State Key Laboratory of Quantum Optics and Quantum Optics Devices

In this Letter, we report the first experimental realization and investigation of a spin-orbit coupled Fermi gas. Both spin dephasing in spin dynamics and momentum distribution asymmetry of the equilibrium state are observed as hallmarks of spin-orbit coupling in a Fermi gas. The single particle dispersion is mapped out by using momentum-resolved radio-frequency spectroscopy. From momentum distribution and momentum-resolved radio-frequency spectroscopy, we observe the change of fermion population in different helicity branches consistent with a finite temperature calculation, which indicates that a Lifshitz transition of the Fermi surface topology change can be found by further cooling the system.

Highly efficient quantum dense coding for continuous variables has been experimentally accomplished by means of exploiting a bright Einstein-Podolsky-Rosen (EPR) beam with anticorrelation of amplitude quadratures and correlation of phase quadratures. Two bits of classical information are encoded on two quadratures of a half of a bright EPR beam, then are simultaneously decoded by the other half of the EPR beam with the sensitivities beyond that of the shot noise limit. A high degree of immunity to unauthorized eavesdropping has been experimentally demonstrated.

Quartz-enhanced photoacoustic spectroscopy (QEPAS) is a sensitive gas detection technique which requires frequent calibration and has a long response time. Here we report beat frequency (BF) QEPAS that can be used for ultra-sensitive calibration-free trace-gas detection and fast spectral scan applications. The resonance frequency and Q-factor of the quartz tuning fork (QTF) as well as the trace-gas concentration can be obtained simultaneously by detecting the beat frequency signal generated when the transient response signal of the QTF is demodulated at its non-resonance frequency. Hence, BF-QEPAS avoids a calibration process and permits continuous monitoring of a targeted trace gas. Three semiconductor lasers were selected as the excitation source to verify the performance of the BF-QEPAS technique. The BF-QEPAS method is capable of measuring lower trace-gas concentration levels with shorter averaging times as compared to conventional PAS and QEPAS techniques and determines the electrical QTF parameters precisely.

Optical diodes controlling the flow of light are of principal significance for optical information processing. They transmit light from an input to an output, but not in the reverse direction. This breaking of time reversal symmetry is conventionally achieved via Faraday or nonlinear effects. For applications in a quantum network, features such as the abilities of all-optical control, on-chip integration, and single-photon operation are important. Here we propose an all-optical optical diode which requires neither magnetic fields nor strong input fields. It is based on a "moving" photonic crystal generated in a three-level electromagnetically induced transparency medium in which the refractive index of a weak probe is modulated by the moving periodic intensity of a strong standing coupling field with two detuned counterpropagating components. Because of the Doppler effect, the frequency range of the crystal's band gap for the probe copropagating with the moving crystal is shifted from that for the counterpropagating probe. This mechanism is experimentally demonstrated in a room temperature Cs vapor cell.

A tripartite entangled state of bright optical field is experimentally produced using an Einstein-Podolsky-Rosen entangled state for continuous variables and linear optics. The controlled dense coding among a sender, a receiver, and a controller is demonstrated by exploiting the tripartite entanglement. The obtained three-mode "position" correlation and relative "momentum" correlation between the sender and the receiver, and thus the improvements of the measured signal to noise ratios of amplitude and phase signals with respect to the shot noise limit are 3.28 and 3.18 dB, respectively. If the mean photon number n equals 11 the channel capacity can be controllably inverted between 2.91 and 3.14. When n is larger than 1.0 and 10.52, the channel capacity of the controlled dense coding is predicted to exceed the ideal single channel capacity of coherent and squeezed state light communication, respectively.

We present a continuous-variable (CV) Gaussian analog of cluster states, a new class of CV multipartite entangled states that can be generated from squeezing and quantum nondemolition coupling ${H}_{I}=\ensuremath{\hbar}\ensuremath{\chi}{X}_{A}{X}_{B}$. The entanglement properties of these states are studied in terms of classical communication and local operations. The graph states as general forms of the cluster states are presented. A chain for a one-dimensional example of cluster states can be readily experimentally produced only with squeezed light and beam splitters.

