State Key Laboratory of Loess and Quaternary Geology

Research Article| September 01, 2004 Continuous deformation of the Tibetan Plateau from global positioning system data Pei-Zhen Zhang; Pei-Zhen Zhang 1State Key Laboratory of Earthquake Dynamics, Institute of Geology, Chinese Earthquake Administration, Beijing 100029, China, and State Key Laboratory of Loess and Quaternary Geology, IEE, CAS, Xi'an, China Search for other works by this author on: GSW Google Scholar Zhengkang Shen; Zhengkang Shen 2State Key Laboratory of Earthquake Dynamics, Institute of Geology, Chinese Earthquake Administration, Beijing 100029, China, and Department of Earth and Space Sciences, University of California, Los Angeles, California 90024, USA Search for other works by this author on: GSW Google Scholar Min Wang; Min Wang 3State Key Laboratory of Earthquake Dynamics, Institute of Geology, Chinese Earthquake Administration, Beijing 100029, China Search for other works by this author on: GSW Google Scholar Weijun Gan; Weijun Gan 3State Key Laboratory of Earthquake Dynamics, Institute of Geology, Chinese Earthquake Administration, Beijing 100029, China Search for other works by this author on: GSW Google Scholar Roland Bürgmann; Roland Bürgmann 4Department of Earth and Planetary Science, University of California, Berkeley, California 94720, USA Search for other works by this author on: GSW Google Scholar Peter Molnar; Peter Molnar 5Department of Geological Sciences, and Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, Colorado 80309, USA Search for other works by this author on: GSW Google Scholar Qi Wang; Qi Wang 6Institute of Seismology, Chinese Earthquake Administration, Wuhan 430071, China Search for other works by this author on: GSW Google Scholar Zhijun Niu; Zhijun Niu 7National Earthquake Infrastructure Service, Chinese Earthquake Administration, Beijing 100081, China Search for other works by this author on: GSW Google Scholar Jianzhong Sun; Jianzhong Sun 7National Earthquake Infrastructure Service, Chinese Earthquake Administration, Beijing 100081, China Search for other works by this author on: GSW Google Scholar Jianchun Wu; Jianchun Wu 7National Earthquake Infrastructure Service, Chinese Earthquake Administration, Beijing 100081, China Search for other works by this author on: GSW Google Scholar Sun Hanrong; Sun Hanrong 7National Earthquake Infrastructure Service, Chinese Earthquake Administration, Beijing 100081, China Search for other works by this author on: GSW Google Scholar You Xinzhao You Xinzhao 7National Earthquake Infrastructure Service, Chinese Earthquake Administration, Beijing 100081, China Search for other works by this author on: GSW Google Scholar Author and Article Information Pei-Zhen Zhang 1State Key Laboratory of Earthquake Dynamics, Institute of Geology, Chinese Earthquake Administration, Beijing 100029, China, and State Key Laboratory of Loess and Quaternary Geology, IEE, CAS, Xi'an, China Zhengkang Shen 2State Key Laboratory of Earthquake Dynamics, Institute of Geology, Chinese Earthquake Administration, Beijing 100029, China, and Department of Earth and Space Sciences, University of California, Los Angeles, California 90024, USA Min Wang 3State Key Laboratory of Earthquake Dynamics, Institute of Geology, Chinese Earthquake Administration, Beijing 100029, China Weijun Gan 3State Key Laboratory of Earthquake Dynamics, Institute of Geology, Chinese Earthquake Administration, Beijing 100029, China Roland Bürgmann 4Department of Earth and Planetary Science, University of California, Berkeley, California 94720, USA Peter Molnar 5Department of Geological Sciences, and Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, Colorado 80309, USA Qi Wang 6Institute of Seismology, Chinese Earthquake Administration, Wuhan 430071, China Zhijun Niu 7National Earthquake Infrastructure Service, Chinese Earthquake Administration, Beijing 100081, China Jianzhong Sun 7National Earthquake Infrastructure Service, Chinese Earthquake Administration, Beijing 100081, China Jianchun Wu 7National Earthquake Infrastructure Service, Chinese Earthquake Administration, Beijing 100081, China Sun Hanrong 7National Earthquake Infrastructure Service, Chinese Earthquake Administration, Beijing 100081, China You Xinzhao 7National Earthquake Infrastructure Service, Chinese Earthquake Administration, Beijing 100081, China Publisher: Geological Society of America Received: 12 Feb 2004 Revision Received: 06 May 2004 Accepted: 10 May 2004 First Online: 03 Mar 2017 Online ISSN: 1943-2682 Print ISSN: 0091-7613 Geological Society of America Geology (2004) 32 (9): 809–812. https://doi.org/10.1130/G20554.1 Article history Received: 12 Feb 2004 Revision Received: 06 May 2004 Accepted: 10 May 2004 First Online: 03 Mar 2017 Cite View This Citation Add to Citation Manager Share Icon Share Facebook Twitter LinkedIn MailTo Tools Icon Tools Get Permissions Search Site Citation Pei-Zhen Zhang, Zhengkang Shen, Min Wang, Weijun Gan, Roland Bürgmann, Peter Molnar, Qi Wang, Zhijun Niu, Jianzhong Sun, Jianchun Wu, Sun Hanrong, You Xinzhao; Continuous deformation of the Tibetan Plateau from global positioning system data. Geology 2004;; 32 (9): 809–812. doi: https://doi.org/10.1130/G20554.1 Download citation file: Ris (Zotero) Refmanager EasyBib Bookends Mendeley Papers EndNote RefWorks BibTex toolbar search Search Dropdown Menu toolbar search search input Search input auto suggest filter your search All ContentBy SocietyGeology Search Advanced Search Abstract Global positioning system velocities from 553 control points within the Tibetan Plateau and on its margins show that the present-day tectonics in the plateau is best described as deformation of a continuous medium, at least when averaged over distances of >∼100 km. Deformation occurs throughout the plateau interior by ESE-WNW extension and slightly slower NNE-SSW shortening. Relative to Eurasia, material within the plateau interior moves roughly eastward with speeds that increase toward the east, and then flows southward around the eastern end of the Himalaya. Crustal thickening on the northeastern and eastern margins of the plateau occurs over a zone ∼400 km wide and cannot be the result of elastic strain on a single major thrust fault. Shortening there accommodates much of India's penetration into Eurasia. A description in terms of movements of rigid blocks with elastic strain associated with slip on faults between them cannot match the velocity field. You do not have access to this content, please speak to your institutional administrator if you feel you should have access.

