Observatoire de Physique du Globe de Clermont-Ferrand

Abstract. Mobility particle size spectrometers often referred to as DMPS (Differential Mobility Particle Sizers) or SMPS (Scanning Mobility Particle Sizers) have found a wide range of applications in atmospheric aerosol research. However, comparability of measurements conducted world-wide is hampered by lack of generally accepted technical standards and guidelines with respect to the instrumental set-up, measurement mode, data evaluation as well as quality control. Technical standards were developed for a minimum requirement of mobility size spectrometry to perform long-term atmospheric aerosol measurements. Technical recommendations include continuous monitoring of flow rates, temperature, pressure, and relative humidity for the sheath and sample air in the differential mobility analyzer. We compared commercial and custom-made inversion routines to calculate the particle number size distributions from the measured electrical mobility distribution. All inversion routines are comparable within few per cent uncertainty for a given set of raw data. Furthermore, this work summarizes the results from several instrument intercomparison workshops conducted within the European infrastructure project EUSAAR (European Supersites for Atmospheric Aerosol Research) and ACTRIS (Aerosols, Clouds, and Trace gases Research InfraStructure Network) to determine present uncertainties especially of custom-built mobility particle size spectrometers. Under controlled laboratory conditions, the particle number size distributions from 20 to 200 nm determined by mobility particle size spectrometers of different design are within an uncertainty range of around ±10% after correcting internal particle losses, while below and above this size range the discrepancies increased. For particles larger than 200 nm, the uncertainty range increased to 30%, which could not be explained. The network reference mobility spectrometers with identical design agreed within ±4% in the peak particle number concentration when all settings were done carefully. The consistency of these reference instruments to the total particle number concentration was demonstrated to be less than 5%. Additionally, a new data structure for particle number size distributions was introduced to store and disseminate the data at EMEP (European Monitoring and Evaluation Program). This structure contains three levels: raw data, processed data, and final particle size distributions. Importantly, we recommend reporting raw measurements including all relevant instrument parameters as well as a complete documentation on all data transformation and correction steps. These technical and data structure standards aim to enhance the quality of long-term size distribution measurements, their comparability between different networks and sites, and their transparency and traceability back to raw data.

