Denver Federal Center

Excitation-emission matrix (EEM) fluorescence spectroscopy has been widely used to characterize dissolved organic matter (DOM) in water and soil. However, interpreting the > 10,000 wavelength-dependent fluorescence intensity data points represented in EEMs has posed a significant challenge. Fluorescence regional integration, a quantitative technique that integrates the volume beneath an EEM, was developed to analyze EEMs. EEMs were delineated into five excitation-emission regions based on fluorescence of model compounds, DOM fractions, and marine waters or freshwaters. Volumetric integration under the EEM within each region, normalized to the projected excitation-emission area within that region and dissolved organic carbon concentration, resulted in a normalized region-specific EEM volume (phi(i,n)). Solid-state carbon nuclear magnetic resonance (13C NMR), Fourier transform infrared (FTIR) analysis, ultraviolet-visible absorption spectra, and EEMs were obtained for standard Suwannee River fulvic acid and 15 hydrophobic or hydrophilic acid, neutral, and base DOM fractions plus nonfractionated DOM from wastewater effluents and rivers in the southwestern United States. DOM fractions fluoresced in one or more EEM regions. The highest cumulative EEM volume (phi(T,n) = sigma phi(i,n)) was observed for hydrophobic neutral DOM fractions, followed by lower phi(T,n) values for hydrophobic acid, base, and hydrophilic acid DOM fractions, respectively. An extracted wastewater biomass DOM sample contained aromatic protein- and humic-like material and was characteristic of bacterial-soluble microbial products. Aromatic carbon and the presence of specific aromatic compounds (as indicated by solid-state 13C NMR and FTIR data) resulted in EEMs that aided in differentiating wastewater effluent DOM from drinking water DOM.

Over the last three years, a major international effort has been made by the Sub-Commission on Earthquake Algorithms of the International Association of Seismology and the Physics of the Earth's Interior (IASPEI) to generate new global traveltime tables for seismic phases to update the tables of Jeffreys & Bullen (1940). The new tables are specifically designed for convenient computational use, with high-accuracy interpolation in both depth and range. The new iasp91 traveltime tables are derived from a radially stratified velocity model which has been constructed so that the times for the major seismic phases are consistent with the reported times for events in the catalogue of the International Seismological Centre (ISC) for the period 1964–1987. The baseline for the P-wave traveltimes in the iasp91 model has been adjusted to provide only a small bias in origin time for well-constrained events at the main nuclear testing sites around the world. For P-waves at teleseismic distances, the new tables are about 0.7s slower than the 1968 P-tables (Herrin 1968) and on average about 1.8-1.9 s faster than the Jeffreys & Bullen (1940) tables. For S-waves the teleseismic times lie between those of the JB tables and the results of Randall (1971). Because the times for all phases are derived from the same velocity model, there is complete consistency between the traveltimes for different phases at different focal depths. The calculation scheme adopted for the new iasp91 tables is that proposed by Buland & Chapman (1983). Tables of delay time as a function of slowness are stored for each traveltime branch, and interpolated using a specially designed tau spline which takes care of square-root singularities in the derivative of the traveltime curve at certain critical slownesses. With this representation, once the source depth is specified, it is straightforward to find the traveltime explicitly for a given epicentral distance. The computational cost is no higher than a conventional look-up table, but there is increased accuracy in constructing the traveltimes for a source at arbitrary depth. A further advantage over standard tables is that exactly the same procedure can be used for each phase. For a given source depth, it is therefore possible to generate very rapidly a comprehensive list of traveltimes and associated derivatives for the main seismic phases which could be observed at a given epicentral distance.

1 0 320 seconds Distance, in centimeters Distance, in centimeters 10 10 5 0 0 5 0 Cerium(4), in millimoles per liter Cover Techniques and Methods 6-A43 U.S.

