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アセトニトリルおよびマロンニトリルの電解フッ素化反応
Watanabe, Chang, and and 1 other
Denki Kagaku oyobi Kogyo Butsuri Kagaku5 Feb 1972Open access
アセトニトリルおよびマロンニトリルの電解フッ素化反応
Watanabe, Chang, and and 1 other · Denki Kagaku oyobi Kogyo Butsuri Kagaku · 5 Feb 1972
Abstract
A study has been made of the electrochemical fluorination of acetonitrile and malononitrile under a variety of operating conditns These nitriles yielded signicant amounts of CF3CNC2F5NF2 NF2(CF2)3NF2NF2(CF2)2CNC3F7NF2C2F5CNtogether with C2F6NF3and C3F8compounds containing carbon-nitrogen bond In the fluorination of acetonitrilethe total 1rrent eciency of the products increased with an increase in electrolysis temperature and current densityand was highest at the2mo1solution In malononitrilethe eHect of electrolysis tperature was essentially the same as observed in acetonitrilebut no appreciable effect of crent density ws observed The optimum conditions for the formation of the compomds containing carbon-nitrogen bond werecurrent density of10-20mAcm2substrate concentration of2moland electrolysis temperature of2C 1n the fluorination of acetonitrileand2moland150C fQr ma1Qonitrile 1 (lntrGductiGn) n