High and selective CO2 uptake, H2 storage and methanol sensing on the amine-decorated 12-connected MOF CAU-1

Si, Xiaoliang; Jiao, Chengli; Li, Fen; Zhang, Jian; Wang, Shuang; Liu, Shuang; Li, Zhibao; Sun, Lixian; Xu, Fen; Gabélica, Z.; Schick, Christoph

doi:10.1039/c1ee01380g

Public

High and selective CO2 uptake, H2 storage and methanol sensing on the amine-decorated 12-connected MOF CAU-1

Shared by NobleBlocks on Jan 1, 2011 • 12:00 AM UTC

Authors:

Xiaoliang Si

Chengli Jiao

Fen Li

Abstract

The amine-decorated microporous metal–organic framework CAU-1 was readily synthesized and activated using a home-made efficient protocol. It exhibited a high heat of adsorption for CO2, high CO2 uptake capacity, and an impressive selectivity for CO2 over N2. At 273 K and up to 1 atm, CO2 uptake capa...

Subject

Microporous material

Methanol

Adsorption

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