New empirical traveltime curves for the major seismic phases have been derived from the catalogues of the International Seismological Centre by relocating events by using P readings, depth phases and the iasp91 traveltimes, and then re-associating phase picks. A smoothed set of traveltime tables is extracted by a robust procedure which gives estimates of the variance of the traveltimes for each phase branch. This set of smoothed empirical times is then used to construct a range of radial velocity profiles, which are assessed against a number of different measures of the level of fit between the empirical times and the predictions of the models. These measures are constructed from weighted sums of L2 misfits for individual phases. The weights are chosen to provide a measure of the probable reliability of the picks for the different phases. A preferred model, ak135, is proposed which gives a significantly better fit to a broad range of phases than is provided by the iasp91 and sp6 models. The differences in velocity between ak135 and these models are generally quite small except at the boundary of the inner core, where reduced velocity gradients are needed to achieve satisfactory performance for PKP differential time data. The potential resolution of velocity structure has been assessed with the aid of a non-linear search procedure in which 5000 models have been generated in bounds about ak135. Misfit calculations are performed for each of the phases in the empirical traveltime sets, and the models are then sorted using different overall measures of misfit. The best 100 models for each criterion are displayed in a model density plot which indicates the consistency of the different models. The interaction of information from different phases can be analysed by comparing the different misfit measures. Structure in the mantle is well resolved except at the base, and ak135 provides a good representation of core velocities.

Abstract Shale-gas resource plays can be distinguished by gas type and system characteristics. The Newark East gas field, located in the Fort Worth Basin, Texas, is defined by thermogenic gas production from low-porosity and low-permeability Barnett Shale. The Barnett Shale gas system, a self-contained source-reservoir system, has generated large amounts of gas in the key productive areas because of various characteristics and processes, including (1) excellent original organic richness and generation potential; (2) primary and secondary cracking of kerogen and retained oil, respectively; (3) retention of oil for cracking to gas by adsorption; (4) porosity resulting from organic matter decomposition; and (5) brittle mineralogical composition. The calculated total gas in place (GIP) based on estimated ultimate recovery that is based on production profiles and operator estimates is about 204 bcf/section (5.78 × 109 m3/1.73 × 104 m3). We estimate that the Barnett Shale has a total generation potential of about 609 bbl of oil equivalent/ac-ft or the equivalent of 3657 mcf/ac-ft (84.0 m3/m3). Assuming a thickness of 350 ft (107 m) and only sufficient hydrogen for partial cracking of retained oil to gas, a total generation potential of 820 bcf/section is estimated. Of this potential, approximately 60% was expelled, and the balance was retained for secondary cracking of oil to gas, if sufficient thermal maturity was reached. Gas storage capacity of the Barnett Shale at typical reservoir pressure, volume, and temperature conditions and 6% porosity shows a maximum storage capacity of 540 mcf/ac-ft or 159 scf/ton.

Abstract We relocate nearly 100,000 events that occurred during the period 1964 to 1995 and are well-constrained teleseismically by arrival-time data reported to the International Seismological Centre (ISC) and to the U.S. Geological Survey's National Earthquake Information Center (NEIC). Hypocenter determination is significantly improved by using, in addition to regional and teleseismic P and S phases, the arrival times of PKiKP, PKPdf, and the teleseismic depth phases pP, pwP, and sP in the relocation procedure. A global probability model developed for later-arriving phases is used to independently identify the depth phases. The relocations are compared to hypocenters reported in the ISC and NEIC catalogs and by other sources. Differences in our epicenters with respect to ISC and NEIC estimates are generally small and regionally systematic due to the combined effects of the observing station network and plate geometry regionally, differences in upper mantle travel times between the reference earth models used, and the use of later-arriving phases. Focal depths are improved substantially over most other independent estimates, demonstrating (for example) how regional structures such as downgoing slabs can severely bias depth estimation when only regional and teleseismic P arrivals are used to determine the hypocenter. The new data base, which is complete to about Mw 5.2 and includes all events for which moment-tensor solutions are available, has immediate application to high-resolution definition of Wadati-Benioff Zones (WBZs) worldwide, regional and global tomographic imaging, and other studies of earth structure.