Research Article| April 01, 2002 Secular changes in tonalite-trondhjemite-granodiorite composition as markers of the progressive cooling of Earth Hervé Martin; Hervé Martin 1Laboratoire Magmas et Volcans, Observatoire de Physique du Globe de Clermont-Ferrand, Université Blaise Pascal, Centre National de la Recherche Scientifique 5, rue Kessler 63038, Clermont-Ferrand cedex, France Search for other works by this author on: GSW Google Scholar Jean-François Moyen Jean-François Moyen 1Laboratoire Magmas et Volcans, Observatoire de Physique du Globe de Clermont-Ferrand, Université Blaise Pascal, Centre National de la Recherche Scientifique 5, rue Kessler 63038, Clermont-Ferrand cedex, France Search for other works by this author on: GSW Google Scholar Author and Article Information Hervé Martin 1Laboratoire Magmas et Volcans, Observatoire de Physique du Globe de Clermont-Ferrand, Université Blaise Pascal, Centre National de la Recherche Scientifique 5, rue Kessler 63038, Clermont-Ferrand cedex, France Jean-François Moyen 1Laboratoire Magmas et Volcans, Observatoire de Physique du Globe de Clermont-Ferrand, Université Blaise Pascal, Centre National de la Recherche Scientifique 5, rue Kessler 63038, Clermont-Ferrand cedex, France Publisher: Geological Society of America Received: 13 Sep 2001 Revision Received: 23 Nov 2001 Accepted: 27 Nov 2001 First Online: 02 Jun 2017 Online ISSN: 1943-2682 Print ISSN: 0091-7613 Geological Society of America Geology (2002) 30 (4): 319–322. https://doi.org/10.1130/0091-7613(2002)030<0319:SCITTG>2.0.CO;2 Article history Received: 13 Sep 2001 Revision Received: 23 Nov 2001 Accepted: 27 Nov 2001 First Online: 02 Jun 2017 Cite View This Citation Add to Citation Manager Share Icon Share Facebook Twitter LinkedIn MailTo Tools Icon Tools Get Permissions Search Site Citation Hervé Martin, Jean-François Moyen; Secular changes in tonalite-trondhjemite-granodiorite composition as markers of the progressive cooling of Earth. Geology 2002;; 30 (4): 319–322. doi: https://doi.org/10.1130/0091-7613(2002)030<0319:SCITTG>2.0.CO;2 Download citation file: Ris (Zotero) Refmanager EasyBib Bookends Mendeley Papers EndNote RefWorks BibTex toolbar search Search Dropdown Menu toolbar search search input Search input auto suggest filter your search All ContentBy SocietyGeology Search Advanced Search Abstract Archean tonalite-trondhjemite-granodiorite associations (TTG) are classically thought to generate through partial melting of hydrous metabasalts. However, the chemical composition of the least differentiated TTG parental magmas evolved from 4.0 to 2.5 Ga. During this interval, the Mg# as well as the Ni and Cr contents increased, which is interpreted as reflecting increased interactions between felsic melts generated by metabasalt melting and mantle peridotite. Similarly, (CaO + Na2O) and Sr also increased over time, thus reflecting an increase in the abundance of plagioclase in the melt residue. The presence or absence of residual plagioclase is interpreted in terms of melting depth. The demonstrated interaction between TTG parental magmas and the mantle rules out their genesis by fusion of previously underplated metabasalt and favors the melting of subducted slab material. At 4.0 Ga, Earth's geothermal gradient was sufficiently high to allow slab melting at shallow depths where plagioclase was stable. Consequently, due to the small thickness of the overlying mantle wedge, felsic magmas interacted little with the mantle. At 2.5 Ga, however, owing to lower geothermal gradients, the melting depth was greater and plagioclase became no longer stable in the thick mantle wedge overlying the subducted slab. As a result, felsic magmas reacted strongly with the mantle peridotite. The changes of TTG composition during Archean time can be thus interpreted as reflecting the progressive cooling of Earth. You do not have access to this content, please speak to your institutional administrator if you feel you should have access.

A 2‐hourly data set of atmospheric precipitable water (PW) has been produced from the zenith path delay (ZPD) derived from ground‐based Global Positioning System (GPS) measurements. The PW data are available every 2 hours from 80 to 268 International GNSS Service (IGS, formally International GPS Service) ground stations from 1997 to 2004. The accuracy of the IGS ZPD product is roughly 4 mm. An analysis technique is developed to convert ZPD to PW on a global scale. Special efforts are made on deriving surface pressure (P s ) and water‐vapor‐weighted atmospheric mean temperature (T m ), which are two key parameters for converting ZPD to PW. P s is derived from global, 3‐hourly surface synoptic observations with temporal, vertical and horizontal adjustments. T m is calculated from NCEP/NCAR reanalysis with temporal, vertical and horizontal interpolations. The derived P s and T m at the GPS location and height have root‐mean‐square (rms) errors of 1.65 hPa and 1.3 K, respectively. A theoretical error analysis concludes that typical PW error associated with the errors in ZPD, T m and P s is on the order of 1.5 mm. The PW data set is compared with radiosonde, microwave radiometer (MWR) and satellite data. The GPS and radiosonde PW comparisons at 98 stations around the globe show a mean difference of 1.08 mm (drier for radiosonde data) with a standard deviation of differences of 2.68 mm, which corresponds to mean percentage difference and standard deviation of 5.5% and 10.6%, respectively. The bias is primarily due to known dry biases in the Vaisala radiosonde data. The RMS difference between GPS and radiosonde/MWR data ranges from 1.2 mm to 2.83 mm. The latitudinal and seasonal variations of PW derived from the GPS data agree well with that from International Satellite Cloud Climatology Project (ISCCP) data if the ISCCP data are sampled only at grid boxes containing GPS stations. The large difference between GPS and ISCCP data in the subtropics is interesting, but is not easily explained. The comparisons did not reveal any systematic bias in GPS PW data and show that a RMS difference of less than 3 mm between GPS‐derived PW and other data sets is achieved. The comparison study also illustrates the value of GPS‐estimated PW for examining the quality of other data sets, such as those from radiosondes and MWR. Preliminary analysis of this data set shows interesting and significant diurnal variations in PW in four different regions.

