Honeywell (Romania)

A new D–π–A dye based on dihexyloxy-substituted triphenylamine moiety has been synthesized and its preliminary performances in DSSCs are reported.

In this paper, we report on the structural, optical, and electrical properties of a wide compositional range of AlxIn1−xN thin layers deposited on glass and polyethylene terephthalate substrates. AlxIn1−xN layers of controlled composition were obtained by a simple reactive magnetron co-sputtering protocol, using a single aluminium target with indium insets, by varying the Al/In target surface area ratio, and the composition of the deposition atmosphere. The relevant physical properties were investigated and discussed. It is shown that the texture of the thin films is dependent on the cation ratio, while the bowing parameters of lattice constants and band gap values are larger than those of epitaxial layers.

Abstract Background The honey bee (Apis mellifera) is an ecologically and economically important species that provides pollination services to natural and agricultural systems. The biodiversity of the honey bee in parts of its native range is endangered by migratory beekeeping and commercial breeding. In consequence, some honey bee populations that are well adapted to the local environment are threatened with extinction. A crucial step for the protection of honey bee biodiversity is reliable differentiation between native and nonnative bees. One of the methods that can be used for this is the geometric morphometrics of wings. This method is fast, is low cost, and does not require expensive equipment. Therefore, it can be easily used by both scientists and beekeepers. However, wing geometric morphometrics is challenging due to the lack of reference data that can be reliably used for comparisons between different geographic regions. Findings Here, we provide an unprecedented collection of 26,481 honey bee wing images representing 1,725 samples from 13 European countries. The wing images are accompanied by the coordinates of 19 landmarks and the geographic coordinates of the sampling locations. We present an R script that describes the workflow for analyzing the data and identifying an unknown sample. We compared the data with available reference samples for lineage and found general agreement with them. Conclusions The extensive collection of wing images available on the Zenodo website can be used to identify the geographic origin of unknown samples and therefore assist in the monitoring and conservation of honey bee biodiversity in Europe.

This paper introduces the Hard Soft Acid Base (HSAB) concept as a promising tool for the selection of gas sensing layers. Target gas molecule - sensitive layer tandems are discussed and interpreted in the terms of this theory. Sensing layers suitable for carbon dioxide, nitrogen dioxide, sulphur dioxide, and hydrogen sulphide detection are presented and classified according to this concept. For oxygen and mineral acids detection, an indirect HSAB approach is discussed. The paper explains how the HSAB principle can be useful in designing gas sensing layers for different types of sensing structures, such as: surface acoustic waves (SAW), colorimetric, chemoresistive, etc.

Damping effects are very important in MEMS-based sensors and actuators. In this paper we use analytical models and finite element (FE) computations to quantify the energy losses due to viscous fluid damping, acoustic radiation and thermo-elastic damping. To treat the case where squeeze/slide film models can not be applied, we have implemented in a commercial FE package a new incompressible flow solver based on a gauge formulation. We are thus able to solve for full flows around complex 3D geometries in the frequency domain and predict viscous damping of resonant MEMS structures. The full methodology is exemplified on the response of a MEMS silicon resonator, including acoustic driving and piezoelectric sensing.

The current paper reports on a sonochemical synthesis method for manufacturing nanostructured (typical grain size of 50 nm) SrTi0.6Fe0.4O2.8 (Sono-STFO40) powder. This powder is characterized using X ray-diffraction (XRD), Mössbauer spectroscopy and Scanning Electron Microscopy (SEM), and results are compared with commercially available SrTi0.4Fe0.6O2.8 (STFO60) powder. In order to manufacture resistive oxygen sensors, both Sono-STFO40 and STFO60 are deposited, by dip-pen nanolithography (DPN) method, on an SOI (Silicon-on-Insulator) micro-hotplate, employing a tungsten heater embedded within a dielectric membrane. Oxygen detection tests are performed in both dry (RH = 0%) and humid (RH = 60%) nitrogen atmosphere, varying oxygen concentrations between 1% and 16% (v/v), at a constant heater temperature of 650 °C. The oxygen sensor, based on the Sono-STFO40 sensing layer, shows good sensitivity, low power consumption (80 mW), and short response time (25 s). These performance are comparable to those exhibited by state-of-the-art O2 sensors based on STFO60, thus proving Sono-STFO40 to be a material suitable for oxygen detection in harsh environments.