The submarine hydrothermal activity on and near the Galápagos Rift has been explored with the aid of the deep submersible Alvin. Analyses of water samples from hydrothermal vents reveal that hydrothermal activity provides significant or dominant sources and sinks for several components of seawater; studies of conductive and convective heat transfer suggest that two-thirds of the heat lost from new oceanic lithosphere at the Galápagos Rift in the first million years may be vented from thermal springs, predominantly along the axial ridge within the rift valley. The vent areas are populated by animal communities. They appear to utilize chemosynthesis by sulfur-oxidizing bacteria to derive their entire energy supply from reactions between the seawater and the rocks at high temperatures, rather than photosynthesis.

A series of chapters on techniques describes methods used by the U.S. Geological Survey for planning and conducting water-resources investigations. The material is arranged under major subject headings called books and is further subdivided into sections and chapters. Book 5 is on laboratory analyses; section A is on water. The unit of publication, the chapter, is limited to a narrow field of subject matter. "Methods for Determination of Inorganic Substances in Water and Fluvial Sediments" is the first chapter under section A of book 5. The chapter number includes the letter of the section.

Abstract Pore-throat sizes in siliciclastic rocks form a continuum from the submillimeter to the nanometer scale. That continuum is documented in this article using previously published data on the pore and pore-throat sizes of conventional reservoir rocks, tight-gas sandstones, and shales. For measures of central tendency (mean, mode, median), pore-throat sizes (diameters) are generally greater than 2 μm in conventional reservoir rocks, range from about 2 to 0.03 μm in tight-gas sandstones, and range from 0.1 to 0.005 μm in shales. Hydrocarbon molecules, asphaltenes, ring structures, paraffins, and methane, form another continuum, ranging from 100 Å (0.01 μm) for asphaltenes to 3.8 Å (0.00038 μm) for methane. The pore-throat size continuum provides a useful perspective for considering (1) the emplacement of petroleum in consolidated siliciclastics and (2) fluid flow through fine-grained source rocks now being exploited as reservoirs.