The Armorican Massif (western France) provides an excellent record of the Palaeozoic history of the Variscan belt. Following the Late Neoproterozoic Cadomian orogeny, the Cambro-Ordovician rifting was associated with oceanic spreading. The Central- and North-Amorican domains (which together constitute the core of the Armorica microplate) are bounded by two composite suture zones. To the north, the Léon domain (correlated with the “Normannian High” and the “Mid-German Crystalline Rise” in the Saxo-Thuringian Zone) records the development of a nappe stack along the northern suture zone, and was backthrusted over the central-Armorican domain during the Carboniferous. To the south, an intermediate block (“Upper Allochthon”) records a complex, polyorogenic history, with an early high-temperature event followed by the first generation of eclogites (Essarts). This intermediate block overthrusts to the north the Armorica microplate (Saint-Georges-sur-Loire), to the south: (i) relics of an oceanic domain; and (ii) the Gondwana palaeomargin. The collision occurred during a Late Devonian event, associated with a second generation of eclogites (Cellier).

Abstract A review of remote sensing technology for lower tropospheric thermodynamic (TD) profiling is presented with focus on high accuracy and high temporal‐vertical resolution. The contributions of these instruments to the understanding of the Earth system are assessed with respect to radiative transfer, land surface‐atmosphere feedback, convection initiation, and data assimilation. We demonstrate that for progress in weather and climate research, TD profilers are essential. These observational systems must resolve gradients of humidity and temperature in the stable or unstable atmospheric surface layer close to the ground, in the mixed layer, in the interfacial layer—usually characterized by an inversion—and the lower troposphere. A thorough analysis of the current observing systems is performed revealing significant gaps that must be addressed to fulfill existing needs. We analyze whether current and future passive and active remote sensing systems can close these gaps. A methodological analysis and demonstration of measurement capabilities with respect to bias and precision is executed both for passive and active remote sensing including passive infrared and microwave spectroscopy, the global navigation satellite system, as well as water vapor and temperature Raman lidar and water vapor differential absorption lidar. Whereas passive remote sensing systems are already mature with respect to operational applications, active remote sensing systems require further engineering to become operational in networks. However, active remote sensing systems provide a smaller bias as well as higher temporal and vertical resolutions. For a suitable mesoscale network design, TD profiler system developments should be intensified and dedicated observing system simulation experiments should be performed.

Abstract. Aerosol physical and chemical properties and trace gas concentrations were measured during the QUEST field campaign in March–April 2003, in Hyytiälä, Finland. Our aim was to understand the role of oxidation products of VOC's such as mono- and sesquiterpenes in atmospheric nucleation events. Particle chemical compositions were measured using the Aerodyne Aerosol Mass Spectrometer, and chemical compositions of aerosol samples collected with low-pressure impactors and a high volume sampler were analysed using a number of techniques. The results indicate that during and after new particle formation, all particles larger than 50 nm in diameter contained similar organic substances that are likely to be mono- and sesquiterpene oxidation products. The oxidation products identified in the high volume samples were shown to be mostly aldehydes. In order to study the composition of particles in the 10–50 nm range, we made use of Tandem Differential Mobility Analyzer results. We found that during nucleation events, both 10 and 50 nm particle growth factors due to uptake of ethanol vapour correlate strongly with gas-phase monoterpene oxidation product (MTOP) concentrations, indicating that the organic constituents of particles smaller than 50 nm in diameter are at least partly similar to those of larger particles. We furthermore showed that particle growth rates during the nucleation events are correlated with the gas-phase MTOP concentrations. This indicates that VOC oxidation products may have a key role in determining the spatial and temporal features of the nucleation events. This conclusion was supported by our aircraft measurements of new 3–10 nm particle concentrations, which showed that the nucleation event on 28 March 2003, started at the ground layer, i.e. near the VOC source, and evolved together with the mixed layer. Furthermore, no new particle formation was detected upwind away from the forest, above the frozen Gulf of Bothnia.

