Secondary Amines from the lron(II) Ion-Catalyzed Reaction of Amine Oxides: A General Method for the Dealkylation of Tertiary Amines

Monković, Ivo; Ν. C. Wong, Henry; Bachand, Carol

doi:10.1055/s-1985-31342

Public

Secondary Amines from the lron(II) Ion-Catalyzed Reaction of Amine Oxides: A General Method for the Dealkylation of Tertiary Amines

Shared by NobleBlocks on Jan 1, 1985 • 12:00 AM UTC

Authors:

Ivo Monković

Henry Ν. C. Wong

Carol Bachand

Abstract

La desalkylation d'amines tertiaires se fait par une reaction «one pot»: oxydation d'amines tertiaires par l'acide m-chloroperbenzoique dans le dichloromethane suivie d'addition de FeCl 2 ; application a la synthese de (−)-methoxy-3 morphinanol-14, d'octahydroisoquinoleines, de derives de pyridine, ...

Subject

Chemistry

Dichloromethane

Alkylation

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