United States Air Force Research Laboratory

High entropy alloys (HEAs) are barely 12 years old. The field has stimulated new ideas and has inspired the exploration of the vast composition space offered by multi-principal element alloys (MPEAs). Here we present a critical review of this field, with the intent of summarizing key findings, uncovering major trends and providing guidance for future efforts. Major themes in this assessment include definition of terms; thermodynamic analysis of complex, concentrated alloys (CCAs); taxonomy of current alloy families; microstructures; mechanical properties; potential applications; and future efforts. Based on detailed analyses, the following major results emerge. Although classical thermodynamic concepts are unchanged, trends in MPEAs can be different than in simpler alloys. Common thermodynamic perceptions can be misleading and new trends are described. From a strong focus on 3d transition metal alloys, there are now seven distinct CCA families. A new theme of designing alloy families by selecting elements to achieve a specific, intended purpose is starting to emerge. A comprehensive microstructural assessment is performed using three datasets: experimental data drawn from 408 different alloys and two computational datasets generated using the CALculated PHAse Diagram (CALPHAD) method. Each dataset emphasizes different elements and shows different microstructural trends. Trends in these three datasets are all predicted by a ‘structure in – structure out’ (SISO) analysis developed here that uses the weighted fractions of the constituent element crystal structures in each dataset. A total of 13 distinct multi-principal element single-phase fields are found in this microstructural assessment. Relationships between composition, microstructure and properties are established for 3d transition metal MPEAs, including the roles of Al, Cr and Cu. Critical evaluation shows that commercial austenitic stainless steels and nickel alloys with 3 or more principal elements are MPEAs, as well as some established functional materials. Mechanical properties of 3d transition metal CCAs are equivalent to commercial austenitic stainless steels and nickel alloys, while some refractory metal CCAs show potential to extend the service strength and/or temperature of nickel superalloys. Detailed analyses of microstructures and properties allow two major HEA hypotheses to be resolved. Although the ‘entropy effect’ is not supported by the present data, it has nevertheless made an enduring contribution by inspiring a clearer understanding of the importance of configurational entropy on phase stability. The ‘sluggish diffusion’ hypothesis is also not supported by available data, but it motivates re-evaluation of a classical concept of metallic diffusion. Building on recent published work, the CCA field has expanded to include materials with metallic, ionic or covalent bonding. It also includes microstructures with any number of phases and any type of phases. Finally, the MPEA field is shown to include both structural and functional materials applications. A significant number of future efforts are recommended, with an emphasis on developing high-throughput experiments and computations for structural materials. The review concludes with a brief description of major accomplishments of the field and insights gained from the first 12 years of research. The field has lost none of its potency and continues to pose new questions and offer new possibilities. The vast range of complex compositions and microstructures remains the most compelling motivation for future studies.

Wind and temperature profiles for a wide range of stability conditions have been analyzed in the context of Monin-Obukhov similarity theory. Direct measurements of heat and momentum fluxes enabled determination of the Obukhov length L, a key independent variable in the steady-state, horizontally homogeneous, atmospheric surface layer. The free constants in several interpolation formulas can be adjusted to give excellent fits to the wind and temperature gradient data. The behavior of the gradients under neutral conditions is unusual, however, and indicates that von Kármán's constant is ∼0.35, rather than 0.40 as usually assumed, and that the ratio of eddy diffusivities for heat and momentum at neutrality is ∼1.35, compared to the often-suggested value of 1.0. The gradient Richardson number, computed from the profiles, and the Obukhov stability parameter z/L, computed from the measured fluxes, are found to be related approximately linearly under unstable conditions. For stable conditions the Richard on number approaches a limit of ∼0.21 as stability increases. A comparison between profile-derived and measured fluxes shows good agreement over the entire stability range of the observations.

Abstract The behaviour of spectra and cospectra of turbulence in the surface layer is described within the framework of similarity theory using wind and temperature fluctuation data obtained in the 1968 AFCRL Kansas experiments. With appropriate normalization, the spectra and cospectra are each reduced to a family of curves which spread out according to z/L at low frequencies but converge to a single universal curve in the inertial subrange. The paper compares these results with data obtained by other investigators over both land and water. Spectral constants for velocity and temperature are determined and the variability in the recent estimates of the constants is discussed. The high‐frequency behaviour is consistent with local isotropy. In the inertial subrange, where the spectra fall as n −5/3 , the cospectra fall faster: uω and ωθ as n −7/3 , and u θ, on the average, as n −5/2 . The 4/3 ratio between the transverse and longitudinal spectral levels is observed at wavelengths of the order of the height above ground under unstable conditions and at wavelengths of the order of L/10 under stable conditions. This lower isotropic limit is shown to be governed by the combined effects of shear and buoyancy on small‐scale eddies.