Abstract Rb, Sr, and magnetic susceptibility have been measured in the last interglacial–glacial loess profiles at Luochuan and Huanxian, central China. A high degree of similarity between the parameters in both profiles suggests that variations of Rb/Sr ratios in the sequence can be regarded as an indicator of East Asian summer monsoon strength. Matching the Rb/Sr record with the SPECMAP δ 18 O curve suggests that the Rb/Sr ratio responds sensitively to changes of the East Asian monsoon induced by global ice-volume variation.

Light-absorbing organic carbon (i.e., brown carbon or BrC) in the atmospheric aerosol has significant contribution to light absorption and radiative forcing. However, the link between BrC optical properties and chemical composition remains poorly constrained. In this study, we combine spectrophotometric measurements and chemical analyses of BrC samples collected from July 2008 to June 2009 in urban Xi’an, Northwest China. Elevated BrC was observed in winter (5 times higher than in summer), largely due to increased emissions from wintertime domestic biomass burning. The light absorption coefficient of methanol-soluble BrC at 365 nm (on average approximately twice that of water-soluble BrC) was found to correlate strongly with both parent polycyclic aromatic hydrocarbons (parent-PAHs, 27 species) and their carbonyl oxygenated derivatives (carbonyl-OPAHs, 15 species) in all seasons (r2 > 0.61). These measured parent-PAHs and carbonyl-OPAHs account for on average ∼1.7% of the overall absorption of methanol-soluble BrC, about 5 times higher than their mass fraction in total organic carbon (OC, ∼0.35%). The fractional solar absorption by BrC relative to element carbon (EC) in the ultraviolet range (300–400 nm) is significant during winter (42 ± 18% for water-soluble BrC and 76 ± 29% for methanol-soluble BrC), which may greatly affect the radiative balance and tropospheric photochemistry and therefore the climate and air quality.