The procedures currently employed to retrieve vector wind information from single-Doppler radar observations are reviewed briefly. In particular, those procedures implying a linearity hypothesis for the wind field are shown to be particular cases of a method termed VVP (Volume Velocity Processing). This method, which makes full use of radar velocity data filling a volume, is first tested on simulated observations in order to assess its accuracy, then applied to actual data and shown to yield unbiased parameters of the horizontal vector wind field, as well as an estimate of the hydrometeor fall velocity and several control parameters.

Abstract. Atmospheric new particle formation (NPF) is an important phenomenon in terms of global particle number concentrations. Here we investigated the frequency of NPF, formation rates of 10 nm particles, and growth rates in the size range of 10–25 nm using at least 1 year of aerosol number size-distribution observations at 36 different locations around the world. The majority of these measurement sites are in the Northern Hemisphere. We found that the NPF frequency has a strong seasonal variability. At the measurement sites analyzed in this study, NPF occurs most frequently in March–May (on about 30 % of the days) and least frequently in December–February (about 10 % of the days). The median formation rate of 10 nm particles varies by about 3 orders of magnitude (0.01–10 cm−3 s−1) and the growth rate by about an order of magnitude (1–10 nm h−1). The smallest values of both formation and growth rates were observed at polar sites and the largest ones in urban environments or anthropogenically influenced rural sites. The correlation between the NPF event frequency and the particle formation and growth rate was at best moderate among the different measurement sites, as well as among the sites belonging to a certain environmental regime. For a better understanding of atmospheric NPF and its regional importance, we would need more observational data from different urban areas in practically all parts of the world, from additional remote and rural locations in North America, Asia, and most of the Southern Hemisphere (especially Australia), from polar areas, and from at least a few locations over the oceans.

Within cloud water, microorganisms are metabolically active and, thus, are expected to contribute to the atmospheric chemistry. This article investigates the interactions between microorganisms and the reactive oxygenated species that are present in cloud water because these chemical compounds drive the oxidant capacity of the cloud system. Real cloud water samples with contrasting features (marine, continental, and urban) were taken from the puy de Dôme mountain (France). The samples exhibited a high microbial biodiversity and complex chemical composition. The media were incubated in the dark and subjected to UV radiation in specifically designed photo-bioreactors. The concentrations of H(2)O(2), organic compounds, and the ATP/ADP ratio were monitored during the incubation period. The microorganisms remained metabolically active in the presence of ()OH radicals that were photo-produced from H(2)O(2). This oxidant and major carbon compounds (formaldehyde and carboxylic acids) were biodegraded by the endogenous microflora. This work suggests that microorganisms could play a double role in atmospheric chemistry; first, they could directly metabolize organic carbon species, and second, they could reduce the available source of radicals through their oxidative metabolism. Consequently, molecules such as H(2)O(2) would no longer be available for photochemical or other chemical reactions, which would decrease the cloud oxidant capacity.

Rising air pollution levels in South Asia will have worldwide environmental consequences. Transport of pollutants from the densely populated regions of India, Pakistan, China, and Nepal to the Himalayas may lead to substantial radiative forcing in South Asia with potential effects on the monsoon circulation and, hence, on regional climate and hydrological cycles, as well as to dramatic impacts on glacier retreat. An improved description of particulate sources is needed to constrain the simulation of future regional climate changes. Here, the first evidence of very frequent new particle formation events occurring up to high altitudes is presented. A 16-month record of aerosol size distribution from the Nepal Climate Observatory at Pyramid (Nepal, 5,079 m above sea level), the highest atmospheric research station, is shown. Aerosol concentrations are driven by intense ultrafine particle events occurring on >35% of the days at the interface between clean tropospheric air and the more polluted air rising from the valleys. During a pilot study, we observed a significant increase of ion cluster concentrations with the onset of new particle formation events. The ion clusters rapidly grew to a 10-nm size within a few hours, confirming, thus, that in situ nucleation takes place up to high altitudes. The initiation of the new particle events coincides with the shift from free tropospheric downslope winds to thermal upslope winds from the valley in the morning hours. The new particle formation events represent a very significant additional source of particles possibly injected into the free troposphere by thermal winds.

