Joint Research Centre

We present the results from a survey of i-dropout objects selected from ~1550 deg^2 of multicolor imaging data from the Sloan Digital Sky Survey, to search for luminous quasars at z>5.8. Objects with i*-z*>2.2 and z*<20.2 are selected, and follow-up J band photometry is used to separate L and T type cool dwarfs from high-redshift quasars. We describe the discovery of three new quasars, at z=5.82, 5.99 and 6.28, respectively. Their spectra show strong and broad Ly alpha+NV emission lines, and very strong Ly alpha absorption, with a mean continuum decrement D_A > 0.90. The ARC 3.5m spectrum of the z=6.28 quasar shows that over a range of 300 A immediately blueward of the Ly alpha emission, the average transmitted flux is only 0.003 +/-0.020 times that of the continuum level, consistent with zero flux, and suggesting a tentative detection of the complete Gunn-Peterson trough. The existence of strong metal lines suggests early chemical enrichment in the quasar enviornment. The three new objects, together with the previously published z=5.8 quasar form a complete color-selected flux-limited sample at z>5.8. We estimate that at $z=6$, the comoving density of luminous quasars at M_1450 < -26.89 (h=0.5, Omega=1)is 1.1x10^-9 Mpc^-3. This is a factor of ~2 lower than that at z~5, and is consistent with an extrapolation of the observed quasar evolution at low-z. We discuss the contribution of quasars to the ionizing background at z~6. The luminous quasars discussed in the paper have central black hole masses of several times 10^9 M_sun by the Eddington argument. Their observed space density provides a sensitive test of models of quasar and galaxy formation at high redshift. (Abridged)

• A carbon utilisation plant that synthesise methanol is simulated in CHEMCAD. • The total amount of CO 2 demand is 1.46 t/t methanol . • The CO 2 not-produced compared to a conventional plant is 0.54 t/t methanol . • Production costs results too high for a financially attractive project. • There is a net potential for CO 2 emissions reduction of 2.71 MtCO 2 /yr in Europe. The purpose of this paper is to assess via techno-economic and environmental metrics the production of methanol (MeOH) using H 2 and captured CO 2 as raw materials. It evaluates the potential of this type of carbon capture and utilisation (CCU) plant on (i) the net reduction of CO 2 emissions and (ii) the cost of production, in comparison with the conventional synthesis process of MeOH Europe. Process flow modelling is used to estimate the operational performance and the total purchased equipment cost; the flowsheet is implemented in CHEMCAD, and the obtained mass and energy flows are utilised as input to calculate the selected key performance indicators (KPIs). CO 2 -based metrics are used to assess the environmental impact. The evaluated MeOH plant produces 440 ktMeOH/yr, and its configuration is the result of a heat integration process. Its specific capital cost is lower than for conventional plants. However, raw materials prices, i.e. H 2 and captured CO 2 , do not allow such a project to be financially viable. In order to make the CCU plant financially attractive, the price of MeOH should increase in a factor of almost 2, or H 2 costs should decrease almost 2.5 times, or CO 2 should have a value of around 222 €/t, under the assumptions of this work. The MeOH CCU-plant studied can utilise about 21.5% of the CO 2 emissions of a pulverised coal (PC) power plant that produces 550 MW net of electricity. The net CO 2 emissions savings represent 8% of the emissions of the PC plant (mainly due to the avoidance of consuming fossil fuels as in the conventional MeOH synthesis process). The results demonstrate that there is a net but small potential for CO 2 emissions reduction; assuming that such CCU plants are constructed in Europe to meet the MeOH demand growth and the quantities that are currently imported, the net CO 2 emissions reduction could be of 2.71 MtCO 2 /yr.

Electrochemical impedance spectroscopy (EIS) is a widely applied non-destructive method of characterisation of Li-ion batteries. Despite its ease of application, there are inherent challenges in ensuring the quality and reproducibility of the measurement, as well as reliable interpretation and validation of impedance data. Here, we present a focus review summarising best metrological practice in the application of EIS to commercial Li-ion cells. State-of-the-art methods of EIS interpretation and validation are also reported and examined to highlight the benefits and drawbacks of the technique.

