A Microporous Metal−Organic Framework for Separation of CO2/N2 and CO2/CH4 by Fixed-Bed Adsorption

Bastin, Laurent; S. Bárcia, Patrick; Hurtado, E.J.; A.C. Silva, José; E. Rodrigues‬, Alírio; Chen, Banglin

doi:10.1021/jp077618g

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A Microporous Metal−Organic Framework for Separation of CO2/N2 and CO2/CH4 by Fixed-Bed Adsorption

Shared by NobleBlocks on Jan 16, 2008 • 12:00 AM UTC

Authors:

Laurent Bastin

Patrick S. Bárcia

E.J. Hurtado

Abstract

A microporous MOF Zn(BDC)(4,4'-Bipy)0.5 (MOF-508b, BDC = 1,4-benzenedicarboxylate, 4,4'-Bipy = 4,4'-bipyridine) was examined for the separation and removal of CO2 from its binary CO2/N2 and CO2/CH4 and ternary CO2/CH4/N2 mixtures by fixed-bed adsorption. With one-dimensional pores of about 4.0 × 4.0...

Subject

Microporous material

Adsorption

Ternary operation

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