Hybrid polyoxotungstate/MIL-101 materials: synthesis, characterization, and catalysis of H2O2-based alkene epoxidation.

NV, Maksimchuk; KA, Kovalenko; SS, Arzumanov; YA, Chesalov; MS, Melgunov; AG, Stepanov; VP, Fedin; OA, Kholdeeva

doi:10.1021/ic902459f

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Hybrid polyoxotungstate/MIL-101 materials: synthesis, characterization, and catalysis of H2O2-based alkene epoxidation.

Shared by NobleBlocks on Mar 1, 2010 • 12:00 AM UTC

Authors:

Maksimchuk NV

Kovalenko KA

Arzumanov SS

Abstract

Polyoxotungstates [PW(4)O(24)](3-) (PW(4)) and [PW(12)O(40)](3-) (PW(12)) have been inserted into nanocages of the metal organic framework MIL-101. The hybrid materials PW(x)/MIL-101 (x = 4 or 12) containing 5-14 wt % of polyoxotungstate have been obtained and characterized by elemental analysis, N(...

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