Submillimetre Common-User Bolometer Array 2 (SCUBA-2) is an innovative 10 000 pixel bolometer camera operating at submillimetre wavelengths on the James Clerk Maxwell Telescope (JCMT). The camera has the capability to carry out wide-field surveys to unprecedented depths, addressing key questions relating to the origins of galaxies, stars and planets. With two imaging arrays working simultaneously in the atmospheric windows at 450 and 850 m, the vast increase in pixel count means that SCUBA-2 maps the sky 100-150 times faster than the previous SCUBA instrument. In this paper, we present an overview of the instrument, discuss the physical characteristics of the superconducting detector arrays, outline the observing modes and data acquisition, and present the early performance figures on the telescope. We also showcase the capabilities of the instrument via some early examples of the science SCUBA-2 that have already been undertaken. In 2012 February, SCUBA-2 began a series of unique legacy surveys for the JCMT community. These surveys will take 2.5 yr and the results are already providing complementary data to the shorter wavelength, shallower, larger area surveys

The increasing ambition of climate targets creates a major role for hydrogen especially in achieving carbon-neutrality in sectors presently difficult to decarbonise. This work examines to what extent the currently carbon-intensive hydrogen production in Europe could be replaced by water electrolysis using electricity from renewable energy resources (RES) such as solar photovoltaic, onshore/offshore wind and hydropower (green hydrogen). The study assesses the technical potential of RES at regional and national levels considering environmental constraints, land use limitations and various techno-economic parameters. It estimates localised clean hydrogen production and examines the capacity to replace carbon-intensive hydrogen hubs with ones that use RES-based water electrolysis. Findings reveal that -at national level- the available RES electricity potential exceeds the total electricity demand and the part for hydrogen production from electrolysis in all analysed countries. At regional level, from the 109 regions associated with hydrogen production (EU27 and UK), 88 regions (81%) show an excess of potential RES generation after covering the annual electricity demand across all sectors and hydrogen production. Notably, 84 regions have over 50% excess RES electricity potential after covering the total electricity demand and that for water electrolysis. The study provides evidence on the option to decarbonize hydrogen production at regional level. It shows that such transformation is possible and compatible with the ongoing transition towards carbon–neutral power systems in the EU. Overall, this work aims to serve as a tool for designing hydrogen strategies in harmony with renewable energy policies.

Lithium ion batteries are a proven technology for automotive applications and their continued use in the future electric vehicle fleet is undeniable. In addition to battery performance and durability, battery safety is paramount to ensure confidence and widespread adoption of electromobility in our society. This comprehensive review aims at presenting the various international standards and regulations for safety testing of lithium ion batteries in automotive applications under various abusive environments. Safety tests are presented and analysed including mechanical, electrical, environmental and hazards of chemical nature. The intention of this review is compiling the most relevant standards and regulations to identify shortcomings and areas for future improvement.

The oceans of the earth offer vast amounts of renewable energy. Technologies to harness the power of the seas are at an early stage of development. Even the most advances technologies, namely tidal current and ocean wave still face considerable barriers and many obstacles remain. Research, development and innovation can help overcome those barriers. This review provides an overview over the current state of research in the field of ocean energy. In particular, the authors focus on research beyond technology or technological improvements. This article also highlights areas where research gaps exists and where future research efforts should be directed to.

We discuss measurements of the properties of about 10,000 asteroids detected in 500 deg2 of sky in the Sloan Digital Sky Survey (SDSS) commissioning data. The moving objects are detected in the magnitude range 14 < r < 21.5, with a baseline of 5 minutes. Extensive tests show that the sample is at least 98% complete, with the contamination rate of less than 3%. We find that the size distribution of asteroids resembles a broken power-law, independent of the heliocentric distance: D^{-2.3} for 0.4 km < D < 5 km, and D^{-4} for 5 km < D < 40 km. As a consequence of this break, the number of asteroids with r < 21.5 is ten times smaller than predicted by extrapolating the power-law relation observed for brighter asteroids (r < 18). The observed counts imply that there are about 530,000 objects with D>1 km in the asteroid belt, or about four times less than previous estimates. The distribution of main belt asteroids in the 4-dimensional SDSS color space is bimodal, and the two groups can be associated with S (rocky) and C (carbonaceous) asteroids. A strong bimodality is also seen in the heliocentric distribution of asteroids and suggests the existence of two distinct belts: the inner rocky belt, about 1 AU wide (FWHM) and centered at R~2.8 AU, and the outer carbonaceous belt, about 0.5 AU wide and centered at R~3.2 AU. The colors of Hungarias, Mars crossers, and near-Earth objects are more similar to the C-type than to S-type asteroids, suggesting that they originate in the outer belt. (abridged).