We propose a scheme for transferring quantum states from the propagating light fields to macroscopic, collective vibrational degree of freedom of a massive mirror by exploiting radiation pressure effects. This scheme may prepare an Einstein-Podolsky-Rosen state in position and momentum of a pair of distantly separated movable mirrors by utilizing the entangled light fields produced from a nondegenerate optical parametric amplifier.

Although many emerging new phenomena have been unraveled in two dimensional (2D) materials with long-range spin orderings, the usually low critical temperature in van der Waals (vdW) magnetic material has thus far hindered the related practical applications. Here, we show that ferromagnetism can hold above 300 K in a metallic phase of 1T-CrTe2 down to the ultra-thin limit. It thus makes CrTe2 so far the only known exfoliated ultra-thin vdW magnets with intrinsic long-range magnetic ordering above room temperature. An in-plane room-temperature negative anisotropic magnetoresistance (AMR) was obtained in ultra-thin CrTe2 devices, with a sign change in the AMR at lower temperature, with −0.6% and +5% at 300 and 10 K, respectively. Our findings provide insights into magnetism in ultra-thin CrTe2, expanding the vdW crystals toolbox for future room-temperature spintronic applications.

Chirality plays an important role in chemistry, biology, and materials science. The recent discovery of the B40(-/0) borospherenes marks the onset of a class of boron-based nanostructures. Here we report the observation of axially chiral borospherene in the B(39)(-) nanocluster on the bases of photoelectron spectroscopy, global minimum searches, and electronic structure calculations. Extensive structural searches in combination with density functional and CCSD(T) calculations show that B(39)(-) has a C3 cage global minimum with a close-lying C2 cage isomer. Both the C3 and C2 B(39)(-) cages are chiral with degenerate enantiomers. The C3 global minimum consists of three hexagons and three heptagons around the vertical C3 axis. The C2 isomer is built on two hexagons on the top and at the bottom of the cage with four heptagons around the waist. Both the C3 and C2 axially chiral isomers of B(39)(-) are present in the experiment and contribute to the observed photoelectron spectrum. The chiral borospherenes also exhibit three-dimensional aromaticity, featuring σ and π double delocalization for all valence electrons. Molecular dynamics simulations reveal that these chiral B(39)(-) cages are structurally fluxional above room temperature, compared to the highly robust D(2d)B40 borospherene. The current findings add chiral members to the borospherene family and indicate the structural diversity of boron-based nanomaterials.

The cluster states and Greenberger-Horne-Zeilinger (GHZ) states are two different types of multipartite quantum entangled states. We present the first experimental results generating continuous variable quadripartite cluster and GHZ entangled states of electromagnetic fields. Utilizing two amplitude-quadrature and two phase-quadrature squeezed states of light and linearly optical transformations, the two types of entangled states for amplitude and phase quadratures of light are experimentally produced. The combinations of the measured quadrature variances prove the full inseparability of the generated four subsystems. The presented experimental schemes show that the multipartite entanglement of continuous variables can be deterministically generated with the relatively simple implementation.

The unconditional entanglement swapping for continuous variables is experimentally demonstrated. Two initial entangled states are produced from two nondegenerate optical parametric amplifiers operating at de-amplification. Through implementing the direct measurement of the Bell-state between two optical beams from each amplifier the remaining two optical beams, which have never directly interacted with each other, are entangled. The quantum correlation degrees of 1.23 and 1.12 dB below the shot noise limit for the amplitude and phase quadratures resulting from the entanglement swapping are measured straightly.