Version française d'un article qui sera publié dans le "Journal of Climate and Applied Meteorology" en 1987

Abstract. The ozone profile records of a large number of limb and occultation satellite instruments are widely used to address several key questions in ozone research. Further progress in some domains depends on a more detailed understanding of these data sets, especially of their long-term stability and their mutual consistency. To this end, we made a systematic assessment of 14 limb and occultation sounders that, together, provide more than three decades of global ozone profile measurements. In particular, we considered the latest operational Level-2 records by SAGE II, SAGE III, HALOE, UARS MLS, Aura MLS, POAM II, POAM III, OSIRIS, SMR, GOMOS, MIPAS, SCIAMACHY, ACE-FTS and MAESTRO. Central to our work is a consistent and robust analysis of the comparisons against the ground-based ozonesonde and stratospheric ozone lidar networks. It allowed us to investigate, from the troposphere up to the stratopause, the following main aspects of satellite data quality: long-term stability, overall bias and short-term variability, together with their dependence on geophysical parameters and profile representation. In addition, it permitted us to quantify the overall consistency between the ozone profilers. Generally, we found that between 20 and 40 km the satellite ozone measurement biases are smaller than ±5 %, the short-term variabilities are less than 5–12 % and the drifts are at most ±5 % decade−1 (or even ±3 % decade−1 for a few records). The agreement with ground-based data degrades somewhat towards the stratopause and especially towards the tropopause where natural variability and low ozone abundances impede a more precise analysis. In part of the stratosphere a few records deviate from the preceding general conclusions; we identified biases of 10 % and more (POAM II and SCIAMACHY), markedly higher single-profile variability (SMR and SCIAMACHY) and significant long-term drifts (SCIAMACHY, OSIRIS, HALOE and possibly GOMOS and SMR as well). Furthermore, we reflected on the repercussions of our findings for the construction, analysis and interpretation of merged data records. Most notably, the discrepancies between several recent ozone profile trend assessments can be mostly explained by instrumental drift. This clearly demonstrates the need for systematic comprehensive multi-instrument comparison analyses.

Clouds are key components in Earth's functioning. In addition of acting as obstacles to light radiations and chemical reactors, they are possible atmospheric oases for airborne microorganisms, providing water, nutrients and paths to the ground. Microbial activity was previously detected in clouds, but the microbial community that is active in situ remains unknown. Here, microbial communities in cloud water collected at puy de Dôme Mountain's meteorological station (1465 m altitude, France) were fixed upon sampling and examined by high-throughput sequencing from DNA and RNA extracts, so as to identify active species among community members. Communities consisted of ~103-104 bacteria and archaea mL-1 and ~102-103 eukaryote cells mL-1. They appeared extremely rich, with more than 28 000 distinct species detected in bacteria and 2 600 in eukaryotes. Proteobacteria and Bacteroidetes largely dominated in bacteria, while eukaryotes were essentially distributed among Fungi, Stramenopiles and Alveolata. Within these complex communities, the active members of cloud microbiota were identified as Alpha- (Sphingomonadales, Rhodospirillales and Rhizobiales), Beta- (Burkholderiales) and Gamma-Proteobacteria (Pseudomonadales). These groups of bacteria usually classified as epiphytic are probably the best candidates for interfering with abiotic chemical processes in clouds, and the most prone to successful aerial dispersion.