Research Article| July 01, 1988 The formation and failure of natural dams JOHN E. COSTA; JOHN E. COSTA 1U.S. Geological Survey, Cascades Volcano Observatory, 5400 MacArthur Boulevard, Vancouver, Washington 98661 Search for other works by this author on: GSW Google Scholar ROBERT L. SCHUSTER ROBERT L. SCHUSTER 2U.S. Geological Survey, M.S. 966, Denver Federal Center, Lakewood Colorado 80225 Search for other works by this author on: GSW Google Scholar Author and Article Information JOHN E. COSTA 1U.S. Geological Survey, Cascades Volcano Observatory, 5400 MacArthur Boulevard, Vancouver, Washington 98661 ROBERT L. SCHUSTER 2U.S. Geological Survey, M.S. 966, Denver Federal Center, Lakewood Colorado 80225 Publisher: Geological Society of America First Online: 01 Jun 2017 Online ISSN: 1943-2674 Print ISSN: 0016-7606 Geological Society of America GSA Bulletin (1988) 100 (7): 1054–1068. https://doi.org/10.1130/0016-7606(1988)100<1054:TFAFON>2.3.CO;2 Article history First Online: 01 Jun 2017 Cite View This Citation Add to Citation Manager Share Icon Share Facebook Twitter LinkedIn Email Permissions Search Site Citation JOHN E. COSTA, ROBERT L. SCHUSTER; The formation and failure of natural dams. GSA Bulletin 1988;; 100 (7): 1054–1068. doi: https://doi.org/10.1130/0016-7606(1988)100<1054:TFAFON>2.3.CO;2 Download citation file: Ris (Zotero) Refmanager EasyBib Bookends Mendeley Papers EndNote RefWorks BibTex toolbar search Search Dropdown Menu toolbar search search input Search input auto suggest filter your search All ContentBy SocietyGSA Bulletin Search Advanced Search Abstract Of the numerous kinds of dams that form by natural processes, dams formed from landslides, glacial ice, and late-neoglacial moraines present the greatest threat to people and property. Landslide dams form in a wide range of physiographic settings. The most common types of mass movements that form landslide dams are rock and debris avalanches; rock and soil slumps and slides; and mud, debris, and earth flows. The most common initiation mechanisms for dam-forming landslides are excessive rainfall and snowmelt and earthquakes.Landslide dams can be classified into six categories based on their relation with the valley floor. Type I dams (11% of 184 landslide dams from around the world that we were able to classify) do not reach from one valley side to the other. Type II dams (44%) span the entire valley floor, in some cases depositing material high on opposite valley sides. Type III dams (41%) move considerable distances both upstream and downstream from the landslide failure. Type IV dams (<1%) are rare and involve the contemporaneous failure of material from both sides of a valley. Type V dams (<1%) also are rare and are created when a single landslide sends multiple tongues of debris into a valley and forms two or more landslide dams in the same reach of river. Type VI dams (3%) involve one or more failure surfaces that extend under the stream or valley and emerge on the opposite valley side.Many landslide dams fail shortly after formation. In our sample of 73 documented landslide-dam failures, 27% of the landslide dams failed less than 1 day after formation, and about 50% failed within 10 days. Over-topping is by far the most common cause of failure. The timing of failure and the magnitude of the resulting floods are controlled by dam size and geometry; material characteristics of the blockage; rate of inflow to the impoundment; size and depth of the impoundment; bedrock control of flow; and engineering controls such as artificial spill-ways, diversions, tunnels, and planned breaching by blasting or conventional excavation.Glacial-ice dams can produce at least nine kinds of ice-dammed lakes. The most dangerous are lakes formed in main valleys dammed by tributary glaciers. Failure can occur by erosion of a drainage tunnel under or through the ice dam or by a channel over the ice dam. Cold polar-ice dams generally drain supraglacially or marginally by downmelting of an outlet channel. Warmer, temperate-ice dams tend to fail by sudden englacial or subglacial breaching and drainage.Late-neoglacial moraine-dammed lakes are located in steep mountain areas affected by the advances and retreats of valley glaciers in the last several centuries. These late-neoglacial dams pose hazards because (1) they are sufficiently young that vegetation has not stabilized their slopes, (2) many dam faces are steeper than the angle of repose, (3) these dams and lakes are immediately downslope from steep crevassed glaciers and near-vertical rock slopes, and (4) downstream from these dams are steep canyons with easily erodible materials that can be incorporated in the flow and increase flood peaks. The most common reported failure mechanism is overtopping and breaching by a wave or series of waves in the lake generated by icefalls, rockfalls, or snow or rock avalanches. Melting of ice cores or frozen ground and piping and seepage are other possible failure mechanisms.Natural dams may cause upstream flooding as the lake rises and downstream flooding as a result of failure of the dam. Although data are few, for the same potential energy at the dam site, ownstream flood peaks from the failure of glacier-ice dams are smaller than those from landslide, moraine, and structed earth-fill and rock-fill dam failures. Moraine-dam failures appear to produce some of the largest downstream flood peaks for potential energy at the dam site greater than 1011-1012 joules. Differences in flood peaks natural-dam failures appear to be controlled by dam characteristics and failure mechanisms. This content is PDF only. Please click on the PDF icon to access. 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More than half (52%) of the spatial and temporal variance in multidecadal drought frequency over the conterminous United States is attributable to the Pacific Decadal Oscillation (PDO) and the Atlantic Multidecadal Oscillation (AMO). An additional 22% of the variance in drought frequency is related to a complex spatial pattern of positive and negative trends in drought occurrence possibly related to increasing Northern Hemisphere temperatures or some other unidirectional climate trend. Recent droughts with broad impacts over the conterminous U.S. (1996, 1999-2002) were associated with North Atlantic warming (positive AMO) and northeastern and tropical Pacific cooling (negative PDO). Much of the long-term predictability of drought frequency may reside in the multidecadal behavior of the North Atlantic Ocean. Should the current positive AMO (warm North Atlantic) conditions persist into the upcoming decade, we suggest two possible drought scenarios that resemble the continental-scale patterns of the 1930s (positive PDO) and 1950s (negative PDO) drought.