Abstract State-of-the-art atomic clocks are based on the precise detection of the energy difference between two atomic levels, which is measured in terms of the quantum phase accumulated over a given time interval1–4. The stability of optical-lattice clocks (OLCs) is limited both by the interrupted interrogation of the atomic system by the local-oscillator laser (Dick noise5) and by the standard quantum limit (SQL) that arises from the quantum noise associated with discrete measurement outcomes. Although schemes for removing the Dick noise have been recently proposed and implemented4, 6–8, performance beyond the SQL by engineering quantum correlations (entanglement) between atoms9–20 has been demonstrated only in proof-of-principle experiments with microwave clocks of limited stability. The generation of entanglement on an optical-clock transition and operation of an OLC beyond the SQL represent important goals in quantum metrology, but have not yet been demonstrated experimentally16. Here we report the creation of a many-atom entangled state on an OLC transition, and use it to demonstrate a Ramsey sequence with an Allan deviation below the SQL after subtraction of the local-oscillator noise. We achieve a metrological gain of $$4.{4}_{-0.4}^{+0.6}$$ 4 . 4 - 0 . 4 + 0 . 6 decibels over the SQL by using an ensemble consisting of a few hundred ytterbium-171 atoms, corresponding to a reduction of the averaging time by a factor of 2.8 ± 0.3. Our results are currently limited by the phase noise of the local oscillator and Dick noise, but demonstrate the possible performance improvement in state-of-the-art OLCs1–4 through the use of entanglement. This will enable further advances in timekeeping precision and accuracy, with many scientific and technological applications, including precision tests of the fundamental laws of physics21–23, geodesy24–26 and gravitational-wave detection27.

This review aims to discuss the latest advancements in quartz-enhanced photoacoustic spectroscopy (QEPAS) based trace-gas sensing. Starting from the QEPAS basic physical principles, the most used QEPAS configurations will be described. This is followed by a detailed theoretical analysis and experimental study regarding the influence of quartz tuning forks (QTFs) geometry on their optoacoustic transducer performance. Furthermore, an overview of the latest developments in QEPAS trace-gas sensor technology employing custom QTFs will be reported. Results obtained by exploiting novel micro-resonator configurations, capable of increasing the QEPAS signal-to-noise ratio by more than two orders of magnitude and the utilization of QTF overtone flexural modes for QEPAS based sensing will be presented. A comparison of the QEPAS performance of different spectrophone configurations is reported based upon signal-to-noise ratio. Finally, a novel QEPAS approach allowing simultaneous dual-gas detection will be described.

concentration measurements with a 3.7-W power consumption.

Laser-induced breakdown spectroscopy (LIBS) has been widely studied due to its unique advantages such as remote sensing, real-time multi-elemental detection and none-to-little damage. With the efforts of researchers around the world, LIBS has been developed by leaps and bounds. Moreover, in recent years, more and more Chinese LIBS researchers have put tremendous energy in promoting LIBS applications. It is worth mentioning that the application of LIBS in a specific field has its special application background and technical difficulties, therefore it may develop in different stages. A review summarizing the current development status of LIBS in various fields would be helpful for the development of LIBS technology as well as its applications especially for Chinese LIBS community since most of the researchers in this field work in application. In the present work, we summarized the research status and latest progress of main research groups in coal, metallurgy, and water, etc. Based on the current research status, the challenges and opportunities of LIBS were evaluated, and suggestions were made to further promote LIBS applications.

Multi-gas detection represents a suitable solution in many applications, such as environmental and atmospheric monitoring, chemical reaction and industrial process control, safety and security, oil&gas and biomedicine. Among optical techniques, Quartz-Enhanced Photoacoustic Spectroscopy (QEPAS) has been demonstrated to be a leading-edge technology for addressing multi-gas detection, thanks to the modularity, ruggedness, portability and real time operation of the QEPAS sensors. The detection module consists in a spectrophone, mounted in a vacuum-tight cell and detecting sound waves generated via photoacoustic excitation within the gas sample. As a result, the sound detection is wavelength-independent and the volume of the absorption cell is basically determined by the spectrophone dimensions, typically in the order of few cubic centimeters. In this review paper, the implementation of the QEPAS technique for multi-gas detection will be discussed for three main areas of applications: i) multi-gas trace sensing by exploiting non-interfering absorption features; ii) multi-gas detection dealing with overlapping absorption bands; iii) multi-gas detection in fluctuating backgrounds. The fundamental role of the analysis and statistical tools will be also discussed in detail in relation with the specific applications. This overview on QEPAS technique, highlighting merits and drawbacks, aims at providing ready-to-use guidelines for multi-gas detection in a wide range of applications and operating conditions.

