National Science and Technology Council

Two-dimensional transition metal dichalcogenides (TMDCs) such as molybdenum sulfide MoS2 and tungsten sulfide WSe2 have potential applications in electronics because they exhibit high on-off current ratios and distinctive electro-optical properties. Spatially connected TMDC lateral heterojunctions are key components for constructing monolayer p-n rectifying diodes, light-emitting diodes, photovoltaic devices, and bipolar junction transistors. However, such structures are not readily prepared via the layer-stacking techniques, and direct growth favors the thermodynamically preferred TMDC alloys. We report the two-step epitaxial growth of lateral WSe2-MoS2 heterojunction, where the edge of WSe2 induces the epitaxial MoS2 growth despite a large lattice mismatch. The epitaxial growth process offers a controllable method to obtain lateral heterojunction with an atomically sharp interface.

This paper presents a model of microwave emissions from rough surfaces. We derive a more complete expression of the single-scattering terms in the integral equation method (IEM) surface scattering model. The complementary components for the scattered fields are rederived, based on the removal of a simplifying assumption in the spectral representation of Green's function. In addition, new but compact expressions for the complementary field coefficients can be obtained after quite lengthy mathematical manipulations. Three-dimensional Monte Carlo simulations of surface emission from Gaussian rough surfaces were used to examine the validity of the model. The results based on the new version (advanced IEM) indicate that significant improvements for emissivity prediction may be obtained for a wide range of roughness scales, in particular in the intermediate roughness regions. It is also shown that the original IEM produces larger errors that lead to tens of Kelvins in brightness temperature, which are unacceptable for passive remote sensing.

In the oligotrophic North Atlantic and North Pacific, ultrafiltration studies show that concentrations of soluble iron and soluble iron-binding organic ligands are much lower than previously presumed "dissolved" concentrations, which were operationally defined as that passing through a 0.4-micrometer pore filter. Our studies indicate that substantial portions of the previously presumed "dissolved" iron (and probably also iron-binding ligands) are present in colloidal size range. The soluble iron and iron-binding organic ligands are depleted at the surface and enriched at depth, similar to distributions of major nutrients. By contrast, colloidal iron shows a maximum at the surface and a minimum in the upper nutricline. Our results suggest that "dissolved" iron may be less bioavailable to phytoplankton than previously thought and that iron removal through colloid aggregation and settling should be considered in models of the oceanic iron cycle.

Agriculture's global environmental impacts are widely expected to continue expanding, driven by population and economic growth and dietary changes. This Review highlights climate change as an additional amplifier of agriculture's environmental impacts, by reducing agricultural productivity, reducing the efficacy of agrochemicals, increasing soil erosion, accelerating the growth and expanding the range of crop diseases and pests, and increasing land clearing. We identify multiple pathways through which climate change intensifies agricultural greenhouse gas emissions, creating a potentially powerful climate change-reinforcing feedback loop. The challenges raised by climate change underscore the urgent need to transition to sustainable, climate-resilient agricultural systems. This requires investments that both accelerate adoption of proven solutions that provide multiple benefits, and that discover and scale new beneficial processes and food products.

We propose a method to invert surface wave dispersion data directly for 3-D variations of shear wave speed, that is, without the intermediate step of phase or group velocity maps, using frequency-dependent ray tracing and a wavelet-based sparsity-constrained tomographic inversion. A fast marching method is used to compute, at each period, surface wave traveltimes and ray paths between sources and receivers. This avoids the assumption of great-circle propagation that is used in most surface wave tomographic studies, but which is not appropriate in complex media. To simplify the problem we consider quasi-stratified media with smoothly varying seismic properties. We represent the 3-D shear wave speed model by means of 1-D profiles beneath grid points, which are determined from all dispersion data simultaneously using a wavelet-based sparsity-constrained tomographic method. The wavelet coefficients of the wave speed model are estimated with an iteratively reweighted least squares algorithm, and upon iteration the surface wave ray paths and the data sensitivity matrix are updated using the newly obtained wave speed model. To demonstrate its feasibility, we apply the method to determine the 3-D shallow crustal shear wave speed variations in the Taipei basin of Taiwan using short period interstation Rayleigh wave phase velocity dispersion measurements extracted from the ambient noise cross-correlation method. The results are consistent with previous studies and reveal strong shallow crustal heterogeneity that correlates with surface geology.