Abstract It is a puzzle as to why more severe haze formed during the New Year Holiday in 2020 (NYH‐20), when China was in an unprecedented state of shutdown to contain the coronavirus (COVID‐19) outbreak, than in 2019 (NYH‐19). We performed a comprehensive measurement and modeling analysis of the aerosol chemistry and physics at multiple sites in China (mainly in Shanghai) before, during, and after NYH‐19 and NYH‐20. Much higher secondary aerosol fraction in PM 2.5 were observed during NYH‐20 (73%) than during NYH‐19 (59%). During NYH‐20, PM 2.5 levels correlated significantly with the oxidation ratio of nitrogen ( r 2 = 0.77, p < 0.01), and aged particles from northern China were found to impede atmospheric new particle formation and growth in Shanghai. A markedly enhanced efficiency of nitrate aerosol formation was observed along the transport pathways during NYH‐20, despite the overall low atmospheric NO 2 levels.

were measured in wintertime Beijing, and the total concentrations of 14 trace elements were 1.3-7.3 times higher during severe pollution days than during low pollution days. Fe, Zn, and Pb were the most abundant elements independent of the PM pollution levels. Chemical fractionation shows that Pb, Mn, Cd, As, Sr, Co, V, Cu, and Ni were present mainly in the bioavailable fraction. Positive matrix factorization was used to resolve the sources of particulate trace elements into dust, oil combustion, coal combustion, and traffic-related emissions. Traffic-related emission contributed 65% of total mass of the measured elements during low pollution days. However, coal combustion dominated (58%) during severe pollution days. By combining element-specific health risk analyses and source apportionment results, we conclude that traffic-related emission dominates the health risks by particulate trace elements during low pollution days, while coal combustion becomes equally or even more important during moderate and severe pollution days.

Abstract We performed a global scale analysis of available leaf wax n ‐alkane δ D data compiled from our new results, as well as from the literature and expressed as average values of D/H ratios from three common lipids of n ‐alkanes with odd carbon numbers ( n ‐C 27 , n ‐C 29 , and n ‐C 31 ) from living higher plants. Our results clearly indicate multiple controls of hydrogen isotope composition and its variability in plants leaf wax. (1) At the global scale, precipitation δ D values play a dominating factor that exercises the first order of control for hydrogen isotopic compositions in plant leaf wax. The hydrogen isotopic composition of plant leaf wax tracks the decreasing trend of precipitation δ D with increasing latitude. (2) Because of different water acquisition systems, plant life form influences the hydrogen isotopic composition of leaf wax n ‐alkanes with woody plants and grasses having different responses to the change of global precipitation δ D. (3) Physiological difference, due to different photosynthesis pathways or different water usage strategies, can leave an imprint on δ D patterns of plant leaf waxes, causing δ D variations among plants using the same source water. While these results better explain the variability of hydrogen isotope composition in leaf wax, they also have important implications for the interpretation of n ‐alkane δ D data from fossils and ancient sediments.

The aeolian Red Clay sequence in the central part of the Chinese Loess Plateau was investigated in an attempt to obtain magnetostratigraphic and palaeoclimatic records. From the results, we deduce that aeolian dust accumulation and the related East Asia palaeomonsoon system began at least 7.6 Myr ago, and that the Tibetan Plateau had reached a significant elevation by that time. The Late Tertiary palaeoclimatic history of the Red Clay as reflected by magnetic susceptibility is reconstructed for the time period 7.6–2.5 Ma. Increases in aeolian dust accumulation for the last 7.6 Myr appear to have a close relation with the uplift processes of the Tibetan Plateau. The remarkable increase of aeolian dust accumulation beginning at 3.2 Ma appears to reflect the influence of an increasing global ice volume on the East Asian monsoon and aeolian dust accumulation.

