Expanding the Ligand Framework Diversity of Carbodicarbenes and Direct Detection of Boron Activation in the Methylation of Amines with CO2.

WC, Chen; JS, Shen; T, Jurca; CJ, Peng; YH, Lin; YP, Wang; WC, Shih; GP, Yap; TG, Ong

doi:10.1002/anie.201507921

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Expanding the Ligand Framework Diversity of Carbodicarbenes and Direct Detection of Boron Activation in the Methylation of Amines with CO2.

Shared by NobleBlocks on Oct 22, 2015 • 12:00 AM UTC

Authors:

Chen WC

Shen JS

Jurca T

Abstract

A simple and convergent synthetic strategy used to increase the diversity of the carbodicarbene ligand framework through incorporation of unsymmetrical pendant groups is reported. Structural analysis and spectroscopic studies of ligands and their Rh complexes are reported. Reactivity studies reveal ...

Subject

Organocatalysis

Ligand Design

Carbene Ligands

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