Since mid 60s, Surface Acoustic Wave (SAW) devices have been using extensively in electronics for telecommunication. However, their potential use in the sensors field is only a matter of recent interest. This paper presents an overview of the sensing mechanisms that allow detection of temperature, strain (for pressure & torque), mass, conductivity (e.g. gas detection) and viscosity by means of SAW based devices. Design and technological challenges are presented, as well as solutions to overcome them in order to obtain reliable devices. The possibility of using such devices as passive wireless sensors is also discussed.

This paper reviews and addresses certain aspects of Silicon-On-Insulator (SOI) technologies for a harsh environment. The paper first describes the need for specialized sensors in applications such as (i) domestic and other small-scale boilers, (ii) CO <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> Capture and Sequestration, (iii) oil & gas storage and transportation, and (iv) automotive. We describe in brief the advantages and special features of SOI technology for sensing applications requiring temperatures in excess of the typical bulk silicon junction temperatures of 150 <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">o</sup> C. Finally we present the concepts, structures and prototypes of simple and smart micro-hotplate and Infra Red (IR) based emitters for NDIR (Non Dispersive IR) gas sensors in harsh environments.

The Hard Soft Acid Base (HSAB) theory is introduced as a new tool to select or design sensitive materials for carbon dioxide detection with SAW-BAW (Surface Acoustic Waves - Bulk Acoustic Waves) devices. According to HSAB, CO <inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</inf> is hard acid, thus small organic or inorganic molecules, or polymers which can act as hard bases could be suitable candidates as sensing layers for carbon dioxide detection. As a consequence of this theory, we propose the following polymers as potential candidates for CO <inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</inf> sensing: simple polyallylamine, N-substituted polyallylamine, polydiallylamine and polyvinylamine, and mixtures of these polymers. The SAW device coated with one of the selected polymers, polyallyamine, shows good sensitivity for CO <inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</inf> concentration (in the range 500–5000 ppm), long term stability and repeatability.

Synthesis of a new type of calixarene-doped polyaniline (PANI) is reported. Polyaniline as a free base (emeraldine) was synthesized by a chemical method, in the presence of HCl and ammonium peroxodisulphate as oxidant. PANI was doped with p-sulfonatocalix|4|arene. The structure of the protonic acid doped- PANI was investigated by infrared and UV-VIS spectroscopies. The spectral features of dopant are found in the doped polyaniline. The synthesized polyaniline exhibits enhanced solubility in dimethyl for mamide and N-methyl pyrrolidon, which is useful for sensing

The synthesis of two new types of nanocomposite matrices, the first based on polyallylamine (PAA) and aminocarbon nanotubes, the second on polyethyleneimine (PEI) and aminocarbon nanotubes, are reported. The surface acoustic wave (SAW) sensors, coated with the two selected nanocomposites, showed good sensitivities when varying the CO <inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</inf> concentrations in the range (500–5000)ppm. The sensor sensitivity is larger when using polyethyleneimine aminocarbon nanotubes than in the case when only a pure polyethyleneimine layer is considered for coating.

Waveguides in photonic crystal slabs (PCS) can be obtained by omitting a row of holes (Wl-waveguides). In general the propagation properties in such waveguides suffer from the unavoidable periodic sidewall corrugation caused by the remaining parts of the crystal. The corrugation acts as a Bragg reflector, causing the occurrence of so-called mini stopbands in the transmission of the waveguide. The effect is quite strong in PCS with circular holes, but it can be significantly reduced if correctly oriented hexagonal holes are used. This so-called hexagon-type PCS allows the design of waveguides, bends and splitters having a relatively high group velocity and a wide transmission window in the PCS stopband for modes having their magnetic field oriented mainly perpendicular to the slab.

Within this paper we present a thermodynamic methodology for the selection of non-toxic metals which could be used as lead-free consumable anodes in electrochemical galvanic oxygen sensors. Starting from thermodynamic nobility theory, metals like copper, bismuth or antimony are proposed to replace lead in future galvanic O <inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</inf> sensors. The thermodynamic theory provides voltage windows which increase from copper (0.7 V), to bismuth (0.857 V) and antimony (1.076 V). The experimental voltage windows are smaller than the theoretical ones, but these experimental values increase in the same order from Cu, to Bi and Sb, as predicted by our methodology.