We present maps, source catalogue and number counts of the largest, most complete and unbiased extragalactic submillimetre survey: the 850-m

Approximately 10% of active galactic nuclei exhibit relativistic jets, which are powered by the accretion of matter onto supermassive black holes. Although the measured width profiles of such jets on large scales agree with theories of magnetic collimation, the predicted structure on accretion disk scales at the jet launch point has not been detected. We report radio interferometry observations, at a wavelength of 1.3 millimeters, of the elliptical galaxy M87 that spatially resolve the base of the jet in this source. The derived size of 5.5 ± 0.4 Schwarzschild radii is significantly smaller than the innermost edge of a retrograde accretion disk, suggesting that the M87 jet is powered by an accretion disk in a prograde orbit around a spinning black hole.

Variable x-ray and γ-ray emission is characteristic of the most extreme physical processes in the universe. We present multiwavelength observations of a unique γ-ray-selected transient detected by the Swift satellite, accompanied by bright emission across the electromagnetic spectrum, and whose properties are unlike any previously observed source. We pinpoint the event to the center of a small, star-forming galaxy at redshift z = 0.3534. Its high-energy emission has lasted much longer than any γ-ray burst, whereas its peak luminosity was ∼100 times higher than bright active galactic nuclei. The association of the outburst with the center of its host galaxy suggests that this phenomenon has its origin in a rare mechanism involving the massive black hole in the nucleus of that galaxy.

Energy policy often builds on insights gained from quantitative energy models and their underlying data. As climate change mitigation and economic concerns drive a sustained transformation of the energy sector, transparent and well-founded analyses are more important than ever. We assert that models and their associated data must be openly available to facilitate higher quality science, greater productivity through less duplicated effort, and a more effective science-policy boundary. There are also valid reasons why data and code are not open: ethical and security concerns, unwanted exposure, additional workload, and institutional or personal inertia. Overall, energy policy research ostensibly lags behind other fields in promoting more open and reproducible science. We take stock of the status quo and propose actionable steps forward for the energy research community to ensure that it can better engage with decision-makers and continues to deliver robust policy advice in a transparent and reproducible way.

Ocean energy has the potential to play a significant role in the future energy system, whilst contributing to the reduction of carbon emissions and stimulating economic growth in coastal and remote areas. Ocean energy has attracted increasing interest, particularly in the EU, which is currently at the forefront of ocean energy development. \n\nTidal and Wave energy represents the two most advance types of ocean energy technologies. In the EU, the aim is to reach 100 GW of combined wave and tidal capacity installed by 2050. In order to achieve these targets the sector needs to overcome a series of challenges and barriers with regards to technology readiness, financing and market establishment, administrative and environmental issues and the availability of grid connections especially in remote areas. Currently these barriers are hindering the sector's progress; its ability to attract inwards investments and to engage with the supply chain to unlock cost-reduction mechanisms. A number of policy initiatives and mechanisms have been put in place to ensure that ocean energy technologies could become cost-competitive in the short term, in order to exploit the benefits that these technologies could provide to the EU.

We present ZJHKL'M' photometry of a sample of 58 late-M, L, and T dwarfs, most of which are identified from the Sloan Digital Sky Survey and the Two Micron All-Sky Survey. Near-infrared spectra and spectral classifications for most of this sample are presented in a companion paper by Geballe et al. We derive the luminosities of 18 dwarfs in the sample and the results imply that the effective temperature range for the L dwarfs in our sample is approximately 2200-1300 K and for the T dwarfs 1300-800 K. We obtained new photometric data at the United Kingdom Infrared Telescope for: 42 dwarfs at Z, 34 dwarfs at JHK, 21 dwarfs at L', as well as M' data for two L dwarfs and two T dwarfs. The M' data provide the first accurate photometry for L and T dwarfs in this bandpass - for a T2 and a T5 dwarf, we find K-M'=1.2 and 1.6, respectively. These colors are much bluer than predicted by models suggesting that CO may be more abundant in these objects than expected, as has been found for the T6 dwarf Gl 229B. We also find that K-L' increases monotonically through most of the M, L, and T subclasses, but it is almost constant between types L6 and T5. The degeneracy is probably due to the onset of methane absorption at the blue edge of the L' bandpass. The JHK colors of L dwarfs show significant scatter, suggesting that the fluxes in these bandpasses are sensitive to variations in photospheric dust properties. The H-K colors of the later T dwarfs also show some scatter which we suggest is due to variations in pressure-induced molecular hydrogen opacity, which is sensitive to gravity and metallicity.