In the wake of the end-Permian mass extinction, the Early Triassic (~251.9 to 247 million years ago) is portrayed as an environmentally unstable interval characterized by several biotic crises and heavily depauperate marine benthic ecosystems. We describe a new fossil assemblage-the Paris Biota-from the earliest Spathian (middle Olenekian, ~250.6 million years ago) of the Bear Lake area, southeastern Idaho, USA. This highly diversified assemblage documents a remarkably complex marine ecosystem including at least seven phyla and 20 distinct metazoan orders, along with algae. Most unexpectedly, it combines early Paleozoic and middle Mesozoic taxa previously unknown from the Triassic strata, among which are primitive Cambrian-Ordovician leptomitid sponges (a 200-million year Lazarus taxon) and gladius-bearing coleoid cephalopods, a poorly documented group before the Jurassic (~50 million years after the Early Triassic). Additionally, the crinoid and ophiuroid specimens show derived anatomical characters that were thought to have evolved much later. Unlike previous works that suggested a sluggish postcrisis recovery and a low diversity for the Early Triassic benthic organisms, the unexpected composition of this exceptional assemblage points toward an early and rapid post-Permian diversification for these clades. Overall, it illustrates a phylogenetically diverse, functionally complex, and trophically multileveled marine ecosystem, from primary producers up to top predators and potential scavengers. Hence, the Paris Biota highlights the key evolutionary position of Early Triassic fossil ecosystems in the transition from the Paleozoic to the Modern marine evolutionary fauna at the dawn of the Mesozoic era.

A seismic refraction transect across the Galicia Bank continental margin shows that the original continental crust thins westward from 17 to 2 km immediately east of a margin‐parallel peridotite ridge (PR). Immediately west of the PR, oceanic crust is only 2.5–3.5 km thick, but farther west (oceanward) it thickens to 7 km. The PR caps a ∼60‐km‐wide lens‐shaped serpentinized peridotite body underlying both thinned continental and thin oceanic crust. When superimposed on a reflection time version of the velocity model, the S reflector is clearly intracrustal at its east end. Westward, S cuts down to lower crustal levels, eventually coinciding with the top of the serpentinized peridotite lens (original crust‐mantle boundary). These observations render almost impossible the seafloor exposure of the PR by S acting as a top‐to‐the‐west detachment fault. Numerical models of melting and borehole subsidence information constrain our rifting model. The easternmost continental crust experienced a total stretching factor of 4.3 (most likely in two stages); it probably occurred over ∼25 m.y., with the highest rate of stretching at the beginning of the main earlier rift phase (Valanginian; 141–135 Ma). The 3 (4.7) km thick continental crust (depending on whether serpentinized peridotite is assigned to crust or mantle), which may include melt products, requires stretching factors of more than 11 (7) and a rift duration of more than 25 (13) m.y. The thin oceanic crust immediately west of the PR is explained by conductive cooling of the mantle during the long prebreakup stretching phase, which temporarily caused reduced melting immediately after breakup.

Six garnet pyroxenites from Beni Bousera, Morocco, yield a mean lutetium-hafnium age of 25 +/- 1 million years ago and show a wide range in hafnium isotope compositions (varepsilonHf = -9 to +42 25 million years ago), which exceeds that of known basalts (0 to +25). Therefore, primary melts of garnet pyroxenites cannot be the source of basalts. The upper mantle may be an aggregate of pyroxenites that were left by the melting of oceanic crust at subduction zones and peridotites that were contaminated by the percolation of melts from these pyroxenites. As a consequence, the concept of geochemical heterogeneities as passive tracers is inadequate. Measured lutetium-hafnium partitioning of natural minerals requires a reassessment of some experimental work relevant to mantle melting in the presence of garnet.

Abstract. Aerosol particles are essential constituents of the Earth's atmosphere, impacting the earth radiation balance directly by scattering and absorbing solar radiation, and indirectly by acting as cloud condensation nuclei. In contrast to most greenhouse gases, aerosol particles have short atmospheric residence times, resulting in a highly heterogeneous distribution in space and time. There is a clear need to document this variability at regional scale through observations involving, in particular, the in situ near-surface segment of the atmospheric observation system. This paper will provide the widest effort so far to document variability of climate-relevant in situ aerosol properties (namely wavelength dependent particle light scattering and absorption coefficients, particle number concentration and particle number size distribution) from all sites connected to the Global Atmosphere Watch network. High-quality data from almost 90 stations worldwide have been collected and controlled for quality and are reported for a reference year in 2017, providing a very extended and robust view of the variability of these variables worldwide. The range of variability observed worldwide for light scattering and absorption coefficients, single-scattering albedo, and particle number concentration are presented together with preliminary information on their long-term trends and comparison with model simulation for the different stations. The scope of the present paper is also to provide the necessary suite of information, including data provision procedures, quality control and analysis, data policy, and usage of the ground-based aerosol measurement network. It delivers to users of the World Data Centre on Aerosol, the required confidence in data products in the form of a fully characterized value chain, including uncertainty estimation and requirements for contributing to the global climate monitoring system.