“Spin” has been recently reported as an important degree of electronic freedom to improve the performance of electrocatalysts and photocatalysts. This work demonstrates the manipulations of spin-polarized electrons in CsPbBr3 halide perovskite nanoplates (NPLs) to boost the photocatalytic CO2 reduction reaction (CO2RR) efficiencies by doping manganese cations (Mn2+) and applying an external magnetic field. Mn-doped CsPbBr3 (Mn-CsPbBr3) NPLs exhibit an outstanding photocatalytic CO2RR compared to pristine CsPbBr3 NPLs due to creating spin-polarized electrons after Mn doping. Notably, the photocatalytic CO2RR of Mn-CsPbBr3 NPLs is significantly enhanced by applying an external magnetic field. Mn-CsPbBr3 NPLs exhibit 5.7 times improved performance of photocatalytic CO2RR under a magnetic field of 300 mT with a permanent magnet compared to pristine CsPbBr3 NPLs. The corresponding mechanism is systematically investigated by magnetic circular dichroism spectroscopy, ultrafast transient absorption spectroscopy, and density functional theory simulation. The origin of enhanced photocatalytic CO2RR efficiencies of Mn-CsPbBr3 NPLs is due to the increased number of spin-polarized photoexcited carriers by synergistic doping of the magnetic elements and applying a magnetic field, resulting in prolonged carrier lifetime and suppressed charge recombination. Our result shows that manipulating spin-polarized electrons in photocatalytic semiconductors provides an effective strategy to boost photocatalytic CO2RR efficiencies.

The optimum mode-to-pump ratio in scaling fiber-coupled laser-diode end-pumped lasers to higher power has been investigated by including the thermal effect into the space-dependent rate equation analysis. The optical path difference (OPD) distribution has been derived as a function of the pump-beam quality, focus position of pumping light, and pump radius at the focal plane under the assumption that the end faces of the crystal are thermally insulated. The diffraction losses arising from thermally induced spherical aberration have been estimated by the Strehl intensity ratio. The present results for the optimum mode-to-pump ratio are markedly different from previous analyses in which thermal effects are neglected. Here, the optimum mode-to-pump ratio is a decreasing function of input pump power, and is less than unity in the case of a slightly high pump power. The practical example of a Nd:YAG laser pumped by a 13-W fiber-coupled laser diode is considered to confirm our physical analysis.

Dissolved inorganic phosphorus (DIP) concentrations in the oligotrophic surface waters of the South China Sea decrease from ∼20 nM in March 2000 to ∼5 nM in July 2000, in response to seasonal water column stratification. These minimum DIP concentrations are one order of magnitude higher than those in the P‐limited, iron‐replete stratified surface waters of the western North Atlantic, suggesting that the ecosystem in the South China Sea may be limited by bioavailable nitrogen or some trace nutrient rather than DIP. Nutrient enrichment experiments using either nitrate, phosphate or both indicate that nitrogen limits the net growth of phytoplankton in the South China Sea, at least during March and July 2000. The fixed nitrogen limitation may result from the excess phosphate (N:P<16) transported into the South China Sea from the North Pacific relative to microbial population needs, or from iron control of nitrogen fixation. The iron‐limited nitrogen fixation hypothesis is supported by the observation of low population densities of Trichodesmium spp. (<48 × 10 3 trichomes/m 3 ), the putative N 2 fixing cyanobacterium, and with low concentrations of dissolved iron (∼0.2–0.3 nM) in the South China Sea surface water. Our results suggest that nitrogen fixation can be limited by available iron even in regions with a high rate of atmospheric dust deposition such as in the South China Sea.

Organic–inorganic hybrid two-dimensional (2D) perovskites have recently attracted great attention in optical and optoelectronic applications due to their inherent natural quantum-well structure. We report the growth of high-quality millimeter-sized single crystals belonging to homologous two-dimensional (2D) hybrid organic–inorganic Ruddelsden–Popper perovskites (RPPs) of (BA)2(MA)n−1PbnI3n+1 (n = 1, 2, and 3) by a slow evaporation at a constant-temperature (SECT) solution-growth strategy. The as-grown 2D hybrid perovskite single crystals exhibit excellent crystallinity, phase purity, and spectral uniformity. Low-threshold lasing behaviors with different emission wavelengths at room temperature have been observed from the homologous 2D hybrid RPP single crystals. Our result demonstrates that solution-growth homologous organic–inorganic hybrid 2D perovskite single crystals open up a new window as a promising candidate for optical gain media.

