Mn(III)-mediated phosphonation-azidation of alkenes: a facile synthesis of β-azidophosphonates.

J, Xu; X, Li; Y, Gao; L, Zhang; W, Chen; H, Fang; G, Tang; Y, Zhao

doi:10.1039/c5cc03995a

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Mn(III)-mediated phosphonation-azidation of alkenes: a facile synthesis of β-azidophosphonates.

Shared by NobleBlocks on Jun 1, 2015 • 12:00 AM UTC

Authors:

Xu J

Li X

Gao Y

Abstract

A new and general method for the synthesis of β-azidophosphonates has been achieved through Mn(OAc)3-mediated radical oxidative phosphonation-azidation of alkenes. The starting materials of P(O)-H compounds, alkenes, and azidotrimethylsilane are stable and cheap. This method can be easily adapted fo...

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