Geological records have shown that the deserts east of the Helan Mountains in northern China were covered by grass during the Holocene Optimum, whereas during marine oxygen isotope stages 2 and 4 distribution of the deserts was almost the same as at present. The wide advance–retreat cycles of the deserts may have exerted an important control on grain-size changes in the loess of the Loess Plateau by altering the distance between the source and the accumulation zone of the loess. This challenges the widely accepted model that winter monsoon winds were the sole factor responsible for spatial and temporal changes in loess texture. To observe spatial changes in sedimentological characteristics of loess during the last glacial–interglacial cycle, the texture of loess was measured along a north–south transect of the Loess Plateau. This transect consists of nine loess sections, starting at Yulin in the transitional region between the Loess Plateau and the Mu Us Desert and ending at Weinan in the southernmost part of the Loess Plateau. Southward changes in sand (>63 μm) content along the transect suggest that variations in desert extent have indeed played a significant role in loess grain-size distributions, particularly in the northern part of the Loess Plateau. It is proposed that sand content (>63 μm%) of loess in the loess–desert transitional zone may be used as a proxy indicator for proximity to the desert margin.

Abstract In southeastern China (SEC), the precipitation amount produced by the East Asian summer monsoon (EASM) is almost equivalent to that during the non-summer monsoon (NSM) period, both of them significantly affecting agriculture and socioeconomy. Here, we present a seasonally-resolved stalagmite δ 18 O record (δ 18 O s ) for the interval 1810–2009 AD from E’mei cave, Jiangxi Province, SEC. The comparison between δ 18 O s and instrumental data indicates that the δ 18 O s variability is primarily controlled by the precipitation seasonality (i.e., the ratio of EASM/NSM precipitation) modulated by the El Niño/Southern Oscillation (ENSO) on interannual to interdecadal timescales. Higher (lower) δ 18 O s values thereby correspond to lower (higher) EASM/NSM ratios associated with El Niño (La Niña) events. Significant correlations with ENSO and the Pacific Decadal Oscillation (PDO) indicate that the precipitation seasonality in SEC is remarkably influenced by ocean-atmosphere interactions, with lower (higher) EASM/NSM ratios during warm (cold) phases of ENSO/PDO. The progressive increase in δ 18 O s since 2005 AD may reflect a strengthening of the central Pacific El Niño under continued anthropogenic global warming. The relationship between seasonal precipitation and δ 18 O s with ENSO/PDO requires further studies.

Abstract. Although the collapses of several Neolithic cultures in China are considered to have been associated with abrupt climate change during the 4.2 ka BP event (4.2–3.9 ka BP), the timing and nature of this event and the spatial distribution of precipitation between northern and southern China are still controversial. The hydroclimate of this event in southeastern China is still poorly known, except for a few published records from the lower reaches of the Yangtze River. In this study, a high-resolution record of monsoon precipitation between 5.3 and 3.57 ka BP based on a stalagmite from Shennong Cave, Jiangxi Province, southeast China, is presented. Coherent variations in δ18O and δ13C reveal that the climate in this part of China was dominantly wet between 5.3 and 4.5 ka BP and mostly dry between 4.5 and 3.57 ka BP, interrupted by a wet interval (4.2–3.9 ka BP). A comparison with other records from monsoonal China suggests that summer monsoon precipitation decreased in northern China but increased in southern China during the 4.2 ka BP event. We propose that the weakened East Asian summer monsoon controlled by the reduced Atlantic Meridional Overturning Circulation resulted in this contrasting distribution of monsoon precipitation between northern and southern China. During the 4.2 ka BP event the rain belt remained longer at its southern position, giving rise to a pronounced humidity gradient between northern and southern China.

