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Solid State Isomerization

Published in The Chemical Educator • Jun 1, 2008
NobleIDNI8P97W94R53S19
Authors:
David E. Berry
,
Kelli L. Fawkes

Abstract

A two-step synthesis of trans,trans,trans-[RuCl2(CNBut)2(PPh3)2] is described in which the first step uses a microwave reflux to make [RuCl2(PPh3)3] and the second step is the room temperature addition of t-butylisocyanide to a solution of the isolated [RuCl2(PPh3)3]. The final product is isomerized...

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