Catalytic Aminolysis (Amide Formation) from Esters and Carboxylic Acids: Mechanism, Enhanced Ionic Liquid Effect, and its Origin

Oliveira, Vanda; Silva de Jesus, Richard; F. Gomes, Alexandre; C. Gozzo, Fábio; P. Umpierre, Alexandre; A. Z. Suarez, Paulo; C. Rubim, Joel; A. D. Neto, Brenno

doi:10.1002/cctc.201100221

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Catalytic Aminolysis (Amide Formation) from Esters and Carboxylic Acids: Mechanism, Enhanced Ionic Liquid Effect, and its Origin

Shared by NobleBlocks on Oct 26, 2011 • 12:00 AM UTC

Authors:

Vanda Oliveira

Richard Silva de Jesus

Alexandre F. Gomes

Abstract

Abstract This paper describes the use of imidazolium‐based ionic liquids {1‐ n ‐butyl‐3‐methylimidazolium tetrafluoroborate [BMI‐BF 4 ], 1‐ n ‐butyl‐3‐methylimidazolium hexafluorophosphate [BMI‐PF 6 ], and 1‐ n ‐butyl‐3‐methylimidazolium bis(trifluoromethylsulfonyl)imide [BMI‐NTf 2 ]} as efficient s...

Subject

Ionic liquid

Aminolysis

Chemistry

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