Quantum Science and Technology in Arcetri

Entanglement is the basis of quantum technologies aimed at revolutionizing measurements, computing, and communications. This article reviews methods to improve measurement precision and sensitivity by harnessing entangled states of many atomic probe particles. The achievements of different experimental entanglement schemes are presented with theoretical analyses of their fundamental and practical limits, discussing prospects for applications in clocks, frequency standards, and measurements of forces and fields.

We set new constraints on a seven-dimensional space of cosmological parameters within the class of inflationary adiabatic models. We use the angular power spectrum of the cosmic microwave background measured over a wide range of \\ell in the first flight of the MAXIMA balloon-borne experiment (MAXIMA-1) and the low \\ell results from COBE/DMR. We find constraints on the total energy density of the universe, \\Omega=1.0^{+0.15}_{-0.30}, the physical density of baryons, \\Omega_{b}h^2=0.03 +/- 0.01, the physical density of cold dark matter, \\Omega_{cdm}h^2=0.2^{+0.2}_{-0.1}$, and the spectral index of primordial scalar fluctuations, n_s=1.08+/-0.1, all at the 95% confidence level. By combining our results with measurements of high-redshift supernovae we constrain the value of the cosmological constant and the fractional amount of pressureless matter in the universe to 0.45<\\Omega_\\Lambda<0.75 and 0.25<\\Omega_{m}<0.50, at the 95% confidence level. Our results are consistent with a flat universe and the shape parameter deduced from large scale structure, and in marginal agreement with the baryon density from big bang nucleosynthesis.

Entanglement is the key quantum resource for improving measurement sensitivity beyond classical limits. However, the production of entanglement in mesoscopic atomic systems has been limited to squeezed states, described by Gaussian statistics. Here, we report on the creation and characterization of non-Gaussian many-body entangled states. We develop a general method to extract the Fisher information, which reveals that the quantum dynamics of a classically unstable system creates quantum states that are not spin squeezed but nevertheless entangled. The extracted Fisher information quantifies metrologically useful entanglement, which we confirm by Bayesian phase estimation with sub-shot-noise sensitivity. These methods are scalable to large particle numbers and applicable directly to other quantum systems.

Any physical process can be represented as a quantum channel mapping an initial state to a final state. Hence it can be characterized from the point of view of communication theory, i.e., in terms of its ability to transfer information. Quantum information provides a theoretical framework and the proper mathematical tools to accomplish this. In this context the notion of codes and communication capacities have been introduced by generalizing them from the classical Shannon theory of information transmission and error correction. The underlying assumption of this approach is to consider the channel not as acting on a single system, but on sequences of systems, which, when properly initialized allow one to overcome the noisy effects induced by the physical process under consideration. While most of the work produced so far has been focused on the case in which a given channel transformation acts identically and independently on the various elements of the sequence (memoryless configuration in jargon), correlated error models appear to be a more realistic way to approach the problem. A slightly different, yet conceptually related, notion of correlated errors applies to a single quantum system which evolves continuously in time under the influence of an external disturbance which acts on it in a non-Markovian fashion. This leads to the study of memory effects in quantum channels: a fertile ground where interesting novel phenomena emerge at the intersection of quantum information theory and other branches of physics. A survey is taken of the field of quantum channels theory while also embracing these specific and complex settings.

Our PACS and SPIRE images of the Aquila Rift and part of the Polaris Flare regions, taken during the science demonstration phase of <i>Herschel<i/> discovered fascinating, omnipresent filamentary structures that appear to be physically related to compact cores. We briefly describe a new multi-scale, multi-wavelength source extraction method used to detect objects and measure their parameters in our <i>Herschel<i/> images. All of the extracted starless cores (541 in Aquila and 302 in Polaris) appear to form in the long and very narrow filaments. With its combination of the far-IR resolution and sensitivity, <i>Herschel<i/> <i>directly<i/> reveals the filaments in which the dense cores are embedded; the filaments are resolved and have deconvolved widths of ~35” in Aquila and ~59” in Polaris (~9000 AU in both regions). Our first results of observations with <i>Herschel<i/> enable us to suggest that in general dense cores may originate in a process of fragmentation of complex networks of long, thin filaments, likely formed as a result of an interplay between gravity, interstellar turbulence, and magnetic fields. To unravel the roles of the processes, one has to obtain additional kinematic and polarization information; these follow-up observations are planned.

The measurement of relative displacements and deformations is important in many fields such as structural engineering, aerospace, geophysics, and nanotechnology. Optical-fiber sensors have become key tools for strain measurements, with sensitivity limits ranging between 10(-9) and 10(-6)ε hertz (Hz)(-1/2) (where ε is the fractional length change). We report on strain measurements at the 10(-13)ε-Hz(-1/2) level using a fiber Bragg-grating resonator with a diode-laser source that is stabilized against a quartz-disciplined optical frequency comb, thus approaching detection limits set by thermodynamic phase fluctuations in the fiber. This scheme may provide a route to a new generation of strain sensors that is entirely based on fiber-optic systems, which are aimed at measuring fundamental physical quantities; for example, in gyroscopes, accelerometers, and gravity experiments.

