Defence Materials Technology Centre (Australia)

Abstract Thermoelectric (TE) materials have the capability of converting heat into electricity, which can improve fuel efficiency, as well as providing robust alternative energy supply in multiple applications by collecting wasted heat, and therefore, assisting in finding new energy solutions. In order to construct high performance TE devices, superior TE materials have to be targeted via various strategies. The development of high performance TE devices can broaden the market of TE application and eventually boost the enthusiasm of TE material research. This review focuses on major novel strategies to achieve high‐performance TE materials and their applications. Manipulating the carrier concentration and band structures of materials are effective in optimizing the electrical transport properties, while nanostructure engineering and defect engineering can greatly reduce the thermal conductivity approaching the amorphous limit. Currently, TE devices are utilized to generate power in remote missions, solar–thermal systems, implantable or/wearable devices, the automotive industry, and many other fields; they are also serving as temperature sensors and controllers or even gas sensors. The future tendency is to synergistically optimize and integrate all the effective factors to further improve the TE performance, so that highly efficient TE materials and devices can be more beneficial to daily lives.

This paper provides a review of recent developments in the field of Mg corrosion and puts those into context. This includes considerations of corrosion manifestations, material influences, surface treatment, anodization, coatings, inhibition, biodegradable medical applications, stress corrosion cracking, flammability, corrosion mechanisms for HP Mg, critical evaluation of corrosion mechanisms, and concluding remarks. There has been much research recently, and much research continues in this area. This is expected to produce significantly better, more‐corrosion‐resistant Mg alloys.

Power consumption imposes a significant cost for data centers implementing cloud services, yet much of that power is used to maintain excess service capacity during periods of low load. This paper investigates how much can be saved by dynamically “right-sizing” the data center by turning off servers during such periods and how to achieve that saving via an online algorithm. We propose a very general model and prove that the optimal offline algorithm for dynamic right-sizing has a simple structure when viewed in reverse time, and this structure is exploited to develop a new “lazy” online algorithm, which is proven to be 3-competitive. We validate the algorithm using traces from two real data-center workloads and show that significant cost savings are possible. Additionally, we contrast this new algorithm with the more traditional approach of receding horizon control.

Synthetic procedure of three-dimensional porous graphene-like sheets <italic>via</italic> low-temperature graphitization.

Metal additive manufacturing (AM) is an innovative manufacturing technique, which builds parts incrementally layer by layer. Thus, metal AM has inherent advantages in part complexity, time, and waste saving. However, due to its complex thermal cycle and rapid solidification during processing, the alloys well suit and commercially used for metal AM today are limited. Therefore, it is important to understand the alloying strategy and current progress with materials performance to consider alloy development for metal AM. This review presents the current range of alloys available for metal AM, including titanium, steel, nickel, aluminum, less common alloys (including Mg alloys, metal matrix composites alloys, and low melting point alloys), and compositionally complex alloys (including bulk metallic glasses and high entropy alloys) with a focus on the relationship between compositions, processing, microstructures, and properties of each alloy system. In addition, some promising alloy systems for metal AM are highlighted. Approaches for designing and optimizing new materials for metal AM have been summarized.

Selective laser melting (SLM) is a powder bed fusion type metal additive manufacturing process which is being applied to manufacture highly customised and value-added parts in biomedical, defence, aerospace, and automotive industries. Aluminium alloy is one of the widely used metals in manufacturing parts in SLM in these sectors due to its light weight, high strength, and corrosion resistance properties. Parts used in such applications can be subjected to severe dynamic loadings and high temperature conditions in service. It is important to understand the mechanical response of such products produced by SLM under different loading and operating conditions. This paper presents a comprehensive review of the latest research carried out in understanding the mechanical properties of aluminium alloys processed by SLM under static, dynamic, different build orientations, and heat treatment conditions with the aim of identifying research gaps and future research directions.