We present new analytical data of major and trace elements for the geological MPI‐DING glasses KL2‐G, ML3B‐G, StHs6/80‐G, GOR128‐G, GOR132‐G, BM90/21‐G, T1‐G, and ATHO‐G. Different analytical methods were used to obtain a large spectrum of major and trace element data, in particular, EPMA, SIMS, LA‐ICPMS, and isotope dilution by TIMS and ICPMS. Altogether, more than 60 qualified geochemical laboratories worldwide contributed to the analyses, allowing us to present new reference and information values and their uncertainties (at 95% confidence level) for up to 74 elements. We complied with the recommendations for the certification of geological reference materials by the International Association of Geoanalysts (IAG). The reference values were derived from the results of 16 independent techniques, including definitive (isotope dilution) and comparative bulk (e.g., INAA, ICPMS, SSMS) and microanalytical (e.g., LA‐ICPMS, SIMS, EPMA) methods. Agreement between two or more independent methods and the use of definitive methods provided traceability to the fullest extent possible. We also present new and recently published data for the isotopic compositions of H, B, Li, O, Ca, Sr, Nd, Hf, and Pb. The results were mainly obtained by high‐precision bulk techniques, such as TIMS and MC‐ICPMS. In addition, LA‐ICPMS and SIMS isotope data of B, Li, and Pb are presented.

Chars originating from the burning or pyrolysis of vegetation may significantly sorb neutral organic contaminants (NOCs). To evaluate the relationship between the char composition and NOC sorption, a series of char samples were generated by pyrolyzing a wheat residue (Triticum aestivum L.) for 6 h at temperatures between 300 degrees C and 700 degrees C and analyzed for their elemental compositions, surface areas, and surface functional groups. The samples were then studied for their abilities to sorb benzene and nitrobenzene from water. A commercial activated carbon was used as a reference carbonaceous sample. The char samples produced at high pyrolytic temperatures (500-700 degrees C) were well carbonized and exhibited a relatively high surface area (>300 m2/g), little organic matter (<3%), and low oxygen content (< or = 10%). By contrast, the chars formed at low temperatures (300-400 degrees C) were only partially carbonized, showing significantly different properties (<200 m2/g surface area, 40-50% organic carbon, and >20% oxygen). The char samples exhibited a significant range of surface acidity/basicity because of their different surface polar-group contents, as characterized by the Boehm titration data and the NMR and FTIR spectra. The NOC sorption by high-temperature chars occurred almost exclusively by surface adsorption on carbonized surfaces, whereas the sorption by low-temperature chars resulted from the surface adsorption and the concurrent smaller partition into the residual organic-matter phase. The chars appeared to have a higher surface affinity for a polar solute (nitrobenzene) than for a nonpolar solute (benzene), the difference being related to the surface acidity/basicity of the char samples.

Effective mean annual precipitation is related to sediment yield from drainage basins throughout the climatic regions of the United States. Sediment yield is a maximum at about 10 to 14 inches of precipitation, decreasing sharply on both sides of this maximum in one case owing to a deficiency of runoff and in the other to increased density of vegetation. Data are presented illustrating the increase in bulk density of vegetation with increased annual precipitation and the relation of relative erosion to vegetative density. It is suggested that the effect of a climatic change on sediment yield depends not only upon direction of climate change, but also on the climate before the change. Sediment concentration in runoff is shown to increase with decreased annual precipitation, suggesting further that a decrease in precipitation will cause stream channel aggradation.

