Metallocene-Mediated Olefin Polymerization with B−H Chain Transfer Agents:  Synthesis of Chain-End Functionalized Polyolefins and Diblock Copolymers

C. Chung, T.; Xu, Guo-Feng; Lü, Yingying; Hu, Youliang

doi:10.1021/ma011074d

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Metallocene-Mediated Olefin Polymerization with B−H Chain Transfer Agents: Synthesis of Chain-End Functionalized Polyolefins and Diblock Copolymers

Shared by NobleBlocks on Oct 5, 2001 • 12:00 AM UTC

Authors:

T. C. Chung

Guo-Feng Xu

Yingying Lü

Abstract

A systematic study of the scope and limitations of B−H chain transfer agents during metallocene-mediated olefin polymerization is discussed in this contribution. The polymerization procedures provide a convenient route to prepare chain-end functionalized polyolefins and polyolefin diblock copolymers...

Subject

Polyolefin

Polymer chemistry

Metallocene

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