This paper reviews some main results and progress in distributed multi-agent coordination, focusing on papers published in major control systems and robotics journals since 2006. Distributed coordination of multiple vehicles, including unmanned aerial vehicles, unmanned ground vehicles, and unmanned underwater vehicles, has been a very active research subject studied extensively by the systems and control community. The recent results in this area are categorized into several directions, such as consensus, formation control, optimization, and estimation. After the review, a short discussion section is included to summarize the existing research and to propose several promising research directions along with some open problems that are deemed important for further investigations.

abstract A matrix formalism developed by W. T. Thomson is used to obtain the phase velocity dispersion equations for elastic surface waves of Rayleigh and Love type on multilayered solid media. The method is used to compute phase and group velocities of Rayleigh waves for two assumed three-layer models and one two-layer model of the earth's crust in the continents. The computed group velocity curves are compared with published values of the group velocities at various frequencies of Rayleigh waves over continental paths. The scatter of the observed values is larger than the difference between the three computed curves. It is believed that not all of this scatter is due to observational errors, but probably represents a real horizontal heterogeneity of the continental crusts.

The pace of the development of silicon photonics has quickened since 2004 due to investment by industry and government. Commercial state-of-the-art CMOS silicon-on-insulator (SOI) foundries are now being utilized in a crucial test of 1.55-mum monolithic optoelectronic (OE) integration, a test sponsored by the Defense Advanced Research Projects Agency (DARPA). The preliminary results indicate that the silicon photonics are truly CMOS compatible. R&D groups have now developed 10-100-Gb/s electro-optic modulators, ultrafast Ge-on-Si photodetectors, efficient fiber-to-waveguide couplers, and Si Raman lasers. Electrically pumped silicon lasers are under intense investigation, with several approaches being tried; however, lasing has not yet been attained. The new paradigm for the Si-based photonic and optoelectric integrated circuits is that these chip-scale networks, when suitably designed, will operate at a wavelength anywhere within the broad spectral range of 1.2-100 mum, with cryocooling needed in some cases

A matrix formalism developed by W. T. Thomson is used to obtain the phase velocity dispersion equations for elastic surface waves of Rayleigh and Love type on multilayered solid media. The method is used to compute phase and group velocities of Rayleigh waves for two assumed three-layer models and one two-layer model of the earth's crust in the continents. The computed group velocity curves are compared with published values of the group velocities at various frequencies of Rayleigh waves over continental paths. The scatter of the observed values is larger than the difference between the three computed curves. It is believed that not all of this scatter is due to observational errors, but probably represents a real horizontal heterogeneity of the continental crusts.

In a continuing study, three-dimensional elasticity solutions are constructed for rectangular laminates with pinned edges. The lamina tion geometry treated consists of arbitrary numbers of layers which can be isotropic or orthotropic with material symmetry axes parallel to the plate axes. Several specific example problems are solved, in cluding a sandwich plate, and compared to the analogous results in classical laminated plate theory.

Two related criteria based on stress distribution are presented for predicting the uniaxial tensile strength of laminated composites containing through the thickness discontinuities of a general shape. The criteria result in two parameter (unnotched tensile strength and a characteristic dimension) models which are capable of predicting observed discontinuity size effects without resorting to classical concepts of linear elastic fracture mechanics. As a direct consequence of the stress criteria, however, a relationship between Mode I fracture toughness and unnotched laminate tensile strength is determined. Limited comparison of theory to experimental data for circular holes and straight cracks yields good results. The simplicity of the analytical approach coupled with its generality make it of practical value to the designer.

