Laboratoire de Chimie Agro-Industrielle

The authors discuss high-voltage power conversion. Conventional series connection and three-level voltage source inverter techniques are reviewed and compared. A novel versatile multilevel commutation cell is introduced: it is shown that this topology is safer and more simple to control, and delivers purer output waveforms. The authors show how this technique can be applied to either choppers or voltage-source inverters and generalized to any number of switches.< <ETX xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">&gt;</ETX>

Agriculture and farming have a long history. Agriculture is the main economic structure for many developed and developing countries. The modern agricultural practices affect the environment namely nutrient cycle, soil erosion, carbon sequestration, and many other ecological patterns. Organic farming is influential practice to minimize the environmental and ecological impact of sustainable development. Usage of more organic matters in agricultural practices can reduce the adverse effects on the environment by keep saving its natural cycles on recovery process and organic farming may enhance the food quality too. The organic farming may largely exclude the usage of chemical fertilizers, pesticides, growth hormones and feed additives of livestock activities. A combination of organic farming and new technologies is of utmost importance to reduce the limitations and challenges of organic farming. The innovative methods and new approaches making new trends toward sustainability farming system and enhances the agricultural productivity, and quality of life of many farmers in an environmentally friendly way. In other words, organic farming mirrors the sustainability concepts of Global Agriculture.

SummaryIn the field of High Voltage Power Conversion, the circuit designer is often confromed to a serious problem: there arc no semiconductors capable of sustaining the desired voltage (traction applications for example). The first solution inovolves plain series connection of several switches with synchronous cotrol signals, thus obtaining the equivalent of a high voltage switch. Static and dynamic balancing of the voltage across the switches requires all the semiconductors to switch exactly at the same time: this requires selecting semiconductors with the same turn-on and turn-off times or using control strategies Capable of compensating the difference in switching time. In other respects, the output dV/dt at each commumtion is the sum of the dV/dt genceratd by each switch, which is a serious stress for the environment and especially the firing circuits! The technique presented in this paper tolerates semiconductors switching at different times, thus allowing high voltage conversion with standard dV/dr (Fig. 1.a). More, it will be shown that the control signals can be significantly phase-shifted to improve the harmonic spectrum or the output voltage (Fig. 1 .b).

In this paper, the imbricated cells multilevel converters are studied and modeled from a control viewpoint. These converters make use of several switches connected in a series, which allows using switches with reduced voltage ratings; these low voltage switches have lower conduction losses and can switch at higher frequency. In addition to this feature common to all converters using series connected switches, the control signals of multilevel converters can be phase shifted to increase the apparent switching frequency and improve the dynamic performances of the whole converter. It is shown that a multilevel inverter leg, composed of p pairs of switches and p-1 capacitors, forms a multivariable nonlinear system that cannot be properly modeled by standard methods such as state-space averaging. The transient behavior of this system depends on the current harmonics and their phase shift with the different control signals. A specific model is detailed, studied, and used to illustrate the properties of these converters. In particular, the natural balancing of the voltage across the switches is demonstrated and the time constants involved in this process are determined.

From a green and sustainable chemistry standpoint, the current challenge in the polyurethane’s industry is to switch from petrobased polyurethanes (PUs) to biobased polyhydroxyurethanes (PHUs). This review describes the main alternative strategies being developed with a focus on PHUs from vegetable oils and derivatives. The substitution of petrobased polyols by natural oil based polyols was the first route to biobased PUs to be developed. The second strategy involves synthesis without the need of harmful isocyanate by the nucleophilic polyaddition of polyamines to polycyclic carbonates. The technological barrier to the synthesis of biobased cyclic carbonates could be overcome by the chemical transformation of epoxidized vegetable oils or by the use of glycerine carbonate-based intermediates. New families of biobased PHUs with a lower environmental footprint could be generated.

Hydrophobic cotton fibers, obtained by acylation of cellulose with fatty acid using microwaves radiations, have a high selective affinity for vegetable or mineral oil, fuel, and petroleum, in aqueous medium. Their sorption capacity (SC) (weight of liquid picked up by a given weight of sorbent) is about 20 g/g, after draining. They are reusable after simple squeezing, and their SC reaches a constant value, ca. 12 g/g. Moreover, this product is stable in water, whereas raw cotton can develop molds, after oil sorption. Besides, it is also biodegradable.