Research Article| May 01, 1985 Devonian eustatic fluctuations in Euramerica J. G. JOHNSON; J. G. JOHNSON 1Department of Geology, Oregon State University, Corvallis, Oregon 97331 Search for other works by this author on: GSW Google Scholar GILBERT KLAPPER; GILBERT KLAPPER 2Department of Geology, University of Iowa, Iowa City, Iowa 52242 Search for other works by this author on: GSW Google Scholar C. A. SANDBERG C. A. SANDBERG 3U.S. Geological Survey, M.S. 940, Federal Center, Denver, Colorado 80225 Search for other works by this author on: GSW Google Scholar GSA Bulletin (1985) 96 (5): 567–587. https://doi.org/10.1130/0016-7606(1985)96<567:DEFIE>2.0.CO;2 Article history first online: 01 Jun 2017 Cite View This Citation Add to Citation Manager Share Icon Share MailTo Twitter LinkedIn Tools Icon Tools Get Permissions Search Site Citation J. G. JOHNSON, GILBERT KLAPPER, C. A. SANDBERG; Devonian eustatic fluctuations in Euramerica. GSA Bulletin 1985;; 96 (5): 567–587. doi: https://doi.org/10.1130/0016-7606(1985)96<567:DEFIE>2.0.CO;2 Download citation file: Ris (Zotero) Refmanager EasyBib Bookends Mendeley Papers EndNote RefWorks BibTex toolbar search Search Dropdown Menu toolbar search search input Search input auto suggest filter your search All ContentBy SocietyGSA Bulletin Search Advanced Search Abstract The Devonian System of Euramerica contains at least 14 transgressive-regressive (T-R) cycles of eustatic origin. These are separated into three groups (or depophases) and from Carboniferous cycles by three prominent regressions. Twelve post-Lochkovian T-R cycles are recognized, and they commonly appear to result from abrupt deepening events followed by prolonged upward shallowing. Deepening events in the western United States (especially Nevada), western Canada, New York, Belgium, and Germany have been dated in the standard conodont zonation and are demonstrably simultaneous in several or all five regions. This synchroneity indicates control by eustatic sea-level fluctuations rather than by local or regional epeirogeny. Facies shifts in shelf sedimentary successions are more reliable indicators of the timing of sea-level fluctuations than are strandline shifts in the cratonic interior, because the latter are more influenced by local epeirogeny. Strandline shifts are most useful in estimating the relative magnitude for sea-level fluctuations.Devonian facies progressions and the three prominent regressions are of a duration and an order of magnitude that could have been caused by episodes of growth and decay of Devonian oceanic ridge systems. The described T-R cycles could have formed in response to mid-plate thermal uplift and submarine volcanism. The latter process may have been a control on small-scale (1–5 m thick), upward-shallowing cycles within the major T-R cycles. Continental glaciation could have been a factor in sea-level fluctuations only in the Famennian and could not have been responsible for the Devonian facies progressions or the numerous T-R cycles.The Frasnian extinctions were apparently cumulative rather than due to a single calamity. Two rapid sea-level rises occurred just before, and one at, the Frasnian-Famennian boundary. It is probable that this series of deepening events reduced the size of shallow-shelf habitats, caused repeated anoxic conditions in basinal areas, and drowned the reef ecosystems that had sustained the immensely diverse Devonian benthos. This content is PDF only. Please click on the PDF icon to access. First Page Preview Close Modal You do not have access to this content, please speak to your institutional administrator if you feel you should have access.

