Gas-liquid chromatographic separation of aldose enantiomers as trimethylsilyl ethers of methyl 2-(polyhydroxyalkyl)-thiazolidine-4(R)-carboxylates.

Hara, Shuuji; Okabe, Hikaru; Mihashi, Kunihide

doi:10.1248/cpb.35.501

Public

Gas-liquid chromatographic separation of aldose enantiomers as trimethylsilyl ethers of methyl 2-(polyhydroxyalkyl)-thiazolidine-4(R)-carboxylates.

Shared by NobleBlocks on Jan 1, 1987 • 12:00 AM UTC

Authors:

Shuuji Hara

Hikaru Okabe

Kunihide Mihashi

Abstract

Pairs of enantiomers of nine aldoses were separated by gas-liquid chromatography on an OV-17 capillary column as the trimethylsilyl ethers of methyl 2- (polyhydroxyalkyl) -thiazolidine-4 (R) -carboxylates, which were obtained by the reaction of aldoses with L-cysteine methyl ester. This method was a...

Subject

Chemistry

Trimethylsilyl

Thiazolidine

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