A robust valley polarization is a key prerequisite for exploiting valley pseudospin to carry information in next-generation electronics and optoelectronics. Although monolayer transition metal dichalcogenides with inherent spin-valley coupling offer a unique platform to develop such valleytronic devices, the anticipated long-lived valley pseudospin has not been observed yet. Here we demonstrate that robust valley-polarized holes in monolayer WSe2 can be initialized by optical pumping. Using time-resolved Kerr rotation spectroscopy, we observe a long-lived valley polarization for positive trion with a lifetime approaching 1 ns at low temperatures, which is much longer than the trion recombination lifetime (∼10-20 ps). The long-lived valley polarization arises from the transfer of valley pseudospin from photocarriers to resident holes in a specific valley. The optically initialized valley pseudospin of holes remains robust even at room temperature, which opens up the possibility to realize room-temperature valleytronics based on transition metal dichalcogenides.

Atomically thin two-dimensional transition-metal dichalcogenides (TMDCs) have attracted much attention recently due to their unique electronic and optical properties for future optoelectronic devices. The chemical vapor deposition (CVD) method is able to generate TMDCs layers with a scalable size and a controllable thickness. However, the TMDC monolayers grown by CVD may incorporate structural defects, and it is fundamentally important to understand the relation between photoluminescence and structural defects. In this report, point defects (Se vacancies) and oxidized Se defects in CVD-grown MoSe2 monolayers are identified by transmission electron microscopy and X-ray photoelectron spectroscopy. These defects can significantly trap free charge carriers and localize excitons, leading to the smearing of free band-to-band exciton emission. Here, we report that the simple hydrohalic acid treatment (such as HBr) is able to efficiently suppress the trap-state emission and promote the neutral exciton and trion emission in defective MoSe2 monolayers through the p-doping process, where the overall photoluminescence intensity at room temperature can be enhanced by a factor of 30. We show that HBr treatment is able to activate distinctive trion and free exciton emissions even from highly defective MoSe2 layers. Our results suggest that the HBr treatment not only reduces the n-doping in MoSe2 but also reduces the structural defects. The results provide further insights of the control and tailoring the exciton emission from CVD-grown monolayer TMDCs.

A systematic investigation of a series of Nd:YVO/sub 4/ crystals with different dopant concentrations is conducted to scale the performance of diode-end-pumped lasers to higher powers. From the theoretical analysis, the fracture-limited pump power is expressed as a function of the thermal shock parameter, fractional thermal loading, and the absorption coefficient. The thermal shock parameter of Nd:YVO/sub 4/ crystals is determined from the laser experiments. Using the thermal shock parameter and the space-rate-equation model, we calculate the maximum output power in Nd:WO/sub 4/ crystals at the optimum pump condition as a function of the dopant concentration. The theoretical calculations are in good agreement with the experimental results. The influence of lowering the absorption coefficient on the TEM/sub 00/ output efficiency is also studied through the overlapping integral.

A novel approach to modulate the nucleation and growth of perovskite crystals by intermixing precursor-capped nanoparticles has been reported.

In the development of wave scattering models for randomly dielectric rough surfaces, it is usually assumed that the Fresnel reflection coefficients could be approximately evaluated at either the incident angle or the specular angle. However, these two considerations are only applicable to their respective regions of validity. A common question to ask is what are the conditions under which we would choose one or the other of these two approximations? Since these approximations are basically roughness-dependent, how can we handle the in-between cases where neither is appropriate? In this paper, a physical-based transition function that naturally connects these two approximations is proposed. The like-polarized backscattering coefficients are evaluated with the model and are compared with those calculated with a moment method simulation for both Gaussian and non-Gaussian correlated surfaces. It is found that the proposed transition function provides an excellent prediction for the backscattering coefficient in the frequency and angle trends.