Abstract Six satellite-based rainfall estimates (SRFE)—namely, Climate Prediction Center (CPC) morphing technique (CMORPH), the Rainfall Estimation Algorithm, version 2 (RFE2.0), Tropical Rainfall Measuring Mission (TRMM) 3B42, Goddard profiling algorithm, version 6 (GPROF 6.0), Precipitation Estimation from Remotely Sensed Information using Artificial Neural Networks (PERSIANN), Global Satellite Mapping of Precipitation moving vector with Kalman filter (GSMap MVK), and one reanalysis product [the interim ECMWF Re-Analysis (ERA-Interim)]—were validated against 205 rain gauge stations over four African river basins (Zambezi, Volta, Juba–Shabelle, and Baro–Akobo). Validation focused on rainfall characteristics relevant to hydrological applications, such as annual catchment totals, spatial distribution patterns, seasonality, number of rainy days per year, and timing and volume of heavy rainfall events. Validation was done at three spatially aggregated levels: point-to-pixel, subcatchment, and river basin for the period 2003–06. Performance of satellite-based rainfall estimation (SRFE) was assessed using standard statistical methods and visual inspection. SRFE showed 1) accuracy in reproducing precipitation on a monthly basis during the dry season, 2) an ability to replicate bimodal precipitation patterns, 3) superior performance over the tropical wet and dry zone than over semiarid or mountainous regions, 4) increasing uncertainty in the estimation of higher-end percentiles of daily precipitation, 5) low accuracy in detecting heavy rainfall events over semiarid areas, 6) general underestimation of heavy rainfall events, and 7) overestimation of number of rainy days in the tropics. In respect to SRFE performance, GPROF 6.0 and GSMaP-MKV were the least accurate, and RFE 2.0 and TRMM 3B42 were the most accurate. These results allow discrimination between the available products and the reduction of potential errors caused by selecting a product that is not suitable for particular morphoclimatic conditions. For hydrometeorological applications, results support the use of a performance-based merged product that combines the strength of multiple SRFEs.

The EU’s 2018 Bioeconomy Strategy Update and the European Green Deal recently confirmed that the bioeconomy is high on the political agenda in Europe. Here, we propose a conceptual analysis framework for quantifying and analyzing the development of the EU bioeconomy. The bioeconomy has several related concepts (e.g., bio-based economy, green economy, and circular economy) and there are clear synergies between these concepts, especially between the bioeconomy and circular economy concepts. Analyzing the driving factors provides important information for monitoring activities. We first derive the scope of the bioeconomy framework in terms of bioeconomy sectors and products to be involved, the needed geographical coverage and resolution, and time period. Furthermore, we outline a set of indicators linked to the objectives of the EU’s bioeconomy strategy. In our framework, measuring developments will, in particular, focus on the bio-based sectors within the bioeconomy as biomass and food production is already monitored. The selected indicators commit to the EU Bioeconomy Strategy objectives and conform with findings from previous studies and stakeholder consultation. Additionally, several new indicators have been suggested and they are related to measuring the impact of changes in supply, demand drivers, resource availability, and policies on sustainability goals.

The ever-increasing concentration of people and economic growth in the largest cities relative to the rest of the country has slowed down or even reversed in many of the developed European countries over the last decade. This trend contradicts what the global cities, urban economics and new economic geography literature would predict. This trend can be interpreted from two points of view: (1) the trend is due to large obstacles to further large city urbanization and thus is inefficient or (2) this trend highlights alternative pathways to growth than the mega-city approach and may be as, if not more, efficient. This trend may be linked to Europe's uniquely polycentric urban structure with high number of small- and medium-sized cities. In addition, improvements in the access to services, including broadband, outside large cities may have facilitated the higher growth rates of smaller centres and rural regions and increased their appeal for residents and firms. Last but not least, negative externalities in the large cities, such as congestion costs, pollution, labour crowding and high cost of living, may increase the appeal of smaller centres and rural regions.

