Synthesis of Well-Defined <i>N</i>-Heterocyclic Carbene Silver(I) Complexes

de Frémont, Pierre; Scott, Natalie; D. Stevens, Edwin; Ramnial, Taramatee; Lightbody, O.C.; L. B. Macdonald, Charles; A. C. Clyburne, Jason; Abernethy, C.D.; P. Nolan, Steven

doi:10.1021/om050735i

Public

Synthesis of Well-Defined <i>N</i>-Heterocyclic Carbene Silver(I) Complexes

Published in Organometallics • Nov 18, 2005

Authors:

Pierre de Frémont

Natalie Scott

Edwin D. Stevens

Abstract

A series of N-heterocyclic carbene (NHC)AgCl complexes [NHC = SIMes (1), IPr (2), SIPr (3), IPrMe (4), IMe (5), ICy (6), IAd (7), IsB (8), IDD (9), and TPh (10)] have been synthesized through reaction of the imidazolium chloride salts with Ag2O or by direct metalation of the corresponding imidazol-2...

View

Paywalled

Subject

Carbene

Chemistry

IMes

Generate AI Take for this paper

Highlights, strengths & weaknesses, commercial applications, and societal impact — written for this paper on demand.

Subject

Generate AI Take for this paper

Discussions