An original analytical study concerning the torque ripple due to phase commutation on brushless DC motors is developed. The results indicate that the relative ripple is independent of current, varies with speed, and may reach 50% of the average torque. The amplitude of the torque ripple and the duration of the commutation are analyzed, showing how this affects the torque-speed curve of the drive. Simulation as well as experimental results that validate the theoretical analysis are presented.< <ETX xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">&gt;</ETX>

<para xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> This paper examines the detection of mechanical faults in induction motors by an original use of stator current time-frequency analysis. Mechanical faults lead generally to periodic load torque oscillations. The influence of the torque oscillations on the induction motor stator current is studied using an analytical approach. The mechanical fault results in a sinusoidal phase modulation of the stator current, which is equivalent to a time-varying frequency. Based on these assumptions, several signal processing methods suitable for stator current signature analysis are discussed: classical spectral analysis, instantaneous frequency estimation, and the Wigner distribution. Experimental and simulation results validate the theoretical approach in steady-state operating conditions. </para>

The randomness in the structure of two-component dense composite materials influences the scalar effective dielectric constant, in the quasistatic limit. A numerical analysis of this property is developed in this paper. The computer-simulation models used are based on both the finite element method and the boundary integral equation method for two- and three-dimensional structures, respectively. Owing to possible anisotropy the orientation of spatially fixed inhomogeneities of permittivity ε1, embedded in a matrix of permittivity ε2, affects the effective permittivity of the composite material sample. The primary goal of this paper is to analyze this orientation dependence. Second, the effect of the components geometry on the dielectric properties of the medium is studied. Third the effect of inhomogeneities randomly distributed within a matrix is investigated. Changing these three parameters provides a diverse array of behaviors useful to understand the dielectric properties of random composite materials. Finally, the data obtained from this numerical simulation are compared to the results of previous analytical work.

The irreversible thermal inactivation of Bacillus licheniformis alpha-amylase was studied. A two-step behaviour in the irreversible denaturation process was found. Our experimental results are consistent only with the two-step model and rule out the two-isoenzyme one. They suggest that the deactivation mechanism involves the existence of a temperature-dependent intermediate form. Therefore the enzyme could exist in a great number of active conformational states. We have shown that Ca2+ is necessary for the structural integrity of alpha-amylase. Indeed, dialysis against chelating agents leads to a reversible enzyme inactivation, though molecular sieving has no effect. Further, the key role of Ca2+ in the alpha-amylase thermostability is reported. The stabilizing effect of Ca2+ is reflected by the decrease of the denaturation constants of both the native and the intermediate forms. Below 75 degrees C, in the presence of 5 mM-CaCl2, alpha-amylase is completely thermostable. Neither other metal ions nor substrate have a positive effect on enzyme thermostability. The effect of temperature on the native enzyme and on one intermediate form was studied. Both forms exhibit the same optimum temperature. Identical activation parameters for the hydrolytic reaction catalysed by these two forms were found.

We present in this paper a new topology of multilevel converter allowing an increase of input voltage level compared with the imbricated cells converter, while decreasing the stored energy in the converter. This new topology called SMC (stacked multicell converter) consists of a hybrid association of commutation cell making it possible to share the voltage constraint on several switches, and also to improve the output waveforms of the converter in terms of number of levels and switching frequency. After the introduction, the second part is devoted to the presentation of the topology. We give some explanation about the control of the SMC converter, and give some basics design properties for the SMC topology. Some simulation and experimental results obtained on a 50 kVA experimental set-up are presented.

The past decade has seen a surge in the interest in microalgae culture for biodiesel production and other applications as renewable biofuels as an alternative to petroleum transport fuels. The development of new technologies for the culture of these photosynthetic microorganisms and improved knowledge of their biochemical composition has spurred innovation in the field of high-value biomolecules. These developments are only economically viable if all the microalgae fractions are valorized in a biorefinery strategy. Achieving this objective requires an understanding of microalgae content and the cellular localization of the main biomolecular families in order to develop efficient harvest and sequential recovery technologies. This review summarizes the state of the art in microalgae compositions and topologies using some examples of the main industrially farmed microalgae.

The purpose of present study was to stabilize curcumin food pigment by its complexation with divalent ions like (Zn(2+), Cu(2+), Mg(2+), Se(2+)), in "green media" and evaluate its stability in vitro compared to curcumin alone. The curcumin complexes were prepared by mechanical mixture of curcumin and sulfate salts of each metal (metal : curcumin 1/1mol) into unconventional and nontoxic glycerol/water solvent. Two stoichiometry of complex were obtained, 1 : 1 and 1 : 2 (metal/curcumin), respectively. On evaluation of in vitro stability, all complexes were found to provide a higher stability from curcumin alone.

The functional linear model with scalar response is a regression model where the predictor is a random function defined on some compact set of ℝ and the response is scalar. The response is modelled as Y =Ψ( X )+ ɛ , where Ψ is some linear continuous operator defined on the space of square integrable functions and valued in ℝ. The random input X is independent from the noise ɛ . In this paper, we are interested in testing the null hypothesis of no effect, that is, the nullity of Ψ restricted to the Hilbert space generated by the random variable X . We introduce two test statistics based on the norm of the empirical cross‐covariance operator of ( X , Y ). The first test statistic relies on a χ 2 approximation and we show the asymptotic normality of the second one under appropriate conditions on the covariance operator of X . The test procedures can be applied to check a given relationship between X and Y . The method is illustrated through a simulation study.