This review article forms a guideline for LIBS contribution in coal analysis, encompassing fundamental aspects, operation modes, data processing, and analytical results. LIBS applications related to coal utilization are also highlighted (fly ash analysis and combustion monitoring).

We report a first-principles theoretical approach for analyzing linear and circular photogalvanic effects (PGEs) based on density functional theory within the nonequilibrium Green's function formalism. Using this approach we investigate the PGE phenomena in monolayer black phosphorus (MBP) doped with sulfur atoms. The impurity doping breaks the space inversion symmetry of pristine MBP, leading to a C s symmetry with a mirror reflection plane normal to the zigzag direction of the MBP lattice. Governed by this symmetry, a linear PGE is induced in both zigzag and armchair directions, and a circular PGE is induced along the zigzag direction. A robust broadband photoresponse is found from the near-infrared to the visible range for the MBP device. There is a strong anisotropy in PGE: photoresponse in the zigzag direction can be larger by an order of magnitude than that in the armchair direction. We identify the origin of the observed PGE as the inter-band transitions from the impurity and valence bands to the conduction bands, which involves a transfer of angular momentum from photons to electrons.

Free-standing boron nanocages or borospherenes have been observed recently for B40− and B40. There is evidence that a family of borospherenes may exist. However, the smallest borospherene is still not known. Here, we report experimental and computational evidence of a seashell-like borospherene cage for B28− and B28. Photoelectron spectrum of B28− indicated contributions from different isomers. Theoretical calculations showed that the seashell-like B28− borospherene is competing for the global minimum with a planar isomer and it is shown to be present in the cluster beam, contributing to the observed photoelectron spectrum. The seashell structure is found to be the global minimum for neutral B28 and the B28− cage represents the smallest borospherene observed to date. It is composed of two triangular close-packed B15 sheets, interconnected via the three corners by sharing two boron atoms. The B28 borospherene was found to obey the 2(n + 1)2 electron-counting rule for spherical aromaticity.

The measurement sensitivity of quantum probes using N uncorrelated particles is restricted by the standard quantum limit1, which is proportional to $$1/\sqrt{N}$$. This limit, however, can be overcome by exploiting quantum entangled states, such as spin-squeezed states2. Here we report the measurement-based generation of a quantum state that exceeds the standard quantum limit for probing the collective spin of 1011 rubidium atoms contained in a macroscopic vapour cell. The state is prepared and verified by sequences of stroboscopic quantum non-demolition (QND) measurements. We then apply the theory of past quantum states3,4 to obtain spin state information from the outcomes of both earlier and later QND measurements. Rather than establishing a physically squeezed state in the laboratory, the past quantum state represents the combined system information from these prediction and retrodiction measurements. This information is equivalent to a noise reduction of 5.6 decibels and a metrologically relevant squeezing of 4.5 decibels relative to the coherent spin state. The past quantum state yields tighter constraints on the spin component than those obtained by conventional QND measurements. Our measurement uses 1,000 times more atoms than previous squeezing experiments5–10, with a corresponding angular variance of the squeezed collective spin of 4.6 × 10−13 radians squared. Although this work is rooted in the foundational theory of quantum measurements, it may find practical use in quantum metrology and quantum parameter estimation, as we demonstrate by applying our protocol to quantum enhanced atomic magnetometry. A squeezed collective state of 1011 rubidium atoms is generated by quantum non-demolition measurements, and the accuracy of the estimation of their collective spin is improved using past quantum state retrodiction.