The future of carbon dioxide utilisation (CDU) processes, depend on (i) the future demand of synthesised products with CO2, (ii) the availability of captured and anthropogenic CO2, (iii) the overall CO2 not emitted because of the use of the CDU process, and (iv) the economics of the plant. The current work analyses the mentioned statements through different technological, economic and environmental key performance indicators to produce formic acid from CO2, along with their potential use and penetration in the European context. Formic acid is a well-known chemical that has potential as hydrogen carrier and as fuel for fuel cells. This work utilises process flow modelling, with simulations developed in CHEMCAD, to obtain the energy and mass balances, and the purchase equipment cost of the formic acid plant. Through a financial analysis, with the net present value as selected metric, the price of the tonne of formic acid and of CO2 are varied to make the CDU project financially feasible. According to our research, the process saves CO2 emissions when compared to its corresponding conventional process, under specific conditions. The success or effectiveness of the CDU process will also depend on other technologies and/or developments, like the availability of renewable electricity and steam.

We present extensive observations of a sample of distant, submillimetre (submm) galaxies detected in the field of the massive cluster lens Abell 1835, using the Submm Common-User Bolometer Array (SCUBA). Taken in conjunction with earlier observations of other submmselected sources, we now have detailed, multiwavelength observations of seven examples of the submm population, having exploited the combination of achromatic amplification by cluster lenses and lavish archival data sets. These sources, all clearly at z * 1Y illustrate the wide range in the radio and optical properties of distant submm-selected galaxies. We include detailed observations of the first candidate `pure' starburst submm galaxy at high redshift, a z 2X56 interacting galaxy which shows no obvious sign of hosting an AGN. The remaining sources have varying degrees of inferred AGN activity (three out of seven of the most luminous show some evidence of the presence of an AGN), although even when an AGN is obviously present it is still not apparent whether reprocessed radiation from this source dominates the submm emission. In contrast with the variation in the spectral properties, we see relatively homogeneous morphologies for the population, with a large fraction of merging or interacting systems. Our study shows that virtually identical spectral energy distributions are seen for galaxies that exhibit strikingly different optical/UV spectral-line characteristics. We conclude that standard optical/UV spectral classifications are misleading when applied to distant, highly obscured galaxies, and that we must seek other means of determining the various contributions to the overall energy budget of submm galaxies and hence to the far-infrared extragalactic background.

Traction batteries are a key factor in the environmental sustainability of electric mobility and, therefore, it is necessary to evaluate their environmental performance to allow a comprehensive sustainability assessment of electric mobility. This article presents an environmental assessment of a lithium-ion traction battery for plug-in hybrid electric vehicles, characterized by a composite cathode material of lithium manganese oxide (LiMn2O4) and lithium nickel manganese cobalt oxide Li(NixCoyMn1-x-y)O2. Composite cathode material is an emerging technology that promises to combine the merits of several active materials into a hybrid electrode to optimize performance and reduce costs. In this study, the environmental assessment of one battery pack (with a nominal capacity of 11.4 kWh able to be used for about 140,000 km of driving) is carried out by using the Life Cycle Assessment methodology consistent with ISO 14040. The system boundaries are the battery production, the operation phase and recycling at the end of life, including the recovery of various material fractions. The composite cathode technology examined besides a good compromise between the higher and the lower performance of NMC and LMO cathodes, can present good environmental performances. The results of the analysis show that the manufacturing phase is relevant to all assessed impact categories (contribution higher than 60%). With regard to electricity losses due to battery efficiency and battery transport, the contribution to the use phase impact of battery efficiency is larger than that of battery transport. Recycling the battery pack contributes less than 11% to all of the assessed impact categories, with the exception of freshwater ecotoxicity (60% of the life cycle impact). The environmental credits related to the recovery of valuable materials (e.g. cobalt and nickel sulphates) and other metal fractions (e.g. aluminium and steel) are particularly relevant to impact categories such as marine eutrophication, human toxicity and abiotic resource depletion. The main innovations of this article are that (1) it presents the first bill of materials of a lithium-ion battery cell for plug-in hybrid electric vehicles with a composite cathode active material; (2) it describes one of the first applications of the life cycle assessment to a lithium-ion battery pack for plug-in hybrid electric vehicles with a composite cathode active material with the aim of identifying the “hot spots” of this technology and providing useful information to battery manufacturers on potentially improving its environmental sustainability; (3) it evaluates the impacts associated with the use phase based on primary data about the battery pack's lifetime, in terms of kilometres driven; and (4) it models the end-of-life phase of the battery components through processes specifically created for or adapted to the case study.