Laboratoire des Procédés en Milieux Granulaires Granulaires

The work presented here focuses on the analysis of a turbulent boundary layer saturated with saltating particles. Experiments were carried out in a wind tunnel 15m long and 0.6m wide at the University of Aarhus in Denmark with sand grains 242 μm in size for wind speeds ranging from the threshold speed to twice its value. The saltating particles were analysed using particle image velocimetry (PIV) and particle-tracking velocimetry (PTV), and vertical profiles of particle concentration and velocity were extracted. The particle concentration was found to decrease exponentially with the height above the bed, and the characteristic decay height was independent of the wind speed. In contrast with the logarithmic profile of the wind speed, the grain velocity was found to vary linearly with the height. In addition, the measurements indicated that the grain velocity profile depended only slightly on the wind speed. These results are shown to be closely related to the features of the splash function that characterizes the impact of the saltating particles on a sandbed. A numerical simulation is developed that explicitly incorporates low-velocity moments of the splash function in a calculation of the boundary conditions that apply at the bed. The overall features of the experimental measurements are reproduced by simulation.

Abstract Four cathode materials for single chamber solid oxide fuel cell (SC‐SOFC) [La 0.8 Sr 0.2 MnO 3–δ (LSM), Ba 0.5 Sr 0.5 Co 0.8 Fe 0.2 O 3–δ (BSCF), Sm 0.5 Sr 0.5 CoO 3–δ (SSC), and La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 3–δ (LSCF)] were investigated regarding their chemical stability, electrical conductivity, catalytic activity, and polarization resistance under air and methane/air atmosphere. Electrolyte‐supported fuel cells, with Ce 0.9 Gd 0.1 O 2–δ (CGO) electrolyte and a Ni‐CGO anode, were tested in several methane/air mixtures with each cathode materials between 625 and 725 °C. These single cells were not optimized but only designed to compare the four studied cathodes. The decrease of methane‐to‐oxygen ratio from 2 to 0.67 strongly increased the performance of fuel cells for all cathode materials but the effect of temperature was not always significant. Cells with SSC, BSCF, and LSCF have shown a maximum power density about 20 mW cm –2 while the cell with LSM has given only 5 mW cm –2 .

We study fully developed, steady granular flows confined between parallel flat frictional sidewalls using numerical simulations and experiments. Above a critical rate, sidewall friction stabilizes the underlying heap at an inclination larger than the angle of repose. The shear rate is constant and independent of inclination over much of the flowing layer. In the direction normal to the free surface, the solid volume fraction increases on a scale equal to half the flowing layer depth. Beneath a critical depth at which internal friction is invariant, grains exhibit creeping and intermittent cage motion similar to that in glasses, causing gradual weakening of friction at the walls.

In this paper the unsteady translation of coated microbubbles propelled by acoustic radiation force is studied experimentally. A system of two pulsating microbubbles of the type used as contrast agent in ultrasound medical imaging is considered, which attract each other as a result of the secondary Bjerknes force. Optical tweezers are used to isolate the bubble pair from neighboring boundaries so that it can be regarded as if in an unbounded fluid and the hydrodynamic forces acting on the system can be identified unambiguously. The radial and translational dynamics, excited by a 2.25 MHz ultrasound wave, is recorded with an ultrahigh speed camera at 15×106 frames/s. The time-resolved measurements reveal a quasisteady component of the translational velocity, at an average translational Reynolds number ⟨Ret⟩≈0.5, and an oscillatory component at the same frequency as the radial pulsations, as predicted by existing models. Since the coating enforces a no-slip boundary condition, an increased viscous dissipation is expected due to the oscillatory component, similar to the case of an oscillating rigid sphere that was first described by Stokes [“On the effect of the internal friction of fluids on the motion of pendulums,” Trans. Cambridge Philos. Soc. 9, 8 (1851)]. A history force term is therefore included in the force balance, in the form originally proposed by Basset and extended to the case of time-dependent radius by Takemura and Magnaudet [“The history force on a rapidly shrinking bubble rising at finite Reynolds number,” Phys. Fluids 16, 3247 (2004)]. The instantaneous values of the hydrodynamic forces extracted from the experimental data confirm that the history force accounts for the largest part of the viscous force. The trajectories of the bubbles predicted by numerically solving the equations of motion are in very good agreement with the experiment.

Recently, Dean and Lefèvre [Phys. Rev. Lett. 90, 198301 (2003)] developed a method for testing the statistical mechanical theory of granular packings proposed by Edwards and co-workers [Physica A 157, 1080 (1989); Phys. Rev. E 58, 4758 (1998)]. The method relies on the prediction that the ratio of two overlapping volume histograms should be exponential in volume. We extend the method by showing that one can also calculate the entropy of the packing and also that the method can yield false positive results when the histograms are Gaussians with nearly identical variances. We then apply the method to simulations and experiments of granular compaction. The distribution of global volumes (the volume of the entire packing) is nearly Gaussian and it is difficult to conclude if the theory is valid. On the other hand, the distribution of Voronoï volumes clearly obeys the theoretical prediction.

