The effect of water adsorption on the structure of the carboxylate containing metal–organic frameworks Cu-BTC, Mg-MOF-74, and UiO-66

B. DeCoste, Jared; W. Peterson, Gregory; J. Schindler, Bryan; L. Killops, Kato; A. Browe, Matthew; J. Mahle, John

doi:10.1039/c3ta12497e

Public

The effect of water adsorption on the structure of the carboxylate containing metal–organic frameworks Cu-BTC, Mg-MOF-74, and UiO-66

Published in Journal of Materials Chemistry A • Jan 1, 2013

Authors:

Jared B. DeCoste

Gregory W. Peterson

Bryan J. Schindler

Abstract

Metal–organic frameworks (MOFs) with metal–carboxylate bonds, including Cu-BTC (HKUST-1), Mg-MOF-74 (Mg/DOBDC), and UiO-66, have been shown to have varying degrees of water stability. The three MOFs in this study are three of the most highly studied MOFs in the literature. We investigate here how ea...

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Subject

Metal-organic framework

Carboxylate

Adsorption

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