An integral equation method (IEM) surface scattering model was examined in terms of its applicability to laboratory measurement and numerical simulations. New expressions for both single scattering and multiple scattering were obtained by rederiving the scattering coefficient to keep all the phase terms in the spectral representation of the Green's function. After quite intricate mathematical manipulations, a fairly compact form is obtained for the scattering coefficients. In addition, the Fresnel reflection coefficients used in the model were replaced by a transition function that takes surface roughness and permittivity into account. The results of comparisons with both the numerical simulations and measurements for the backscattering case indicate that the IEM is improved, becoming more accurate and practical to use.

The synthesis and characterization of a new series of charge-neutral RuII metal complexes are reported. The compound [Ru(ifpz)2(PPh2Me)2] is a very attractive candidate for the fabrication of saturated red phosphorescent organic light-emitting diode devices (see Figure) with high brightness and very low turn-on voltage.

Abstract The rational design and syntheses of Pt(iqdz) 2 ( 1 ) and Pt(pydz) 2 ( 2 ) bearing isoquinolinyl indazole (iqdz)H or pyridyl indazole (pydz)H groups on the coordinating ligands are reported. Single‐crystal X‐ray diffraction studies of 1 reveal a square planar geometry, in which two iqdz ligands adopt a trans‐configuration. Short N…H contacts (∼2.21 Å) are detected between the ortho‐hydrogen atom of isoquinoline and the adjacent N atom of the indazole fragment, making the overall molecular geometry analogous to that of the platinum( II ) porphyrinato complexes. The lowest absorption bands for both complexes reveal strong state mixings between singlet and triplet (metal‐to‐ligand charge transfer and intra‐ligand) manifolds. This, in combination with the introduction of a camphor‐like structure to avoid the stacking effect, leads to phosphorescence with unprecedented brightness both in solution and in the solid state. Organic light‐emitting diode (OLED) devices fabricated using 1 as a dopant emitter have been achieved in a multilayer configuration. The results constitute the first highly efficient Pt II ‐based red OLED.

One-dimensional piezoelectric nanomaterials have attracted great attention in recent years for their possible applications in mechanical energy scavenging devices. However, it is difficult to control the structural diameter, length, and density of these fibers fabricated by micro/nano-technologies. This work presents a hollow cylindrical near-field electrospinning (HCNFES) process to address production and performance issues encountered previously in either far-field electrospinning (FFES) or near-field electrospinning (NFES) processes. Oriented polyvinylidene fluoride (PVDF) fibers in the form of nonwoven fabric have been directly written on a glass tube for aligned piezoelectricity. Under a high in situ electrical poling field and strong mechanical stretching (the tangential speed on the glass tube collector is about 1989.3 mm s−1), the HCNFES process is able to uniformly deposit large arrays of PVDF fibers with good concentrations of piezoelectric β-phase. The nonwoven fiber fabric (NFF) is transferred onto a polyethylene terephthalate (PET) substrate and fixed at both ends using copper foil electrodes as a flexible textile-fiber-based PVDF energy harvester. Repeated stretching and releasing of PVDF NFF with a strain of 0.05% at 7 Hz produces a maximum peak voltage and current at 76 mV and 39 nA, respectively.

We propose the physical origin for a directional beam of light emitting from a single subwavelength slit in metallic film that is characterized by a corrugation feature at the exiting side of the film. We theorize that the beaming phenomenon can be explained simply as surface plasmon diffraction along the corrugation as long as the multiple scattering effects are taken into account to restate the dispersion relationship of the surface plasmon. In order to prove our theory, both an experimental setup and numerical simulations were undertaken. Results obtained match well with our theory of an explanation based on a surface plasmon diffraction scheme.

The hand delivery of self-administered questionnaires has been presented as an alternative for reducing non-coverage error associated with the mail method at lower cost than face-to-face interviews. This research note draws from experiences using the hand delivery technique (combined with hand retrieval) in rural and small community studies to address practical issues associated with improving coverage, and its relationships with sampling, response, and administrative considerations. It is suggested that while this technique provides needed flexibility in relation to household enumeration options, logistical issues limit its applicability where settlement patterns are dispersed and resources to supplement sampling frames are inadequate. Time and cost outlays are required to maximize its potential. When place-related and administrative conditions can be met, the technique offers promise for reducing non-coverage error and possible sample bias without saerificing response rates. In addition, it provides opportunities to gain experiential insights not possible with other survey methods.