.

The sixth generation (6G) is envisioned to be a spawned key technology that will support the ubiquitous and seamless connection of a massive number of Internet-of-Things (IoT) devices. The extremely high data rate, low end-to-end delay, high mobility of IoT devices propel the desideratum of extenuating the concern of reducing the energy consumption, i.e., green communication. Hence, in this article, we address the concern of green communication in 6G-enabled massive IoT devices by following the cluster-based data dissemination in the network. We propose a novel hybrid whale spotted hyena optimization (HWSHO) algorithm by synthesizing the whale optimizer algorithm (WOA) with exploitation capabilities of spotted hyena optimizer (SHO). We perform a simulation experimental study that shows the supreme performance of our proposed technique over the most recent proposed energy-efficient data dissemination methods. The proposed technique is an exemplary solution that could be pertinent to various hostile applications seeking green communication of 6G-enabled IoT devices.

BACKGROUND: National data do not account for race differences in health risks resulting from racial segregation or the correlation between race and socioeconomic status. Therefore, these data may inaccurately attribute differences in obesity to race rather than differing social context. The goal of this study was to investigate whether race disparities in obesity among women persist in a community of black people and white people living in the same social context with similar income. METHODS: Race disparities in obesity were examined among black women and white women living in the same social context with similar income, using the data from the Exploring Health Disparities in Integrated Communities-SWB (EHDIC-SWB) study, and these estimates were compared to national data (National Health Interview Survey) to determine if race disparities in obesity were attenuated among women in EHDIC-SWB. Obesity was based on participants' self-reported height and weight. Logistic regression was used to examine the association between race and obesity. RESULTS: In the national sample, black women exhibited greater odds of being obese (OR 1.99, 95% CI 1.71 to 2.32) than white women after controlling for covariates. In the EHDIC-SWB sample, black women had similar odds of being obese (OR 1.25, 95% CI 0.90 to 1.75) as compared to white women, after adjusting for covariates. CONCLUSIONS: There are no race disparities in obesity among poor, urban women sharing the same social context. Developing policies that focus on modifying social aspects of the environment may reduce disparities in obesity among low-income women living in urban communities.

Abstract Medical tourism is the act of travelling abroad for health care. The theory of planned behaviour was used to investigate the medical tourism beliefs of 336 undergraduate students in a basic psychology course at a large midwestern American university. Students did not have positive intentions for mere willingness to seek more information about travelling to a developing country to receive medical treatment. An educational intervention is necessary to help promote travel for medical treatment. The intervention may include educating people on the availability of quality health care, highly trained competent doctors and the ability to vacation and see another country. Copyright © 2010 John Wiley & Sons, Ltd.

Two patients who had hemolysis after receiving large doses of intravenous immune serum globulin are reported. Both patients had positive direct antiglobulin tests due to alloantibodies contained in the immune serum globulin. Markedly increased red cell transfusion requirements and elevated serum bilirubin levels provided evidence of hemolysis.

This paper utilizes cointegration and the vector error‐correction model (VECM) to explore the causal relationship between economic growth and growth rate of domestic savings for Congo, Côte d’Ivoire, Ghana, Kenya, South Africa, and Zambia. Specifically, three analyses were undertaken. First, the time series properties of economic growth and domestic savings were ascertained with the help of the augmented Dickey–Fuller unit root procedure. Second, the long‐run relationship between economic growth and growth rate of domestic savings was examined in the context of the Johansen and Juselius (1990) framework. Finally, a Granger‐causality test was undertaken to determine the direction of causality between economic growth and growth rate of domestic savings. The results indicate one order of integration [I(1)] for each of the series. The results of the cointegration tests suggest that there is a long‐run relationship between economic growth and growth rate of savings. The results from the Granger‐causality tests indicate that contrary to the conventional wisdom, economic growth prima facie causes growth rate of domestic savings for most of the countries under consideration.