A series of starch and amylose esters with different degrees of substitution and side-chain length were prepared and studied. The esters were prepared by acylation of the polysaccharide with the appropriate acid chlorides, such as octanoic, dodecanoic, and octadecanoic. The degrees of substitution were 0.54, 1.8, and 2.7. After preparation, the resulting esters were characterized by elemental analysis, 1H nuclear magnetic resonance (1H-NMR), Fourier transform infrared (FTIR), differential scanning (DSC), thermogravimetric analysis (TGA), contact angle, and water uptake measurements. Their mechanical properties and, in particular, the tensile strength and elongation at break depend on the side-chain length and on the degree of substitution. The extent of their biodegradability, after exposure to activated sludge, was assessed by weight loss measurements and scanning electron microscopy (SEM). It was found that these new materials are biodegradable, and the biodegradation rate decreases with increasing degree of esterification. © 1999 John Wiley & Sons, Inc. J Appl Polym Sci 74: 1440–1451, 1999

In the present study, starch octanoates OCST1.8 and OCST2.7 with degrees of substitution (d.s.) of 1.8 and 2.7, respectively, and dodecanoate DODST2.7 (d.s. = 2.7), were prepared by esterification of native starch with fatty acid chlorides. Our analyses, including elemental analysis, FTIR, contact angle, DSC, and TGA measurements confirmed the esterification reaction of starch and the degree of substitution. The ester group was found to act like an internal plasticizer, with an increase in the number and the size of fatty acyl chains grafted onto starch. These starch esters were mixed with low density polyethylene (LDPE) at various proportions in a Haake Rheomixer. Water and moisture absorption, thermal and mechanical properties, and biodegradation were investigated as a function of blend composition. The DODST2.7/LDPE blends showed, in general, better thermal stability and higher elongation, but lower tensile strength and water absorption, than did corresponding OCST/LDPE blends. The addition of starch esters to LDPE led to a very slow rate of biodegradation of these blends. &copy 1997 John Wiley & Sons, Inc. J Appl Polym 65: 705–721, 1997

Protein is one of the major macronutrients essential in human nutrition. Protein sources especially animal sourced proteins are expensive, thus much work has been carried out to explore alternative protein sources. Seaweeds, or macroalgae, are emerging as one of the alternative protein sources. They are rich in protein with an excellent amino acid profile comparable to the other conventional protein sources. Seaweed protein contains bioactive components, such as free amino acids, peptides, lectins, and phycobiliproteins, including phycoerythrin and phycocyanin, among others. Seaweed proteins have been proved for their antihypertensive, antidiabetic, antioxidant, anti-inflammatory, antitumoral, antiviral, antimicrobial, and many other beneficial functional properties. Therefore, seaweed proteins can be a natural alternative source for functional food development. This paper discusses the compositional and nutritional aspects of seaweed protein, protein extraction techniques, functional properties of various seaweed proteins, as well as their safety for new product development and functional food applications.

Different methods are presented for the calculation of torque as a function of rotation angle in an electrical machine. These methods are integrated in a calculation code by using the finite element method. The movement is taken into account by means of the moving band technique, involving quadrilateral finite elements in the airgap. The torque is calculated during the displacement of the moving part by using the following methods: Maxwell stress tensor, coenergy derivation, Coulomb's virtual work, A. Arkkio's method (1988), and the magnetizing current method. The results obtained by the different methods are compared with experimental data and make it possible to obtain practical information concerning the advantages and limitations of each method.< <ETX xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">&gt;</ETX>

The skin serves as the body’s first line of defense, guarding against mechanical, chemical, and thermal damage to the interior organs. It includes a highly developed immune response that serves as a barrier against pathogenic infections. Wound healing is a dynamic process underpinned by numerous cellular activities, including homeostasis, inflammation, proliferation, and remodeling, that require proper harmonious integration to effectively repair the damaged tissue. Following cutaneous damage, microorganisms can quickly enter the tissues beneath the skin, which can result in chronic wounds and fatal infections. Natural phytomedicines that possess considerable pharmacological properties have been widely and effectively employed forwound treatment and infection prevention. Since ancient times, phytotherapy has been able to efficiently treat cutaneous wounds, reduce the onset of infections, and minimize the usage of antibiotics that cause critical antibiotic resistance. There are a remarkable number of wound-healing botanicals that have been widely used in the Northern Hemisphere, including Achiella millefolium, Aloe vera, Althaea officinalis, Calendula officinalis, Matricaria chamomilla, Curcuma longa, Eucalyptus, Jojoba, plantain, pine, green tea, pomegranate, and Inula. This review addresses the most often used medicinal plants from the Northern Hemisphere that facilitate the treatment of wounds, and also suggests viable natural alternatives that can be used in the field of wound care.

The main idea developed in this paper is a novel biconverter structure to supply a doubly fed induction machine (DFIM). Two voltage source inverters (VSIs) feed the stator and rotor windings. The outputs of the two VSIs are combined electromechanically in the machine, and as a result, novel features can be obtained. For example, for high power drive applications, this configuration uses two inverters dimensioned for a half of the DFIM power. A new dual direct torque control is developed with flux model of DFIM. Two switching tables linked to VSI are defined for stator and rotor flux vector control. The satisfactory experimental and simulation results are shown, and they confirm good dynamic behavior in four quadrants of the speed-torque plane. Moreover, experimental results show the correct flux vector control behavior and speed tracking performances.