Calcic soils are commonly developed in Quaternary sediments throughout the arid and semiarid parts of the southwestern United States. In alluvial chronosequences, these soils have regional variations in their content of secondary calcium carbonate (CaCO 3) because of (1) the combined effects of the age of the soil, (2) the amount, seasonal distribution, and concentration of Ca ++in rainfall, and (3) the CaCO 3content and net influx of airborne dust, silt, and sand. This study shows that the morphology and amount of secondary CaCO 3(cS) are valuable correlation tools that can also be used to date calcic soils. The structures in calcic soils are clues to their age and dissolution-precipitation history. Two additional stages of carbonate morphology, which are more advanced than the four stages previously described, are commonly formed in middle Pleistocene and older soils. Stage V morphology includes thick laminae and incipient pisolites, whereas Stage VI morphology includes the products of multiple cycles of brecciation, pisolite formation, and wholesale relamination of breccia fragments. Calcic soils that have Stage VI morphology are associated with the late(?) Miocene constructional surface of the Ogallala Formation of eastern New Mexico and western Texas and the early(?) Pliocene Mormon Mesa surface of the Muddy Creek Formation east of Las Vegas, Nevada. Thus, calcic soils can represent millions of years of formation and, in many cases, provide evidence of climatic, sedimentologic, and geologic events not otherwise recorded. The whole-profile secondary CaCO 3content (cS) is a powerful developmental index for calcic soils: cS is defined as the weight of CaCO 3in a 1-cm 2vertical column through the soil (g/cm 2). This value is calculated from the thickness, CaCO 3concentration, and bulk density of calcic horizons in the soil. (See Soil Survey Staff, 1975, p. 45–46, for a complete definition of calcic horizon.) CaCO 3precipitates in the soil through leaching of external Ca ++that is deposited on the surface and in the upper part of the soil, generally in the A and B horizons. The cS content, maximum stage of CaCO 3morphology, and accumulation rate of CaCO 3in calcic soils of equivalent age can vary over large regions of the southwestern United States in response to regional climatic patterns and the influx of Ca ++dissolved in rainwater and solid CaCO 3 Preliminary uranium-trend ages and cS contents for relict soils of the Las Cruces, New Mexico, chronosequence show that 100,000- to 500,000-year-old soils have similar average rates of CaCO 3accumulation. Conversely, soils formed during the past 50,000 years have accumulated CaCO 3about twice as fast, probably because the amount of vegetative cover decreased in the Holocene and, hence, the potential supply of airborne Ca ++and CaCO 3to the soil surface increased. The quantitative soil-development index cS can be used to estimate the age of calcic soils. This index can also be used to correlate soils formed in unconsolidated Quaternary sediments both locally and regionally, to compare rates of secondary CaCO 3accumulation, and to study landscape evolution as it applies to problems such as earthquake hazards and siting of critical facilities.

Abstract Concentrations of naturally occurring arsenic in ground water vary regionally due to a combination of climate and geology. Although slightly less than half of 30,000 arsenic analyses of ground water in the United States were 1 μg/L, about 10% exceeded 10 μg/L. At a broad regional scale, arsenic concentrations exceeding 10 μg/L appear to be more frequently observed in the western United States than in the eastern half. Arsenic concentrations in ground water of the Appalachian Highlands and the Atlantic Plain generally are very low ( 1 μg/L). Concentrations are somewhat greater in the Interior Plains and the Rocky Mountain System. Investigations of ground water in New England, Michigan, Minnesota, South Dakota, Oklahoma, and Wisconsin within the last decade suggest that arsenic concentrations exceeding 10 μg/L are more widespread and common than previously recognized. Arsenic release from iron oxide appears to be the most common cause of widespread arsenic concentrations exceeding 10 μg/L in ground water. This can occur in response to different geochemical conditions, including release of arsenic to ground water through reaction of iron oxide with either natural or anthropogenic (i.e., petroleum products) organic carbon. Iron oxide also can release arsenic to alkaline ground water, such as that found in some felsic volcanic rocks and alkaline aquifers of the western United States. Sulfide minerals are both a source and sink for arsenic. Geothermal water and high evaporation rates also are associated with arsenic concentrations 10g/L in ground and surface water, particularly in the west.