Highly oxygenated molecules (HOMs) play an important role in the formation and evolution of secondary organic aerosols (SOA). However, the abundance of HOMs in different environments and their relation to the oxidative potential of fine particulate matter (PM) are largely unknown. Here, we investigated the relative HOM abundance and radical yield of laboratory-generated SOA and fine PM in ambient air ranging from remote forest areas to highly polluted megacities. By electron paramagnetic resonance and mass spectrometric investigations, we found that the relative abundance of HOMs, especially the dimeric and low-volatility types, in ambient fine PM was positively correlated with the formation of radicals in aqueous PM extracts. SOA from photooxidation of isoprene, ozonolysis of α- and β-pinene, and fine PM from tropical (central Amazon) and boreal (Hyytiälä, Finland) forests exhibited a higher HOM abundance and radical yield than SOA from photooxidation of naphthalene and fine PM from urban sites (Beijing, Guangzhou, Mainz, Shanghai, and Xi'an), confirming that HOMs are important constituents of biogenic SOA to generate radicals. Our study provides new insights into the chemical relationship of HOM abundance, composition, and sources with the yield of radicals by laboratory and ambient aerosols, enabling better quantification of the component-specific contribution of source- or site-specific fine PM to its climate and health effects.

Abstract. The sources, formation mechanism and amount of organosulfates (OS) in atmospheric aerosol are not yet well understood, partly due to the lack of authentic standards for quantification. In this study, we report an improved robust procedure for the synthesis of organosulfates with different functional groups. Nine authentic organosulfate standards were synthesized and four standards (benzyl sulfate, phenyl sulfate, glycolic acid sulfate, and hydroxyacetone sulfate) were used to quantify their ambient concentrations. The authentic standards and ambient aerosol samples were analyzed using an optimized ultra performance liquid chromatography–electrospray ionization-tandem mass spectrometric method (UPLC–ESI–MS/MS). The recovery ranged from 80.4 to 93.2 %, the limits of detection and limits of quantification obtained were 1.1–16.7 and 3.4–55.6 pg m−3, respectively. Measurements of ambient aerosol particle samples collected in winter 2013/2014 in urban Xi'an, northwestern China, show that glycolic acid sulfate (77.3 ± 49.2 ng m−3) is the most abundant species of the identified organosulfates followed by hydroxyacetone sulfate (1.3 ± 0.5 ng m−3), phenyl sulfate (0.14 ± 0.09 ng m−3), and benzyl sulfate (0.04 ± 0.01 ng m−3). Except for hydroxyacetone sulfate, which seems to form mainly from biogenic emissions in this region, the organosulfates quantified during winter in Xi'an show an increasing trend with an increase in the mass concentrations of organic carbon indicating their anthropogenic origin.

Abstract. Air pollution by particulate matter in China affects human health, the ecosystem and the climate. However, the chemical composition of particulate aerosol, especially of the organic fraction, is still not well understood. In this study, particulate aerosol samples with a diameter of ≤2.5 µm (PM2.5) were collected in January 2014 in three cities located in northeast, east and southeast China, namely Changchun, Shanghai and Guangzhou. Organic aerosol (OA) in the PM2.5 samples was analyzed by an ultrahigh-performance liquid chromatograph (UHPLC) coupled to a high-resolution Orbitrap mass spectrometer in both negative mode (ESI-) and positive mode electrospray ionization (ESI+). After non-target screening including the assignment of molecular formulas, the compounds were classified into five groups based on their elemental composition, i.e., CHO, CHON, CHN, CHOS and CHONS. The CHO, CHON and CHN groups present the dominant signal abundances of 81 %–99.7 % in the mass spectra and the majority of these compounds were assigned to mono- and polyaromatics, suggesting that anthropogenic emissions are a major source of urban OA in all three cities. However, the chemical characteristics of these compounds varied between the different cities. The degree of aromaticity and the number of polyaromatic compounds were substantially higher in samples from Changchun, which could be attributed to the large emissions from residential heating (i.e., coal combustion) during wintertime in northeast China. Moreover, the ESI- analysis showed higher H/C and O/C ratios for organic compounds in Shanghai and Guangzhou compared to samples from Changchun, indicating that OA undergoes more intense photochemical oxidation processes in lower-latitude regions of China and/or is affected to a larger degree by biogenic sources. The majority of sulfur-containing compounds (CHOS and CHONS) in all cities were assigned to aliphatic compounds with low degrees of unsaturation and aromaticity. Here again, samples from Shanghai and Guangzhou show a greater chemical similarity but differ largely from those from Changchun. It should be noted that the conclusions drawn in this study are mainly based on comparison of molecular formulas weighted by peak abundance and thus are associated with inherent uncertainties due to different ionization efficiencies for different organic species.