PURPOSE: Cataract is a significant cause of visual disability with relatively high incidence. It has been proposed that such high incidence is related to oxidative stress induced by continued intraocular penetration of light and consequent photochemical generation of reactive oxygen species, such as superoxide and singlet oxygen and their derivatization to other oxidants, such as hydrogen peroxide and hydroxyl radical. The latter two can also interact to generate singlet oxygen by Haber-Weiss reaction. It has been proposed that in addition to the endogenous enzymatic antioxidant enzymes, the process can be inhibited by many nutritional and metabolic oxyradical scavengers, such as ascorbate, vitamin E, pyruvate, and xanthine alkaloids, such as caffeine. METHODS: Initial verification of the hypothesis has been done primarily by rat and mouse lens organ culture studies under ambient as well as ultraviolet (UV) light irradiation and determining the effect of such irradiation on its physiology in terms of its efficiency of active membrane transport activity and the levels of certain metabolites such as glutathione and adenosine triphosphate as well as in terms of apoptotic cell death. In vivo studies on the possible prevention of oxidative stress and cataract formation have been conducted by administering pyruvate and caffeine orally in drinking water and by their topical application using diabetic and galactosemic animal models. RESULTS: Photosensitized damage to lens caused by exposure to visible light and UVA has been found to be significantly prevented by ascorbate and pyruvate. Caffeine has been found be effective against UVA and UVB. Oral or topical application of pyruvate has been found to inhibit the formation of cataracts induced by diabetes and galactosemia. Caffeine has also been found to inhibit cataract induced by sodium selenite and high levels of galactose. Studies with diabetes are in progress. CONCLUSIONS: Various in vitro and in vivo studies summarized in this review strongly support the hypothesis that light penetration into the eye is a significant contributory factor in the genesis of cataracts. The major effect is through photochemical generation of reactive oxygen species and consequent oxidative stress to the tissue. The results demonstrate that this can be averted by the use of various antioxidants administered preferably by topical route. That they will be so effective is strongly suggested by the effectiveness of pyruvate and caffeine administered topically to diabetic and galactosemic animals.

In this report, we discussed rapid, facile one-pot green synthesis of gold and silver nanoparticles (AuNPs and AgNPs) by using tuber extract of Amorphophallus paeoniifolius, and evaluated their antibacterial activity. AuNPs and AgNPs were synthesized by mixing their respective precursors (AgNO3 and HAuCl4) with tuber extract of Amorphophallus paeoniifolius as the bio-reducing agent. Characterization of AuNPs and AgNPs were confirmed by applying UV-vis spectroscopy, field-emission scanning electron microscopy (FESEM), X-ray diffraction (XRD) analysis, Fourier transform infrared spectroscopy (FTIR), and energy dispersive X-ray spectroscopy (EDS). From UV-vis characterization, surface plasmon resonance spectra were found at 530 nm for AuNPs and 446 nm for AgNPs. XRD data confirmed that both synthesized nanoparticles were face-centered cubic in crystalline nature, and the average crystallite sizes for the assign peaks were 13.3 nm for AuNPs and 22.48 nm for AgNPs. FTIR data evaluated the characteristic peaks of different phytochemical components of tuber extract, which acted as the reducing agent, and possibly as stabilizing agents. The antibacterial activity of synthesized AuNPs and AgNPs were examined in Muller Hinton agar, against two Gram-positive and four Gram-negative bacteria through the disc diffusion method. AuNPs did not show any inhibitory effect, while AgNPs showed good inhibitory effect against both Gram-positive and Gram-negative bacteria.

BACKGROUND: Intralipid® administration at reperfusion elicits protection against myocardial ischemia-reperfusion injury. However, the underlying mechanisms are not fully understood. METHODS: Sprague-Dawley rat hearts were exposed to 15 min of ischemia and 30 min of reperfusion in the absence or presence of Intralipid® 1% administered at the onset of reperfusion. In separate experiments, the reactive oxygen species (ROS) scavenger N-(2-mercaptopropionyl)-glycine was added either alone or with Intralipid®. Left ventricular work and activation of Akt, STAT3, and ERK1/2 were used to evaluate cardioprotection. ROS production was assessed by measuring the loss of aconitase activity and the release of hydrogen peroxide using Amplex Red. Electron transport chain complex activities and proton leak were measured by high-resolution respirometry in permeabilized cardiac fibers. Titration experiments using the fatty acid intermediates of Intralipid® palmitoyl-, oleoyl- and linoleoylcarnitine served to determine concentration-dependent inhibition of complex IV activity and mitochondrial ROS release. RESULTS: Intralipid® enhanced postischemic recovery and activated Akt and Erk1/2, effects that were abolished by the ROS scavenger N-(2-mercaptopropionyl)glycine. Palmitoylcarnitine and linoleoylcarnitine, but not oleoylcarnitine concentration-dependently inhibited complex IV. Only palmitoylcarnitine reached high tissue concentrations during early reperfusion and generated significant ROS by complex IV inhibition. Palmitoylcarnitine (1 µM), administered at reperfusion, also fully mimicked Intralipid®-mediated protection in an N-(2-mercaptopropionyl)-glycine -dependent manner. CONCLUSIONS: Our data describe a new mechanism of postconditioning cardioprotection by the clinically available fat emulsion, Intralipid®. Protection is elicited by the fatty acid intermediate palmitoylcarnitine, and involves inhibition of complex IV, an increase in ROS production and activation of the RISK pathway.