Abstract The Mississippian Barnett Shale serves as source, seal, and reservoir to a world-class unconventional natural-gas accumulation in the Fort Worth basin of north-central Texas. The formation is a lithologically complex interval of low permeability that requires artificial stimulation to produce. At present, production is mainly confined to a limited portion of the northern basin where the Barnett Shale is relatively thick (&amp;gt;300 ft; &amp;gt;92 m), organic rich (present-day total organic carbon &amp;gt; 3.0%), thermally mature (vitrinite reflectance &amp;gt; 1.1%), and enclosed by dense limestone units able to contain induced fractures. The most actively drilled area is Newark East field, currently the largest gas field in Texas. Newark East is 400 mi2 (1036 km2) in extent, with more than 2340 producing wells and about 2.7 tcf of booked gas reserves. Cumulative gas production from Barnett Shale wells through 2003 was about 0.8 tcf. Wells in Newark East field typically produce from depths of 7500 ft (2285 m) at rates ranging from 0.5 to more than 4 mmcf/day. Estimated ultimate recoveries per well range from 0.75 to as high as 7.0 bcf. Efforts to extend the current Barnett play beyond the field limits have encountered several challenges, including westward and northward increases in oil saturation and the absence of lithologic barriers to induced fracture growth. Patterns of oil and gas occurrence in the Barnett, in conjunction with maturation and burial-history data, indicate a complex, multiphased thermal evolution, with episodic expulsion of hydrocarbons and secondary cracking of primary oils to gas in portions of the basin where paleotemperatures were especially elevated. These and other data imply a large-potential Barnett resource for the basin as a whole (possibly &amp;gt;200 tcf gas in place). Recent assessment by the U.S. Geological Survey suggests a mean volume of 26.2 tcf of undiscovered, technically recoverable gas in the central Fort Worth basin. Recovery of a significant portion of this undiscovered resource will require continued improvements in geoscientific characterization and approaches to stimulation of the Barnett reservoirs.

Abstract Concentration–discharge relationships have been widely used as clues to the hydrochemical processes that control runoff chemistry. Here we examine concentration–discharge relationships for solutes produced primarily by mineral weathering in 59 geochemically diverse US catchments. We show that these catchments exhibit nearly chemostatic behaviour; their stream concentrations of weathering products such as Ca, Mg, Na, and Si typically vary by factors of only 3 to 20 while discharge varies by several orders of magnitude. Similar patterns are observed at the inter‐annual time scale. This behaviour implies that solute concentrations in stream water are not determined by simple dilution of a fixed solute flux by a variable flux of water, and that rates of solute production and/or mobilization must be nearly proportional to water fluxes, both on storm and inter‐annual timescales. We compared these catchments' concentration–discharge relationships to the predictions of several simple hydrological and geochemical models. Most of these models can be forced to approximately fit the observed concentration–discharge relationships, but often only by assuming unrealistic or internally inconsistent parameter values. We propose a new model that also fits the data and may be more robust. We suggest possible tests of the new model for future studies. The relative stability of concentration under widely varying discharge may help make aquatic environments habitable. It also implies that fluxes of weathering solutes in streams, and thus fluxes of alkalinity to the oceans, are determined primarily by water fluxes. Thus, hydrology may be a major driver of the ocean‐alkalinity feedback regulating climate change. Copyright © 2009 John Wiley &amp; Sons, Ltd.

Subfossil pollen and plant macrofossil data derived from 14C-dated sediment profiles can provide quantitative information on glacial and interglacial climates. The data allow climate variables related to growing-season warmth, winter cold, and plant-available moisture to be reconstructed. Continental-scale reconstructions have been made for the mid-Holocene (MH, around 6 ka) and Last Glacial Maximum (LGM, around 21 ka), allowing comparison with palaeoclimate simulations currently being carried out as part of the fifth Assessment Report (AR5) of the Intergovernmental Panel on Climate Change. The synthesis of the available MH and LGM climate reconstructions and their uncertainties, obtained using modern-analogue, regression and model-inversion techniques, is presented for four temperature variables and two moisture variables. Reconstructions of the same variables based on surface-pollen assemblages are shown to be accurate and unbiased. Reconstructed LGM and MH climate anomaly patterns are coherent, consistent between variables, and robust with respect to the choice of technique. They support a conceptual model of the controls of Late Quaternary climate change whereby the first-order effects of orbital variations and greenhouse forcing on the seasonal cycle of temperature are predictably modified by responses of the atmospheric circulation and surface energy balance.