Atmospheric chemistry of 4:2 fluorotelomer iodide (n-C4F9CH2CH2I): kinetics and products of photolysis and reaction with OH radicals and Cl atoms.

CJ, Young; MD, Hurley; TJ, Wallington; SA, Mabury

doi:10.1021/jp807322x

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Atmospheric chemistry of 4:2 fluorotelomer iodide (n-C4F9CH2CH2I): kinetics and products of photolysis and reaction with OH radicals and Cl atoms.

Shared by NobleBlocks on Dec 1, 2008 • 12:00 AM UTC

Authors:

Young CJ

Hurley MD

Wallington TJ

Abstract

Relative rate techniques were used to study the title reactions and determine rate constants of k(Cl + C(4)F(9)CH(2)CH(2)I) = (1.25 +/- 0.15) x 10(-12) and k(OH + C(4)F(9)CH(2)CH(2)I) = (1.2 +/- 0.6) x 10(-12) cm(3) molecule(-1) s(-1) in 700 Torr total pressure at 295 K. The fluorotelomer aldehyde (...

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