Lanthanide mixed-ligand complexes of the [Ln(CAPh)3(Phen)] and [LaxEu1-x(CAPh)3(Phen)] (CAPh = carbacylamidophosphate) type. A comparative study of their spectral properties.

OO, Litsis; VA, Ovchynnikov; VP, Scherbatskii; SG, Nedilko; TY, Sliva; VV, Dyakonenko; OV, Shishkin; VI, Davydov; P, Gawryszewska; VM, Amirkhanov

doi:10.1039/c5dt02557e

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Lanthanide mixed-ligand complexes of the [Ln(CAPh)3(Phen)] and [LaxEu1-x(CAPh)3(Phen)] (CAPh = carbacylamidophosphate) type. A comparative study of their spectral properties.

Shared by NobleBlocks on Aug 4, 2015 • 12:00 AM UTC

Authors:

Litsis OO

Ovchynnikov VA

Scherbatskii VP

Abstract

A series of complexes Ln(Pip)3(Phen) (Ln(iii) = La, Ce-Nd, Sm-Lu, Y; HPip (CAPh type ligand) = 2,2,2-trichloro-N-(dipiperidin-1-yl-phosphoryl)acetamide, Phen = 1,10-phenanthroline) has been synthesized. The lanthanum(iii) doped europium(iii) complexes ([LaxEu1-x(Pip)3(Phen)], x = 0.99, 0.95, 0.50) h...

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