Quantum illumination uses entangled signal-idler photon pairs to boost the detection efficiency of low-reflectivity objects in environments with bright thermal noise. Its advantage is particularly evident at low signal powers, a promising feature for applications such as noninvasive biomedical scanning or low-power short-range radar. Here, we experimentally investigate the concept of quantum illumination at microwave frequencies. We generate entangled fields to illuminate a room-temperature object at a distance of 1 m in a free-space detection setup. We implement a digital phase-conjugate receiver based on linear quadrature measurements that outperforms a symmetric classical noise radar in the same conditions, despite the entanglement-breaking signal path. Starting from experimental data, we also simulate the case of perfect idler photon number detection, which results in a quantum advantage compared with the relative classical benchmark. Our results highlight the opportunities and challenges in the way toward a first room-temperature application of microwave quantum circuits.

The optimization of the poor heat transfer characteristics of fluids conventionally employed in solar devices are at present one of the main topics for system efficiency and compactness. In the present work we investigated the optical and thermal properties of nanofluids consisting in aqueous suspensions of single wall carbon nanohorns. The characteristics of these nanofluids were evaluated in view of their use as sunlight absorber fluids in a solar device. The observed nanoparticle-induced differences in optical properties appeared promising, leading to a considerably higher sunlight absorption. We found that the thermal conductivity of the nanofluids was higher than pure water. Both these effects, together with the possible chemical functionalization of carbon nanohorns, make this new kind of nanofluids very interesting for increasing the overall efficiency of the sunlight exploiting device.

A quantum theory of multiphase estimation is crucial for quantum-enhanced sensing and imaging and may link quantum metrology to more complex quantum computation and communication protocols. In this Letter, we tackle one of the key difficulties of multiphase estimation: obtaining a measurement which saturates the fundamental sensitivity bounds. We derive necessary and sufficient conditions for projective measurements acting on pure states to saturate the ultimate theoretical bound on precision given by the quantum Fisher information matrix. We apply our theory to the specific example of interferometric phase estimation using photon number measurements, a convenient choice in the laboratory. Our results thus introduce concepts and methods relevant to the future theoretical and experimental development of multiparameter estimation.

The resource theory of quantum coherence studies the off-diagonal elements of a density matrix in a distinguished basis, whereas the resource theory of purity studies all deviations from the maximally mixed state. We establish a direct connection between the two resource theories, by identifying purity as the maximal coherence which is achievable by unitary operations. The states that saturate this maximum identify a universal family of maximally coherent mixed states. These states are optimal resources under maximally incoherent operations, and thus independent of the way coherence is quantified. For all distance-based coherence quantifiers the maximal coherence can be evaluated exactly, and is shown to coincide with the corresponding distance-based purity quantifier. We further show that purity bounds the maximal amount of entanglement and discord that can be generated by unitary operations, thus demonstrating that purity is the most elementary resource for quantum information processing.

We identify precision limits for the simultaneous estimation of multiple parameters in multimode interferometers. Quantum strategies to enhance the multiparameter sensitivity are based on entanglement among particles, modes, or combining both. The maximum attainable sensitivity of particle-separable states defines the multiparameter shot-noise limit, which can be surpassed without mode entanglement. Further enhancements up to the multiparameter Heisenberg limit are possible by adding mode entanglement. Optimal strategies that saturate the precision bounds are provided.

The Josephson effect is a macroscopic quantum phenomenon that reveals the broken symmetry associated with any superfluid state. Here we report on the observation of the Josephson effect between two fermionic superfluids coupled through a thin tunneling barrier. We show that the relative population and phase are canonically conjugate dynamical variables throughout the crossover from the molecular Bose-Einstein condensate (BEC) to the Bardeen-Cooper-Schrieffer (BCS) superfluid regime. For larger initial excitations from equilibrium, the dynamics of the superfluids become dissipative, which we ascribe to the propagation of vortices through the superfluid bulk. Our results highlight the robust nature of resonant superfluids.

We propose a versatile Loschmidt echo protocol to detect and quantify multiparticle entanglement. It allows us to extract the quantum Fisher information for arbitrary pure states, and finds direct application in quantum metrology. In particular, the protocol applies to states that are generally difficult to characterize, as non-Gaussian states, and states that are not symmetric under particle exchange. We focus on atomic systems, including trapped ions, polar molecules, and Rydberg atoms, where entanglement is generated dynamically via long-range interaction, and show that the protocol is stable against experimental detection errors.