Leaf wax δDn-alkane values have shown to differ significantly among plant life forms (e.g., among grasses, shrubs, and trees) in higher plants. However, the underlying causes for the differences in leaf wax δDn-alkane values among different plant life forms remain poorly understood. In this study, we observed that leaf wax δDn-alkane values between major high plant lineages (eudicots versus monocots) differed significantly under the same environmental conditions. Such a difference primarily inherited from different hydrogen biosynthetic fractionations (εwax-lw). Based upon a reanalysis of the available leaf wax δDn-alkane dataset from modern plants in the Northern Hemisphere, we discovered that the apparent hydrogen fractionation factor (εwax-p) between leaf wax δDn-alkane values of major angiosperm lineages and precipitation δD values exhibited distinguishable distribution patterns at a global scale, with an average of -140‰ for monocotyledonous species, -107‰ for dicotyledonous species. Additionally, variations of leaf wax δDn-alkane values and the εwax-p values in gymnosperms are similar to those of dicotyledonous species. Therefore, the data let us believe that biological factors inherited from plant taxonomies have a significant effect on controlling leaf wax δDn-alkane values in higher plants.

ICP-MS is becoming a competitive technique for measurement of plutonium isotopes. Besides the abundance sensitivity (tailing of 238U to m/z = 239 and 240), isobaric and polyatomic ions interferences (e.g., 238U1H+) are the most critical challenges for determination of low-level plutonium in high uranium samples. This work presents a new method to solve this problem using ICP-MS with two tandem quadrupole separators and a dynamic collision/reaction cell combined with chemical separation. The interference of uranium hydrides (238U1H+ and 238U1H2+) was effectively eliminated using CO2 as reaction gas by converting hydrides to oxides of uranium ions (UO+/UO2+) but still keeping the intensity of the Pu+ signal. The tailing interference of 238U+ (abundance sensitivity) was intensively eliminated by significantly suppressing the 238U+ signal using CO2 as reaction gas and using two tandem quadrupole mass separators in the ICP-MS/MS. With these approaches the overall interference of uranium was reduced to <1 × 10–8, which is 3 orders of magnitude better than the conventional ICP-MS. Combined with chemical separation with a decontamination factor of 105 for uranium, an overall factor of 1012 for elimination of uranium interference was achieved. The developed method was demonstrated to enable accurate determination of <10–15 g/g level plutonium isotopes in environmental samples even in a uranium debris sample with a U/Pu atomic ratio of up to 1012. The developed method was validated by analysis of a spiked solution and certified reference materials of soil.