The pore structure of rocks is highly complex, with wide variations in pore size and shape. In this work, pore‐scale heterogeneity was simulated by distributing spheres, tubes and cracks with variable dimensions on a square lattice. The transport properties of 100 such network realizations, covering 11 orders of magnitude in permeability, were calculated. Seeking the appropriate averaging procedure to calculate the permeability and electrical conductivity from the local pore parameters, we computed the energy locally dissipated in each bond during fluid or electric flow and the energy globally dissipated in the whole network. By equating the latter to the sum of the former, we obtained averaging expressions exactly predicting the transport properties of the network realizations. Since these relations hold on a wide variety of heterogeneous networks covering a broad range of permeabilities and electrical conductivities, we propose that they should also be valid on rocks. We can thus gain insights into how pore‐scale heterogeneity affects the transport properties of rocks.

Abstract. The Chemistry-Aerosol Mediterranean Experiment (ChArMEx; http://charmex.lsce.ipsl.fr) is a collaborative research program federating international activities to investigate Mediterranean regional chemistry-climate interactions. A special observing period (SOP-1a) including intensive airborne measurements was performed in the framework of the Aerosol Direct Radiative Impact on the regional climate in the MEDiterranean region (ADRIMED) project during the Mediterranean dry season over the western and central Mediterranean basins, with a focus on aerosol-radiation measurements and their modeling. The SOP-1a took place from 11 June to 5 July 2013. Airborne measurements were made by both the ATR-42 and F-20 French research aircraft operated from Sardinia (Italy) and instrumented for in situ and remote-sensing measurements, respectively, and by sounding and drifting balloons, launched in Minorca. The experimental setup also involved several ground-based measurement sites on islands including two ground-based reference stations in Corsica and Lampedusa and secondary monitoring sites in Minorca and Sicily. Additional measurements including lidar profiling were also performed on alert during aircraft operations at EARLINET/ACTRIS stations at Granada and Barcelona in Spain, and in southern Italy. Remote-sensing aerosol products from satellites (MSG/SEVIRI, MODIS) and from the AERONET/PHOTONS network were also used. Dedicated meso-scale and regional modeling experiments were performed in relation to this observational effort. We provide here an overview of the different surface and aircraft observations deployed during the ChArMEx/ADRIMED period and of associated modeling studies together with an analysis of the synoptic conditions that determined the aerosol emission and transport. Meteorological conditions observed during this campaign (moderate temperatures and southern flows) were not favorable to producing high levels of atmospheric pollutants or intense biomass burning events in the region. However, numerous mineral dust plumes were observed during the campaign, with the main sources located in Morocco, Algeria and Tunisia, leading to aerosol optical depth (AOD) values ranging between 0.2 and 0.6 (at 440 nm) over the western and central Mediterranean basins. One important point of this experiment concerns the direct observations of aerosol extinction onboard the ATR-42, using the CAPS system, showing local maxima reaching up to 150 M m−1 within the dust plume. Non-negligible aerosol extinction (about 50 M m−1) has also been observed within the marine boundary layer (MBL). By combining the ATR-42 extinction coefficient observations with absorption and scattering measurements, we performed a complete optical closure revealing excellent agreement with estimated optical properties. This additional information on extinction properties has allowed calculation of the dust single scattering albedo (SSA) with a high level of confidence over the western Mediterranean. Our results show a moderate variability from 0.90 to 1.00 (at 530 nm) for all flights studied compared to that reported in the literature on this optical parameter. Our results underline also a relatively low difference in SSA with values derived near dust sources. In parallel, active remote-sensing observations from the surface and onboard the F-20 aircraft suggest a complex vertical structure of particles and distinct aerosol layers with sea spray and pollution located within the MBL, and mineral dust and/or aged North American smoke particles located above (up to 6–7 km in altitude). Aircraft and balloon-borne observations allow one to investigate the vertical structure of the aerosol size distribution showing particles characterized by a large size (&gt; 10 µm in diameter) within dust plumes. In most of cases, a coarse mode characterized by an effective diameter ranging between 5 and 10 µm, has been detected above the MBL. In terms of shortwave (SW) direct forcing, in situ surface and aircraft observations have been merged and used as inputs in 1-D radiative transfer codes for calculating the aerosol direct radiative forcing (DRF). Results show significant surface SW instantaneous forcing (up to −90 W m−2 at noon). Aircraft observations provide also original estimates of the vertical structure of SW and LW radiative heating revealing significant instantaneous values of about 5° K per day in the solar spectrum (for a solar angle of 30°) within the dust layer. Associated 3-D modeling studies from regional climate (RCM) and chemistry transport (CTM) models indicate a relatively good agreement for simulated AOD compared with observations from the AERONET/PHOTONS network and satellite data, especially for long-range dust transport. Calculations of the 3-D SW (clear-sky) surface DRF indicate an average of about −10 to −20 W m−2 (for the whole period) over the Mediterranean Sea together with maxima (−50 W m−2) over northern Africa. The top of the atmosphere (TOA) DRF is shown to be highly variable within the domain, due to moderate absorbing properties of dust and changes in the surface albedo. Indeed, 3-D simulations indicate negative forcing over the Mediterranean Sea and Europe and positive forcing over northern Africa. Finally, a multi-year simulation, performed for the 2003 to 2009 period and including an ocean–atmosphere (O–A) coupling, underlines the impact of the aerosol direct radiative forcing on the sea surface temperature, O–A fluxes and the hydrological cycle over the Mediterranean.