The chemical transformation of benzene under pressure is investigated, at room temperature and at 100 K, by means of infrared spectroscopy. Pressurization-decompression cycles in the 0–50 GPa pressure range have been performed to achieve the complete transformation of the monomer. The yellow-brownish recovered sample has been identified as an amorphous hydrogenated carbon (a-C:H). A correlation has been established between the pressure behavior of the frequencies of both Raman and infrared internal modes, and the corresponding vibrational energies in the S1 excited state (1B2u). From this comparison we conclude that pressure induces a mixing between the ground and the S1 electronic states. The increased ring flexibility enhances the interactions among nearest-neighbor molecules inducing the formation of a network of interconnected benzene units where the aromatic character is lost. The bond breaking mainly occurs during the decompression cycle favored by the density decrease. Radical species form in this stage and rapidly propagate to give the denser a-C:H final product.

Since the pioneering work of Ramsey, atom interferometers are employed for precision metrology, in particular to measure time and to realize the second. In a classical interferometer, an ensemble of atoms is prepared in one of the two input states, whereas the second one is left empty. In this case, the vacuum noise restricts the precision of the interferometer to the standard quantum limit (SQL). Here, we propose and experimentally demonstrate a novel clock configuration that surpasses the SQL by squeezing the vacuum in the empty input state. We create a squeezed vacuum state containing an average of 0.75 atoms to improve the clock sensitivity of 10000 atoms by 2.05_{-0.37}^{+0.34} dB. The SQL poses a significant limitation for today's microwave fountain clocks, which serve as the main time reference. We evaluate the major technical limitations and challenges for devising a next generation of fountain clocks based on atomic squeezed vacuum.

Interactions are known to have dramatic effects on bosonic gases in one dimension (1D). Not only does the ground state transform from a condensate like state to an effective Fermi sea, but new fundamental excitations, which do not have any higher-dimensional equivalents, are predicted to appear. In this work, we trace these elusive excitations via their effects on the dynamical structure factor of 1D strongly interacting Bose gases at low temperature. An array of 1D Bose gases is obtained by loading a $^{87}\mathrm{Rb}$ condensate in a two-dimensional lattice potential. The dynamical structure factor of the system is probed by energy deposition through low-momentum Bragg excitations. The experimental signals are compared to recent theoretical predictions for the dynamical structure factor of the Lieb-Liniger model at $T&gt;0$. Our results demonstrate that the main contribution to the spectral widths stems from the dynamics of the interaction-induced excitations in the gas, which cannot be described by the Luttinger liquid theory.

Light-matter coupling is an ongoing investigation in modern physics and is expected to play a role in quantum information applications. Using single-atom-controlled samples of ultracold rubidium-87 coupled to Rydberg states, scientists show that many-body systems of various sizes can be coherently manipulated as a single ``superatom.''

A major challenge of the phase estimation problem is the engineering of high-intensity entangled probe states. The goal is to significantly enhance above the shot-noise limit the sensitivity of two-mode interferometers. Here we show that this can be achieved by squeezing in input, and then measuring in output, the population fluctuations of a single mode. The second input mode can be left as an arbitrary nonvacuum (e.g., a bright coherent) state. This two-mode state belongs to a novel class of particle-entangled states which are not spin squeezed. Already a 2.4 db gain above shot noise can be obtained when just a single-particle Fock state is injected into the empty input port of a classical interferometer configuration. Higher gains, up to the Heisenberg limit, can be reached with squeezed states of a larger number of particles. We finally study the robustness of this protocol with respect to detection noise.

In this paper we compare the polarization response given by two different chemical potential equalization schemes to be applied to molecular dynamics simulations: the standard fluctuating point charge model (FQ) and the atom–atom charge transfer model (AACT). We have tested the transferability of FQ and AACT parameters, fitted to the polarizability of small size alkanes and polyenes, to large size homologues. We show that the FQ scheme is not adequate for the n-alkanes as it strongly overestimates the polarizability tensor components as the number of carbon atoms increases. The FQ approach has been found more predictive for highly conjugated systems like polyenes, although still unsatisfactory. The AACT parameters tuned on ethane are instead perfectly transferable to alkanes of any length and conformation. The AACT scheme satisfactorily reproduces the polarization response also for highly conjugated systems.

We witness multipartite entanglement in the ground state of the Kitaev chain-a benchmark model of a one dimensional topological superconductor-also with variable-range pairing, using the quantum Fisher information. Phases having a finite winding number, for both short- and long-range pairing, are characterized by a power-law diverging finite-size scaling of multipartite entanglement. Moreover, the occurring quantum phase transitions are sharply marked by the divergence of the derivative of the quantum Fisher information, even in the absence of a closing energy gap.