Stalagmite laminae provide a high-resolution geological record of climate change. In this paper, moving spectral analysis is used to analyse a stalagmite lamina thickness record to study climatic variability. It was found that the dominant cycles of the lamina thickness sequence are 2, 3.3, 5–6, 10–12, 14–18, 133 and 194 years. Some of the cycles are the same as the cycles of modern climatic indices, such as the QBO (Quasi Biennial Oscillation) of 2 years, the QTO (Quasi Triple-year Oscillation) cycle of about 3.5 years, the QFO (Quasi Five-year Oscillation) cycle of 5–6 years and the QEO (Quasi Eleven-year Oscillation) cycle of 11 years. It was also found that there are different dominant cycles in different time periods. Usually, the dominant cycles are stronger in wet periods when the microlaminae are thicker. In dry periods, the microlaminae are thinner and the power of the dominant cycles is also weaker. Another feature is that the power of the dominant cycles and their long-term periods and frequencies appear to change. These phenomena are important for understanding the climatic changes in Beijing area over the last 1 ka.

Abstract. Although there are many studies of particulate matter (PM) pollution in Beijing, the sources and processes of secondary PM species during haze periods remain unclear. Limited studies have investigated the PM formation in highly polluted environments under low- and high-relative-humidity (RH) conditions. Herein, we present a systematic comparison of species in submicron particles (PM1) in wintertime Beijing (29 December 2014 to 28 February 2015) for clean periods and pollution periods under low- and high-RH conditions. PM1 species were measured with an aerosol chemical species monitor (ACSM) and an Aethalometer. Sources and processes for organic aerosol (OA) were resolved by positive matrix factorization (PMF) with a multilinear engine 2 (ME-2). The comparisons for clean, low-RH pollution and high-RH pollution periods are made from three different aspects, namely (a) mass concentration, (b) mass fraction and (c) growth rate in diurnal profiles. OA is the dominant component of PM1, with an average mass concentration of 56.7 µg m−3 (46 %) during high-RH pollution and 67.7 µg m−3 (54 %) during low-RH pollution periods. Sulfate had higher concentration and mass fraction during high-RH pollution periods, while nitrate had higher concentration and mass fraction during low-RH pollution periods. The diurnal variations of nitrate and oxygenated organic aerosol (OOA) showed a daytime increase in their concentrations during all three types of periods. Nitrate had similar growth rates during low-RH (0.40 µg m−3 h−1) and high-RH (0.55 µg m−3 h−1) pollution periods. OOA had a higher growth rate during low-RH pollution periods (1.0 µg m−3 h−1) than during high-RH pollution periods (0.40 µg m−3 h−1). In contrast, sulfate had a decreasing trend during low-RH pollution periods, while it increased significantly with a growth rate of 0.81 µg m−3 h−1 during high-RH pollution periods. These distinctions in mass concentrations, mass fractions and daytime growth rates may be explained by the difference in the formation processes affected by meteorological conditions. In particular, photochemical oxidation and aqueous-phase processes may both produce sulfate and nitrate. The relative importance of the two pathways, however, differs under different meteorological conditions. Additional OOA formation under high-RH (&gt; 70 %) conditions suggests aqueous-related formation pathways. This study provides a general picture of the haze formation in Beijing under different meteorological conditions.

Abstract. Hygroscopicity largely affects environmental and climatic impacts of pollen grains, one important type of primary biological aerosol particles in the troposphere. However, our knowledge of pollen hygroscopicity is rather limited, and the effect of temperature in particular has rarely been explored before. In this work three different techniques, including a vapor sorption analyzer, diffusion reflectance infrared Fourier transform spectroscopy (DRIFTS) and transmission Fourier transform infrared spectroscopy (transmission FTIR) were employed to characterize six anemophilous pollen species and to investigate their hygroscopic properties as a function of relative humidity (RH, up to 95 %) and temperature (5 or 15, 25 and 37 ∘C). Substantial mass increase due to water uptake was observed for all the six pollen species, and at 25 ∘C the relative mass increase at 90 % RH, when compared to that at &lt;1 % RH, ranged from ∼30 % to ∼50 %, varying with pollen species. It was found that the modified κ-Köhler equation can well approximate mass hygroscopic growth of all the six pollen species, and the single hygroscopicity parameter (κ) was determined to be in the range of 0.034±0.001 to 0.061±0.007 at 25 ∘C. In situ DRIFTS measurements suggested that water adsorption by pollen species was mainly contributed to by OH groups of organic compounds they contained, and good correlations were indeed found between hygroscopicity of pollen species and the number of OH groups, as determined using transmission FTIR. An increase in temperature would in general lead to a decrease in hygroscopicity, except for pecan pollen. For example, κ values decreased from 0.073±0.006 at 5 ∘C to 0.061±0.007 at 25 ∘C and to 0.057±0.004 at 37 ∘C for Populus tremuloides pollen, and decreased from 0.060±0.001 at 15 ∘C to 0.054±0.001 at 25 ∘C and 0.050±0.002 at 37 ∘C for paper mulberry pollen.