The thin film of N-doped ZnO/CNT nanocomposite was successfully fabricated on soda lime glass substrate by a simple sol-gel drop-coating method. The structural, morphological, chemical, and optical properties of as prepared samples were characterized by a variety of tools such as X-ray Diffraction (XRD), Field Emission Scanning Electron Microscopy (FE-SEM), Fourier Transform Infrared spectroscopy (FT-IR), and UV-visible spectroscopy. The hexagonal crystalline structure was confirmed from XRD measurement without any other impurity phase detection in samples. The N-doped ZnO/CNT composite showed excellent photo-catalytic activity towards cationic methylene blue (MB) dye degradation with 100% removal rate under UV light irradiation as compared to N-doped ZnO (65%) and pure ZnO (47.36%). The convincing performance has also been observed for the case of visible light irradiation. The enhancement of that photocatalytic activity might be due to narrowing the band gap as well as the reduction of electron-hole pair recombination in ZnO matrix with the incorporation of dopant nitrogen and CNT. It is assumed from the obtained results that N-doped ZnO/CNT nanocomposite thin film can be employed as an economically achievable and ecofriendly method to degrade dye with UV and visible light irradiation. Additionally, density functional theory (DFT) calculations were applied to explore the effect of N-doping on electronic structure of ZnO. The computational study has supported the experimental results of significant band gap contraction, which leads to the maximum absorption towards higher wavelength and no appreciable change of lattice parameters after doping. A conceivable photocatalytic mechanism of N-doped ZnO/CNT nanocomposite has been proposed as well.

African American (AA) women have a lower overall incidence of breast cancer than do Caucasian (CAU) women, but a higher overall mortality. Little is known as to why the incidence of breast cancer is lower yet mortality is higher in AA women. Many studies speculate that this is only a socio-economical problem. This investigation suggests the possibility that molecular mechanisms contribute to the increased mortality of AA women with breast cancer. This study investigates the expression of 14 genes which have been shown to play a role in cancer metastasis. Cell lines derived from AA and CAU patients were analyzed to demonstrate alterations in the transcription of genes known to be involved in cancer and the metastatic process. Total RNA was isolated from cell lines and analyzed by RT-PCR analysis. Differential expression of the 14 targeted genes between a spectrum model (6 breast cancer cell lines and 2 non-cancer breast cell lines) and a metastasis model (12 metastatic breast cancer cell lines) were demonstrated. Additionally, an in vitro comparison of the expression established differences in 5 of the 14 biomarker genes between African American and Caucasian breast cell lines. Results from this study indicates that altered expression of the genes Atp1b1, CARD 10, KLF4, Spint2, and Acly may play a role in the aggressive phenotype seen in breast cancer in African American women.

Forensic imaging is a non-invasive examination process during the forensic investigation. It is mainly used in forensic pathology as an adjunct to the traditional autopsy. In the past two decades, forensic imaging has been vigorously developed by forensic experts from computed tomography (CT) to multiple augmented techniques through CT and magnetic resonance imaging (MRI). The application field of forensic imaging has also been broadened as its advantages are recognised by more forensic practitioners. In addition to the forensic pathology, this technique has been used in other forensic disciplines, including forensic anthropology, forensic odontology, forensic ballistics and wildlife forensics, etc. This article reviews the development of forensic imaging as the practice and research development in different forensic disciplines based on the relevant literature analysis.