In this paper, we report the realization and characterization of a condensation sensor based on indium nitride (InN) layers deposited by magnetron sputtering on glass and flexible plastic substrates, having fast response and using potentially low cost fabrication technology. The InN devices work as open gate thin film sensitive transistors. Condensed water droplets, formed on the open gate region of the sensors, deplete the electron accumulation layer on the surface of InN film, thus decreasing the current of the sensor. The current increases back to its initial value when water droplets evaporate from the exposed InN film surface. The response time is as low as 2 s.

This paper reports on the experimental realization and characterization of a wireless sensing system for machine-tool condition based monitoring. The system comprises a vibration sensor, an ARDUINO Leonardo development board and an RM 42 Blue tooth module. The sensing principle is based on a vibration sensor which includes a piezoelectric AlN layer deposited by sputtering on a flexible stainless steel foil. The functional testing of the sensor using a test stand for asynchronous engines equipped with frequency convertors is demonstrated.

Hard Soft Acid Base (HSAB) theory is introduced as a new tool to select ligands (molecules) for quantum dot covalent functionalization. According to HSAB, only soft acid-soft base bond is covalent. Since most of the transition metal semiconductor cations on the surface of the quantum dots are soft acids, the approach we propose is to select anchors which are soft bases. Following this strategy, the suitable anchors for surface modification of the quantum dots are selected. Moreover, a plethora of bifunctional ligands for assembling quantum dots onto the surface of titania are identified among the existing molecules. The functionalization of a semiconducting organic polymer backbone with HSAB-adequate anchors for the design of polymer-quantum dot hybrid interface is presented. In addition, our new approach coherently explains the heuristic approaches described in the literature.

Two CO <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> sensing mechanisms, based on the Hard Soft Acids Bases (HSAB) and Bronsted-Lowry theories, are discussed and compared. They are evaluated by selecting amino groups-based coating layers, which are deposited on Surface Acoustic Wave (SAW) devices for CO <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> detection. Experimentally measured CO <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> sensitivities of different coating layers, such as polyallylamine (PAA), polyethyleneimine (PEI), nanocomposite matrix based on PAA-aminocarbon nanotubes and PEI-aminocarbon nanotubes, emeraldine, 4-sulfocalix[4]arene-doped polyaniline, matrix based emeraldine and carbonic anhydrase (PACA) are compared and evaluated according to their corresponding sensing mechanism.

The synthesis of pyrene-1-butyric acid (PBA)-doped polyaniline (PANI) and its oxygen sensing properties, through fluorescence quenching, are reported. The structures of both undoped PANI (emeraldine) and PBA-doped PANI are investigated by means of Fourier Transform InfraRed (FT-IR) spectroscopy. The O <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> sensing capability of the synthesized layer is demonstrated through fluorescence spectroscopy performed at different air pressure values. PBA-doped PANI is expected to lead to a fluorophore with better stability and reliability than free PBA. This could bring real benefits to the overall functioning of industrial O2 sensors based on fluorescence quenching.

In this work we present an experimental study of the lifetime of O <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> galvanic sensors in KOH aqueous solution, considering bismuth, copper and antimony as the candidates for lead anode replacement in present devices. An initial accelerated ageing test in 100% O <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> suggested antimony for the next stage. Further experiments have shown an accelerated ageing factor of 18, which allowed the estimation of a lifetime of more than five years for an O <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> galvanic sensor based on Sb anode of large surface area. A scaling law in lifetime as a function surface area (or anode current density) was found, which agreed with electrochemical passivation studies of Sb in alkaline solutions.

It is the purpose of this paper to present a novel generic concept for low drift chemical sensing which is applicable at micro and nanometer scale, based on a new, all-differential approach. At micrometer level, our principle is explained by means of surface acoustic wave (SAW) chemical sensing, while at nano level, we are using the resonant sensing principle to develop our genuine differential concept. Unlike the traditional differential approaches based on functionalized sensing layer in the sensing loop, and on a uncoated surface in the reference loop, our all differential concept provides a better response subtraction between the two paths, as the sensing loop consists of a functionalized sensing layer, as before, but, the reference loop consists of a functionalized non-sensing layer, with the same ageing and humidity behavior as the sensing layer. Twinned electronic reading is used for both loops, and thus all the common mode signals are subtracted in the differential reading, assuring the minimum base line drift of the sensor. Preliminary results of all differential sensor response to humidity and temperature variations are shown for the SAW sensors, with the sensor signal kept independent of their changes.