Zinc oxide based materials are commonly used for the final desulfurization of synthesis gas in Fischer-Tropsch based XTL processes. Although the ZnO sulfidation reaction has been widely studied, little is known about the transformation at the crystal scale, its detailed mechanism and kinetics. A model ZnO material with well-determined characteristics (particle size and shape) has been synthesized to perform this study. Characterizations of sulfided samples (using XRD, TEM and electron diffraction) have shown the formation of oriented polycrystalline ZnS nanoparticles with a predominant hexagonal form (wurtzite phase). TEM observations also have evidenced an outward development of the ZnS phase, showing zinc and oxygen diffusion from the ZnO-ZnS internal interface to the surface of the ZnS particle. The kinetics of ZnO sulfidation by H(2)S has been investigated using isothermal and isobaric thermogravimetry. Kinetic tests have been performed that show that nucleation of ZnS is instantaneous compared to the growth process. A reaction mechanism composed of eight elementary steps has been proposed to account for these results, and various possible rate laws have been determined upon approximation of the rate-determining step. Thermogravimetry experiments performed in a wide range of H(2)S and H(2)O partial pressures have shown that the ZnO sulfidation reaction rate has a nonlinear variation with H(2)S partial pressure at the same time no significant influence of water vapor on reaction kinetics has been observed. From these observations, a mixed kinetics of external interface reaction with water desorption and oxygen diffusion has been determined to control the reaction kinetics and the proposed mechanism has been validated. However, the formation of voids at the ZnO-ZnS internal interface, characterized by TEM and electron tomography, strongly slows down the reaction rate. Therefore, the impact of the decreasing ZnO-ZnS internal interface on reaction kinetics has been taken into account in the reaction rate expression. In this way the void formation at the interface has been modeled considering a random nucleation followed by an isotropic growth of cavities. Very good agreement has been observed between both experimental and calculated rates after taking into account the decrease in the ZnO-ZnS internal interface.

BACKGROUND: Micrometric and nanometric particles are increasingly used in different fields and may exhibit variable toxicity levels depending on their physicochemical characteristics. The aim of this study was to determine the impact of the size parameter on cellular uptake and biological activity, working with well-characterized fluorescent particles. We focused our attention on macrophages, the main target cells of the respiratory system responsible for the phagocytosis of the particles. METHODS: FITC fluorescent silica particles of variable submicronic sizes (850, 500, 250 and 150 nm) but with similar surface coating (COOH) were tailored and physico-chemically characterized. These particles were then incubated with the RAW 264.7 macrophage cell line. After microscopic observations (SEM, TEM, confocal), a quantitative evaluation of the uptake was carried out. Fluorescence detected after a quenching with trypan blue allows us to distinguish and quantify entirely engulfed fluorescent particles from those just adhering to the cell membrane. Finally, these data were compared to the in vitro toxicity assessed in terms of cell damage, inflammation and oxidative stress (evaluated by LDH release, TNF-α and ROS production respectively). RESULTS AND CONCLUSION: Particles were well characterized (fluorescence, size distribution, zeta potential, agglomeration and surface groups) and easily visualized after cellular uptake using confocal and electron microscopy. The number of internalized particles was precisely evaluated. Size was found to be an important parameter regarding particles uptake and in vitro toxicity but this latter strongly depends on the particles doses employed.

This article presents a new in situ method to monitor the particle size distribution (PSD) during batch solution crystallization processes. Using a new in situ imaging probe, the "EZProbe sensor," real time acquisition of 2-D images of particles during the batch process is now possible. To analyze these images, a novel image analysis method is carried out. First, segmentation and restoration algorithms are performed to identify the particles and thereafter geometrical particle measurements are achieved to obtained the PSD of the batch crystallization process over time. Satisfactory measurements are obtained provided that the overall solid concentration does not exceed a threshold above which too many overlapping crystals make discrimination between particles impossible.

The dissipation between two-dimensional (2D) monolayers of bubbles, the so-called quasi-2D foams, and a wall is investigated in two setups: a “liquid pool” system, where the foam is confined between a soap solution and a glass coverslip, and a Hele-Shaw cell, where the foam occupies the narrow gap between two plates. This experimental study reports dissipation measurements for mobile gas/liquid interfaces (free shear boundary condition) over a large range of parameters: in the liquid pool system, velocity and bubble area; in the Hele-Shaw cell, velocity and liquid fraction. The effect of the latter quantity is measured for the first time over more than three orders of magnitude. A full comparison between our results and other experimental studies is proposed and enables to rescale all measurements on a single master curve. It shows that for mobile gas/liquid interfaces, the existing models systematically underestimate the dissipation in flowing foams. This is quantified by a discrepancy factor ξ, ratio of the experimental dissipation measurements to the theoretical predictions, which scales as ξ=1.4(RP/A)−0.5 with RP the Plateau border radius and A the bubble area, showing that the discrepancy is higher for dry foams.