Reduced graphene oxide has certain unique qualities that make them versatile for a myriad of applications. Unlike graphene oxide, reduced graphene oxide is a conductive material and well suited for use in electrically conductive materials, such as solar cell devices. In this study, we report on the synthesis of graphene oxide as well as the fabrication and characterization of dye-sensitized solar cells with a photoanode which is an amalgam of reduced graphene oxide and titanium dioxide. The synthesized reduced graphene oxide and the corresponding photoanode were fully characterized using Ultraviolet-visible, Fourier transform infrared (FTIR), and Raman Spectrometry. The morphology of the sample was assessed using Atomic Force Microscopy, Field Emission Scanning Electron Microscopy, Transmission Electron Microscopy, and Energy Dispersive X-ray Spectroscopy. The photovoltaic characteristics were determined by photocurrent and photo-voltage measurements of the fabricated solar cells. The electrical impedances of both sets of devices were also evaluated. Overall, the solar to electric power efficiency of the device with reduced graphene oxide was observed to be higher (2.02%) than the device without the reduced graphene oxide (1.61%).

Raman spectra of compacted fused silica are presented. Fused silica was sujected to a pressure of 9.0 GPa for 1 hr at 23 °C. The density of the compacted silica was 2.40 g cm−3 compared to 2.22 g cm−3 for the uncompacted glass. Various interesting features of the spectrum are discussed. (AIP)

The beta-normal distribution is characterized by four parameters that jointly describe the location, the scale and the shape properties. The beta-normal distribution can be unimodal or bimodal. This paper studies the bimodality properties of the beta-normal distribution. The region of bimodality in the parameter space is obtained. The beta-normal distribution is applied to fit a numerical bimodal data set. The beta-normal fits are compared with the fits of mixture-normal distribution through simulation.

This qualitative study of forty men from a wide range of family contexts examines the relationships between fathering and men's early adult development. Through assuming responsibility for fathering and continued involvement in child rearing, the fathers in this study perceived significant changes in their life course and personalities. Modes of change, while pervasive and profound, varied along divergent paths. One path characterized engagement in fathering as bringing a “jolt” to the life course. Substantive, but less dramatic changes were perceived by a second group of men who characterized father involvement as a “gentle evoker” of latent personality traits. A majority of men saw fatherhood as the single greatest shaper of their lives. As such, the study offers empirical support to the theoretically and anecdotally based idea that fathering alters the course of adult male development.

This paper examines both the linear and nonlinear causal relationships between crude oil price changes and stock market returns for the United States. In particular, the study applied a bat-tery of unit root tests to ascertain the time series properties of crude oil price changes and stock market returns. The linear and nonlinear causality tests were conducted through the standard VAR and the M-G frameworks, respectively. The results from both the linear and nonlinear unit root tests indicate that crude oil price changes and stock market returns are level stationary. The results from the standard VAR model provide evidence of bidirectional causality between crude oil price changes and stock market returns. The results from the M-G causality test sup-port the finding of nonlinear bidirectional causality between crude oil price changes and stock market returns.

Food is the essential foundation for sustainable and healthy communities. Increasing population and urbanization, limited resources, and complexities of interactions necessitate a comprehensive and in-depth understanding of the dynamics of the global trend of urbanization. The key objective of this paper is to generate new environmental, social and economic perspectives and practices that are responsive to the rapidly urbanizing agricultural food system. We used the sustainability paradigm in the context of environmental, social, and economic sustainability to outline the three transitioning states and perspectives (unconnected/silos; interconnected/linkages; and interdependent/nested/systems) for urban agricultural food systems. We sought to ferret out the key driver/response variables and their cross-scale interactions in the urbanizing food-energy-water nexus. We used a five-step qualitative analytical method to develop a conceptual model to capture the interacting variables and their responses. The complexity in the driver/response variables and their cross-scale interactions were identified. Then three hypothetical scenarios were used to represent complexity modeling: least, medium and most complex. These variables were combined with outside dimensions (e.g., innovation, stakeholders, urbanization) for selected scenarios and deconstructed using spider web and causal loop models. The urbanizing socio-ecological systems, across various spatial (local to global) and temporal scales (days to millennium) as well as smaller temporal scales (days to decades) are described. The iterative multidimensionality of the model makes clear new ways of seeing social issues and opens opportunities for policy solutions, resources and stakeholders to be brought to bear on the issues.