Abstract Ultrawide‐bandgap (UWBG) semiconductors, with bandgaps significantly wider than the 3.4 eV of GaN, represent an exciting and challenging new area of research in semiconductor materials, physics, devices, and applications. Because many figures‐of‐merit for device performance scale nonlinearly with bandgap, these semiconductors have long been known to have compelling potential advantages over their narrower‐bandgap cousins in high‐power and RF electronics, as well as in deep‐UV optoelectronics, quantum information, and extreme‐environment applications. Only recently, however, have the UWBG semiconductor materials, such as high Al‐content AlGaN, diamond and Ga 2 O 3 , advanced in maturity to the point where realizing some of their tantalizing advantages is a relatively near‐term possibility. In this article, the materials, physics, device and application research opportunities and challenges for advancing their state of the art are surveyed.

Our continuing study of the mechanism of flammability reduction of polymer−layered-silicate nanocomposites has yielded results for polypropylene-graft-maleic anhydride and polystyrene−layered-silicate nanocomposites using montmorillonite and fluorohectorite. Cone calorimetry was used to measure the heat release rate and other flammability properties of the nanocomposites, under well-controlled combustion conditions. Both the polymer−layered-silicate nanocomposites and the combustion residues were studied by transmission electron microscopy and X-ray diffraction. We have found evidence for a common mechanism of flammability reduction. We also found that the type of layered silicate, nanodispersion, and processing degradation have an influence on the flammability reduction.

We present a Raman scattering study of wurtzite $\mathrm{ZnO}$ over a temperature range from 80 to $750\phantom{\rule{0.3em}{0ex}}\mathrm{K}$. Second-order Raman features are interpreted in the light of recent ab initio phonon density of states calculations. The temperature dependence of the Raman intensities allows the assignment of difference modes to be made unambiguously. Some weak, sharp Raman peaks are detected whose temperature dependence suggests they may be due to impurity modes. High-resolution spectra of the ${E}_{2}^{\mathrm{high}}$, ${A}_{1}(\mathrm{LO})$, and ${E}_{1}(\mathrm{LO})$ modes were recorded, and an analysis of the anharmonicity and lifetimes of these phonons is carried out. The ${E}_{2}^{\mathrm{high}}$ mode displays a visibly asymmetric line shape. This can be attributed to anharmonic interaction with transverse and longitudinal acoustic phonon combinations in the vicinity of the $K$ point, where the two-phonon density of states displays a sharp edge around the ${E}_{2}^{\mathrm{high}}$ frequency. The temperature dependence of the linewidth and frequency of the ${E}_{2}^{\mathrm{high}}$ mode is well described by a perturbation-theory renormalization of the harmonic ${E}_{2}^{\mathrm{high}}$ frequency resulting from the interaction with the acoustic two-phonon density of states. In contrast, the ${A}_{1}(\mathrm{LO})$ and ${E}_{1}(\mathrm{LO})$ frequencies lie in a region of nearly flat two-phonon density of states, and they exhibit a nearly symmetric Lorentzian line shape with a temperature dependence that is well accounted for by a dominating asymmetric decay channel.

The goal in designing an ionospheric time-delay correctionalgorithm for the single-frequency global positioning system userwas to include the main features of the complex behavior of theionosphere, yet require a minimum of coefficients and usercomputational time, while still yielding an rms correction of at least50 percent. The algorithm designed for this purpose, andimplemented in the GPS satellites, requires only eight coefficientssent as part of the satellite message, contains numerousapproximations designed to reduce user computationalrequirements, yet preserves the essential elements required to obtaingroup delay values along multiple satellite viewing directions.

A facile approach has been developed to prepare B,N co-doped graphene with tuneable composition simply by thermal annealing graphene oxide in the presence of boric acid and ammonia. The resultant BCN graphene (see picture; C gray, H white, B pink, N blue) has superior electrocatalytic activity over commercial Pt/C electrocatalysts for the oxygen reduction reaction in alkaline media. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.

Limitations of classical laminated plate theory are investigated by comparing solutions of several specific boundary value problems in this theory to the corresponding theory of elasticity solutions. The general class of problems treated involves the geometric configuration of any number of isotropic or orthotropic layers bonded together and subjected to cylindrical bending. In general it is found that conventional plate theory leads to a very poor description of laminate response at low span-to-depth ratios, but converges to the exact solution as this ratio increases. The analysis presented is also valid in the study of sand wich plates under cylindrical bending.

