Oxidations by the reagent “O2–H2O2–vanadium derivative–pyrazine-2-carboxylic acid’. Part 12. Main features, kinetics and mechanism of alkane hydroperoxidation†

B. Shul’pin⊗, Georgiy; N. Kozlov⊗, Yuriy; V. Nizova, G.; Süß‐Fink, Georg; Stanislas, Sandrine; Kitaygorodskiy, Alex; S. Kulikova, V.

doi:10.1039/b101442k

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Oxidations by the reagent “O2–H2O2–vanadium derivative–pyrazine-2-carboxylic acid’. Part 12. Main features, kinetics and mechanism of alkane hydroperoxidation†

Shared by NobleBlocks on Jan 1, 2001 • 12:00 AM UTC

Authors:

Georgiy B. Shul’pin⊗

Yuriy N. Kozlov⊗

G. V. Nizova

Abstract

Various combinations of vanadium derivatives (n-Bu4NVO3 is the best catalyst) with pyrazine-2-carboxylic acid (PCA) catalyse the oxidation of saturated hydrocarbons, RH, with hydrogen peroxide and air in acetonitrile solution to produce, at temperatures <40 °C, alkyl hydroperoxides, ROOH, as the mai...

Subject

Chemistry

Radical

Photochemistry

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