Abstract Colloidal processing of fine ceramic powders enables the production of complex shaped ceramics with unique micro and macro structures which are not possible to produce via conventional dry processing routes. Because of this enhanced structural control and shaping capabilities, colloidal processing has been exploited to produce ceramic components with ever increasing complexity and functionalities. In this review, we revisit some of the research efforts on this topic to highlight its relevance and growing importance for the advanced manufacturing of functional ceramics. Selected examples of colloidal systems with increasing level of complexity are discussed to showcase the wide range of structures that can be generated through wet processing approaches. The historical development and background knowledge pertaining to colloids and surface interactions is first briefly reviewed. The major colloidal shape forming and additive manufacturing processes that utilize colloidal pastes and inks are then reviewed, highlighting the control of suspension rheology needed in these techniques. Next, methodologies that combine suspended particles with a pore‐forming phase are discussed as a means to produce porous ceramic materials. Further control over the interactions between anisotropic particles and their alignment in suspensions can be gained via externally applied fields (such as magnetic) to produce texturally aligned green bodies. This leads to bioinspired ceramics that can programmably morph into complex shaped objects upon sintering. Hierarchical porous structures with high mechanical efficiency are also shown as an example of the multiscale designs that can be generated through advanced colloidal processing. As drying of ceramic bodies is an inevitable consequence of wet colloidal processing, the current understanding of this critical processing step is reviewed. Finally, the gaps in knowledge in these fields are discussed to provide our perspective on where the field may support advances in ceramics in the future.

Graphene has become an important research focus in many current fields of science including composite manufacturing. Developmental work in the field of graphene-enhanced composites has revealed several functional and structural characteristics that promise great benefits for their use in a broad range of applications. There has been much interest in the production of multiscale high-performance, lightweight, yet robust, multifunctional graphene-enhanced fiber-reinforced polymer (gFRP) composites. Although there are many reports that document performance enhancement in materials through the inclusion of graphene nanomaterials into a matrix, or its integration onto the reinforcing fiber component, only a few graphene-based products have actually made the transition to the marketplace. The primary focus of this work concerns the structural gFRPs and discussion on the corresponding manufacturing methodologies for the effective incorporation of graphene into these systems. Another important aspect of this work is to present recent results and highlight the excellent functional and structural properties of the resulting gFRP materials with a view to their future applications. Development of clear standards for the assessment of graphene material properties, improvement of existing materials and scalable manufacturing technologies, and specific regulations concerning human health and environmental safety are key factors to accelerate the successful commercialization of gFRPs.

In this review, the evolution of textured lead-free piezoceramics has been explored, primarily focusing on the technique of templated grain growth (TGG) and reactive-templated grain growth (RTGG), as an alternative to single crystals. The mechanics and properties of using template in guiding and orienting the ceramic grains into the same crystal orientation allow for piezoelectric properties approaching those of their single-crystal counterparts. The fabrication process was surveyed in depth, with focus placed on the tape casting process and numerous variables associated with aligning the template seeds in the ceramic matrix. The piezoelectric and ferroelectric properties of the textured ceramics are supposed to be a function of all parameters (tape casting, slurry formation, sintering profile, template properties) in an effort to determine the significance of their contributions to the properties.

Today additive manufacturing is shaping the future of global manufacturing and is influencing the design and manufacturability of tomorrows products. With selective laser melting (SLM), parts can be built directly from computer models or from measurements of existing components to be re-engineered, and therefore bypass traditional manufacturing processes such as cutting, milling and grinding. Benefits include: 1) new designs not possible using conventional subtractive technology, 2) dramatic savings in time, materials, wastage, energy and other costs in producing new components, 3) significant reductions in environmental impact, and 4) faster time to market. SLM builds up finished components from raw material powders layer by layer through laser melting. SLM removes many of the shape restrictions that limit design with traditional manufacturing methods, thereby allowing computationally optimised, high performance structures to be utilised. Functional engineering prototypes and actual components can then be built in their final shape with minimal material wastage. Samples and small product runs can be produced quickly at comparatively low cost to test and build market acceptance without major investment. In this chapter we present and discuss some of the concepts and findings involved in the design, manufacture and examination of high-value aerospace components from Ti-6Al-4V alloy produced at the RMITs Advanced Manufacturing Precinct.

A sensitive electrochemical sensor of paracetamol was developed based on a β-CD/reduced graphene oxide modified electrode.

Since the invention of small arms ammunition, the human torso has required protection from hand-gun bullets, and today’s civil and military personnel are regularly clad in soft body armor systems to cope with these threats. However, increasingly, the threat spectrum has widened to include a plethora of both edged and pointed weapons. Over the past two decades in particular, this has required development of either specific soft armors to defeat that particular threat, or the development of multi-threat vests that can resist both hand-gun bullets and knife and spike attacks. In this review, we provide more details about the various material combinations that are used to defeat a knife or spike, since these armor materials are a lot different from the conventional aramid fabrics, and numerous, widely-different solutions are being pursued. The penetration mechanisms associated with the various forms of attack—stabbing and slashing—are discussed, as well as the use of new fibers, shear thickening fluids, and nano-materials in developing these body armor systems.