Abstract. Particle number concentration and size distribution are important variables needed to constrain the role of atmospheric particles in the Earth radiation budget, both directly and indirectly through CCN activation. They are also linked to regulated variables such as particle mass (PM) and therefore of interest to air quality studies. However, data on their long-term variability are scarce, in particular at high altitudes. In this paper, we investigate the diurnal and seasonal variability of the aerosol total number concentration and size distribution at the puy de Dôme research station (France, 1465 m a.s.l.). We report a variability of aerosol particle total number concentration measured over a five-year (2003–2007) period for particles larger than 10 nm and aerosol size distributions between 10 and 500 nm over a two-year period (January 2006 to December 2007). Concentrations show a strong seasonality with maxima during summer and minima during winter. A diurnal variation is also observed with maxima between 12:00 and 18:00 UTC. At night (00:00–06:00 UTC), the median hourly total concentration varies from 600 to 800 cm−3 during winter and from 1700 to 2200 cm−3 during summer. During the day (08:00–18:00 UTC), the concentration is in the range of 700 to 1400 cm−3 during winter and of 2500 to 3500 cm−3 during summer. An averaged size distribution of particles (10–500 nm) was calculated for each season. The total aerosol number concentrations are dominated by the Aitken mode integral concentrations, which drive most of the winter to summer total concentrations increase. The night to day increase in dominated by the nucleation mode integral number concentration. Because the site is located in the free troposphere only a fraction of the time, in particular at night and during the winter season, we have subsequently analyzed the variability for nighttime and free tropospheric (FT)/residual layer (RL) conditions only. We show that a seasonal variability is still observed for these FT/RL conditions. The FT/RL seasonal variation is due to both seasonal changes in the air mass origin from winter to summer and enhanced concentrations of particles in the residual layer/free troposphere in summer. The later observation can be explained by higher emissions intensity in the boundary layer, stronger exchanges between the boundary layer and the free troposphere as well as enhanced photochemical processes. Finally, aerosols mean size distributions are calculated for a given air mass type (marine/continental/regional) according to the season for the specific conditions of the residual layer/free troposphere. The seasonal variability in aerosol sources seems to be predominant over the continent compared to the seasonal variation of marine aerosol sources. These results are of regional relevance and can be used to constrain chemical-transport models over Western Europe.