A relatively cold period, the ‘Little Ice Age’ (LIA), just prior to the current warm period, has been documented from many regions of the globe. However, hydrological changes (wet/dry conditions) during the LIA appear to be very different across different climatic regimes, suggesting that the position, strength and/or pattern of atmospheric circulation could have changed significantly in the past. Therefore, paleohydrological studies may have some implications for potential future hydrological changes in an anticipated warming world. In this study, we investigated hydrological changes over the last ~800 years in the arid Tarim Basin, northwestern China. We used carbon isotopes of plant remains (mainly leaves) from a 10.5 m long aeolian sand sediment section to evaluate changes in dry/wet conditions. The average value of carbon isotopes of plant remains during the LIA period (~AD 1490 to 1890) is −26.0‰, ranging from −28.2‰ to −23.6‰, much lower than values before (average of −24.3‰, from −25.5‰ to −22.4‰) and after this period (average of −22.8‰, −24.6‰ to −21.6‰). Although other environmental factors could also affect carbon isotopes to some degree, such consistent, large negative isotopic excursions of up to 6‰ strongly suggest a wetter climatic condition in the study area at that time, which is also consistent with two silty clay layers, indicating a wet depositional environment, found around AD 1560 and AD 1625 during the LIA period. This inference is consistent with previous studies suggesting a relatively wet period during the LIA in the Tarim Basin and possibly extending to the western central Asia region, but appears to be opposite to hydrological changes in regions that are today dominated by Asian monsoon systems. This pattern of regional hydrological changes may be related to possible changes in the trajectory or strength of the westerlies and/or the orographic effect in this region, as previous studies suggested.

Abstract. The use of branched glycerol dialkyl glycerol tetraethers (bGDGTs) in loess–palaeosol sequences (LPSs) has shown promises in continental palaeotemperature reconstructions. Thus far, however, little is known about the effect of soil moisture on their distributions in the water-limited Chinese Loess Plateau (CLP). In this study, the relationships between environmental variables and the cyclization of branched tetraethers (CBT) were investigated in arid–subhumid China using 97 surface soils in the CLP and its vicinity, as well as 78 soils with pH &gt; 7 which have been previously published. We find that CBT correlates best with soil water content (SWC) or mean annual precipitation (MAP) for the overall data set. This indicates that CBT is mainly controlled by soil moisture instead of soil pH in alkaline soils from arid–subhumid regions, where water availability is a limiting factor for the producers of bGDGTs. Therefore, we suggest that CBT can potentially be used as a palaeorainfall proxy on the alkaline CLP. According to the preliminary CBT–MAP relationship for modern CLP soils (CBT = −0.0021 × MAP + 1.7, n = 37, r = −0.93), palaeorainfall history was reconstructed from three LPSs (Yuanbao, Lantian, and Mangshan) with published bGDGT data spanning the past 70 ka. The CBT-derived MAP records of the three sites consistently show precession-driven variation resembling the monsoon record based on speleothem δ18O, supporting CBT as a reasonable proxy for palaeorainfall reconstruction in LPS. The direct application of CBT as a palaeorainfall proxy in corroboration with the bGDGT-based temperature proxy may enable us to further assess the temperature/hydrological association for palaeoclimate studies on the CLP.