free vibrations Improvement of dimensional stability and durability is wished for the use of wood as a building material. For the last decade, retification ® has been industrially developed. It consists in a stabilization and preservation of wood by heat treatment. The aim of this study is to find simple and fast methods to characterize heat treated beech. Non destructive testing is expected to be relevant to evaluate the level of treatment and the properties for the use of heat treated wood. Six treatments were carried out in a pilot reactor. The parameters of the retification ® stage (temperature and time) were studied. For each treatment, the non destructive tests (free oscillations in the fundamental mode, colour and dry weight loss)were performed, and the properties for use (mechanical resistance and volumetric shrinkage) measured. Lightness and dry weight loss seem to be suitable properties to characterize beech retification® when the time parameter is fixed. However, they are not suitable for other wood species, and for

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Numerical simulations of assemblies of grains under cyclic loading exhibit "granular ratcheting:" a small net deformation occurs with each cycle, leading to a linear accumulation of deformation with cycle number. We show that this is due to a curious property of the most frequently used models of the particle-particle interaction: namely, that the potential energy stored in contacts is path dependent. There exist closed paths that change the stored energy, even if the particles remain in contact and do not slide. An alternative method for calculating the tangential force removes granular ratcheting.

The second generation biofuels exploits the lignocellulosic materials. The main advantage is to not compete with food chain. In the case of thermochemical means (gasification in an entrained flow reactor followed by Fischer-Tropsch synthesis), a grinding step is necessary to inject particles into the burner. The targeted particle size is about 200µm to reach a total conversion and to improve gas quality. Due to the plastic behaviour of the biomass, this step is strongly energy-consuming. Biomass torrefaction (thermal treatment lower than 300°C) is a way to decrease the grinding energy and to standardize materials (composition and moisture). Contrary to natural wood, torrefied wood has a brittle behaviour and a less mechanical strength. The aim of this study is to investigate the interest of torrefaction on wood grinding energy diminution. The torrefactions were carried out on beech and spruce, in an airtight rotating batch kiln under nitrogen. The effect of torrefaction temperature (160-300°C) and duration (5-60min), on weight loss, grinding energy and powder particles size were examined. The grinding energy was calculated by integration of the electric power of the grinder, which was measured by the means of a wattmeter. A grindability criterion, which took into account both grinding energy (E) and the volume fraction (X) of particles lower than the targeted size (200µm), was defined. Results showed a strong interest of torrefaction on the decrease in energy required for fine wood particle grinding. The grindability criterion could be reduced by 93% for treatments beyond 260°C. However, the global energy balance becomes less favourable. It is necessary to reach a compromise between the consumed energy by torrefaction and the decrease in grinding energy. According to the wood species, an optimum could be established around 10% of weight loss and around 85% of the grindability criterion diminution.

A dry coating technique has been used to change the surface properties of silica gel particles (d50=55μm) by coating with different mass ratios of magnesium stearate - MgSt2 (d50=4.6μm): 1%, 5%, 15% and 30%. The dry coating experiments were performed using a “Hybridizer, a high-speed dry impact blending coater”, manufactured by Nara Machinery (Japan). The surface morphology of the uncoated and coated silica gel particles was observed by environmental scanning electron microscopy (ESEM). The images show that a greater MgSt2 coverage was observed on the surface of silica gel as the MgSt2 mass ratio is increased. In addition, atomic force microscopy (AFM) analysis revealed how this coating process makes possible a discrete and uniform dispersion of the MgSt2 particles. AFM studies were carried out with a scanning probe microscope Multimode Nanoscope IIIA (Digital Instruments/Veeco Metrology Group).

International audience

International audience

International audience

We consider the propagation of a diffusive wave in a scattering medium submitted to a homogeneous expansion. The light multiply scattered by a glass spheres sample is measured. We analyze the variations of the scattered light when the material and the optical wavelength are dilated. We experimentally show that an isotropic expansion of the material is equivalent to a contraction of the wavelength. Moreover, the effect of an expansion of the material on the scattered wave may be canceled by a proportional increase of the wavelength, keeping the phase of the scattered wave unchanged. Applications to the characterization of deformation of disordered materials are outlined.

Selected topics in field of the study of the mechanisms of corrosion and of oxidation of metals or alloys are presented. The first part reports a new model for the mechanism of the breakaway oxidation of ferritic stainless steels in water vapour. The second part is devoted to the physico-chemical aspects of oxidation and presents experimental methods useful in the kinetic modelling applied to two alloys, the zircalloy-4 and an AlMg5 % in the liquid state. In the third part the physical and numerical modelling of the stress corrosion cracking behaviour in face-centered cubic (fcc) alloys is detailed, which enables the study of the influence of macroscopic parameters (such as the temperature or hydrogen activity) on the fracture process.

Abstract In the presented flow simulations a spherical argon gas bubble rises in stagnant liquid metal with initially homogeneously distributed spherical aluminium oxide particles of small inertia. Depending on their relative position to the bubble particles are subjected to different fluid forces and show different collision behaviour. The contribution presents Direct Numerical Simulations with the bubble being geometrically resolved and the inclusions represented as point particles. In the community, the boundary condition at the particle surface is discussed controversially. To elucidate its potential influence, two extreme cases are simulated, one with full no‐slip condition, the other one with full slip condition. It is found that the influence of this change on the result is very small.