We present a comparison of major methodologies of fast generating mock halo or galaxy catalogues. The comparison is done for two-point (power spectrum and two-point correlation function in real and redshift space), and the three-point clustering statistics (bispectrum and three-point correlation function). The reference catalogues are drawn from the BigMultiDark N-body simulation. Both friend-of-friends (including distinct haloes only) and spherical overdensity (including distinct haloes and subhalos) catalogues have been used with the typical number density of a large volume galaxy surveys. We demonstrate that a proper biasing model is essential for reproducing the power spectrum at quasi-linear and even smaller scales. With respect to various clustering statistics, a methodology based on perturbation theory and a realistic biasing model leads to very good agreement with N-body simulations. However, for the quadrupole of the correlation function or the power spectrum, only the method based on semi-N-body simulation could reach high accuracy (1 per cent level) at small scales, i.e. r < 25 h -1 Mpc or k > 0.15 h Mpc -1 . Full N-body solutions will remain indispensable to produce reference catalogues. Nevertheless, we have demonstrated that the more efficient approximate solvers can reach a few per cent accuracy in terms of clustering statistics at the scales interesting for the large-scale structure analysis. This makes them useful for massive production aimed at covariance studies, to scan large parameter spaces, and to estimate uncertainties in data analysis techniques, such as baryon acoustic oscillation reconstruction, redshift distortion measurements, etc.

Purpose The purpose of this paper is to demonstrate the preliminary work on using laser cladding technology for the restoration of structural integrity. Design/methodology/approach The primary methodology used in this research is to develop a laser cladding‐based metal deposition technique to articulate restoration of structural geometry affected by corrosion damages. Following from this method, it is planned to undertake further work to use the laser cladding process to restore geometry and the associated static/fatigue strength. Findings This work has found that it is possible to use laser cladding as a repair technology to improve structural integrity in aluminium alloy aircraft structures in terms of corrosion reduction and geometrical restoration. Initial results have indicated a reduction of static and fatigue resistance with respect to substrate. But more recent works (yet to be published) have revealed improved fatigue strength as measured in comparison to the substrate structural properties. Originality/value The research is based on an acceptable materials processing technique.

Respiratory infections caused by Pseudomonas aeruginosa are a major clinical problem globally, particularly for patients with chronic pulmonary disorders, such as those with cystic fibrosis (CF), non-CF bronchiectasis (nCFB) and severe chronic obstructive pulmonary disease (COPD). In addition, critically ill and immunocompromised patients are also at significant risk of P. aeruginosa infection. For almost half a century, research efforts have focused toward development of a vaccine against infections caused by P. aeruginosa, but a licensed vaccine is not yet available. Significant advances in identifying potential vaccine antigens have been made. Immunisations via both the mucosal and systemic routes have been trialled in animal models and their effectiveness in clearing acute infections demonstrated. The challenge for translation of this research to human applications remains, since P. aeruginosa infections in the human respiratory tract can present both as an acute or chronic infection. In addition, immunisation prior to infection may not be possible for many patients with CF, nCFB or COPD. Therefore, development of a therapeutic vaccine provides an alternative approach for treatment of chronic infection. Preliminary animal and human studies suggest that mucosal immunisation may be effective as a therapeutic vaccine against P. aeruginosa respiratory infections. Nevertheless, more research is needed to improve our understanding of the basic biology of P. aeruginosa and the mechanisms needed to upregulate the induction of host immune pathways to prevent infection. Recognition of variability in the host immune responses for a range of patient health conditions at risk from P. aeruginosa infection is also required to support development of a successful vaccine delivery strategy and vaccine. Activation of mucosal immune responses may provide improved efficacy of vaccination for P. aeruginosa during both acute exacerbations and chronic infection.

The latissimus dorsi added fat flap is an alternative method of natural tissue breast reconstruction. A significant volume of additional subcutaneous back fat is left attached to a traditional latissimus dorsi flap, avoiding the need for an additional implant. The surgical technique and results in 15 patients are discussed.