Solving optimization problems with multiple (often conflicting) objectives is, generally, a very difficult goal. Evolutionary algorithms (EAs) were initially extended and applied during the mid-eighties in an attempt to stochastically solve problems of this generic class. During the past decade, a variety, of multiobjective EA (MOEA) techniques have been proposed and applied to many scientific and engineering applications. Our discussion's intent is to rigorously define multiobjective optimization problems and certain related concepts, present an MOEA classification scheme, and evaluate the variety of contemporary MOEAs. Current MOEA theoretical developments are evaluated; specific topics addressed include fitness functions, Pareto ranking, niching, fitness sharing, mating restriction, and secondary populations. Since the development and application of MOEAs is a dynamic and rapidly growing activity, we focus on key analytical insights based upon critical MOEA evaluation of current research and applications. Recommended MOEA designs are presented, along with conclusions and recommendations for future work.

Although many researchers have examined the role that binaural cues play in the perception of spatially separated speech signals, relatively little is known about the cues that listeners use to segregate competing speech messages in a monaural or diotic stimulus. This series of experiments examined how variations in the relative levels and voice characteristics of the target and masking talkers influence a listener's ability to extract information from a target phrase in a 3-talker or 4-talker diotic stimulus. Performance in this speech perception task decreased systematically when the level of the target talker was reduced relative to the masking talkers. Performance also generally decreased when the target and masking talkers had similar voice characteristics: the target phrase was most intelligible when the target and masking phrases were spoken by different-sex talkers, and least intelligible when the target and masking phrases were spoken by the same talker. However, when the target-to-masker ratio was less than 3 dB, overall performance was usually lower with one different-sex masker than with all same-sex maskers. In most of the conditions tested, the listeners performed better when they were exposed to the characteristics of the target voice prior to the presentation of the stimulus. The results of these experiments demonstrate how monaural factors may play an important role in the segregation of speech signals in multitalker environments.

The need to characterize nanoparticles in solution before assessing the in vitro toxicity is a high priority. Particle size, size distribution, particle morphology, particle composition, surface area, surface chemistry, and particle reactivity in solution are important factors which need to be defined to accurately assess nanoparticle toxicity. Currently, there are no well-defined techniques for characterization of wet nanomaterials in aqueous or biological solutions. Previously reported nanoparticle characterization techniques in aqueous or biological solutions have consisted of the use of ultra-high illumination light microscopy and disc centrifuge sedimentation; however, these techniques are limited by the measurement size range. The current study focuses on characterizing a wide range of nanomaterials using dynamic light scattering (DLS) and transmission electron microscopy, including metals, metal oxides, and carbon-based materials, in water and cell culture media, with and without serum. Cell viability and cell morphology studies were conducted in conjunction with DLS experiments to evaluate toxicological effects from observed agglomeration changes in the presence or absence of serum in cell culture media. Observations of material-specific surface properties were also recorded. It was also necessary to characterize the impact of sonication, which is implemented to aid in particle dispersion and solution mixture. Additionally, a stock solution of nanomaterials used for toxicology studies was analyzed for changes in agglomeration and zeta potential of the material over time. In summary, our results demonstrate that many metal and metal oxide nanomaterials agglomerate in solution and that depending upon the solution particle agglomeration is either agitated or mitigated. Corresponding toxicity data revealed that the addition of serum to cell culture media can, in some cases, have a significant effect on particle toxicity possibly due to changes in agglomeration or surface chemistry. It was also observed that sonication slightly reduces agglomeration and has minimal effect on particle surface charge. Finally, the stock solution experienced significant changes in particle agglomeration and surface charge over time.

Reengineering of the aircraft structural life prediction process to fully exploit advances in very high performance digital computing is proposed. The proposed process utilizes an ultrahigh fidelity model of individual aircraft by tail number, a Digital Twin, to integrate computation of structural deflections and temperatures in response to flight conditions, with resulting local damage and material state evolution. A conceptual model of how the Digital Twin can be used for predicting the life of aircraft structure and assuring its structural integrity is presented. The technical challenges to developing and deploying a Digital Twin are discussed in detail.

Abstract This paper presents a software environment for processing, segmenting, quantifying, representing and manipulating digital microstructure data. The paper discusses the approach to building a generalized representation strategy for digital microstructures and the barriers encountered when trying to integrate a set of existing software tools to create an expandable codebase.