The mitigation of electromagnetic pollution is becoming an increasing issue due to the proliferation and miniaturization of electronic components. Electromagnetic interference (EMI) shields must be considered to bring about electromagnetic compatibility (EMC), where analyzing the shielding effectiveness (SE) is of great importance. Graphene-enhanced polymer composite materials are recently introduced as a replacement for metal-based EMI shielding materials due to their low cost, resistance to corrosion, lightweight, versatile, and straightforward processability, as well as broad bandwidth properties compared to conventional metal-based materials. The SE can be determined from the bulk material properties, including permittivity, permeability, and conductivity, using analytical or numerical solutions to Maxwell's equations. Though, Due to the heterogeneity of graphene-based polymer composites, characterization of these values remains difficult. This article attempts to summarise and critically review the state-of-the-art progress in the fabrication and characterization of these materials. Also, this review elaborates on accurate modelling techniques based on the underlying micromechanics, e.g., percolation, electron tunnelling, agglomeration, imperfect interface, frequency-dependent nanocapacitance and electron hopping. The model is designed to predict the electromagnetic properties of the nanocomposite from the pre-determined properties of the polymer matrix and carbon-based filler. This understanding may ultimately lead to the development of graphene/polymer composites with optimized EMI shielding properties to develop emerging EMI shielding materials. This paper focuses heavily on Graphite Nanoplatelet (GnP)/Epoxy as the choice of graphene/polymer.

The improvement of machinability during laser-assisted milling of Ti-6Al-4V alloy was investigated. The effects of laser processing and milling parameters on cutting forces and tool wear have been examined. It is found that local heating and softening of the workpiece by the laser beam in front of the cutting tool significantly reduced the cutting forces, especially the force in the feed direction during up-cut milling. Laser power, tool–beam distance, depth of cut and cutting speed are the parameters influencing the change of feed force during laser-assisted milling. Analysis of the workpiece temperature rise due to laser beam heating shows that the feed force is strongly dependent on the workpiece temperature in front of the cutting zone; significant reduction of feed force occurred when the temperature in front of thecutting zone was in the range 200–450°C. Edge chipping is found to be the tool failure mode for both conventional milling and laser-assisted milling. A significant improvement in tool life during laser-assisted milling was obtained when the workpiece temperature in front of the cutting zone was at an optimum value. Compressed air was used to remove the chip from the cutting tool, which made the milling process more effective. The optimum workpiece temperature in front of the cutting zone with compressed air delivered through the spindle is about 350°C, higher than that with compressed air delivered through a stationary nozzle (about 230°C). The maximum tool life in the former case is much longer than that in the latter case.

The laser cladding of Ti-6Al-4 V powder on Ti-6Al-4 V substrate has been investigated to determine laser parameters that could be used as a repair technology for Ti-6Al-4 V components. The parameters chosen for the investigation were developed by an analytical laser cladding model. Holding clad height and melt pool depth constant, the traversing speed was varied between 300 mm/min and 1500 mm/min, an associated power for the given speed was calculated by the model. Two different melt pool depths were used in the calculation of laser power for a given process velocity. The resulting microstructures in the clad zone varied from a relatively thin martensitic structure to a dendritic/thick martensitic structure. The heat affected zone (HAZ) showed a refinement of the Widmanstatten microstructure with a decreasing laser traversing speed and a coarser martensitic structure for the sample prepared with a deeper melt pool.

Abstract The present study investigates the influence of ultrasonic treatment on the grain refinement of commercial purity aluminium with a range of Al3Ti1B master alloy additions. When the aluminium contains the smallest amount of added master alloy, ultrasonics caused significant additional grain refinement compared to that provided by the master alloy alone. However, the influence of ultrasonics on grain size reduces with increasing addition of the master alloy which adds additional TiB 2 particles and Ti solute with each incremental addition. Applying the Interdependence model to analyse the experimentally measured grain sizes revealed that the results of this study and those from similar experiments on an Al-2Cu alloy were consistent when the alloy compositions are converted to their growth restriction factors ( Q) and that increasing Q had a major effect on reducing grain size and increasing grain number density. Compared with the application of ultrasonic treatment where an order of magnitude increase in the grain number density is achieved, an increase in the Ti content over the range of master alloy additions, causes the grain number density to increase by approximately three times.