聚合填充法制备铁/二氧化硅/聚乙烯复合颗粒
Published in Cailiao yanjiu xuebao • Apr 22, 2015
Authors:,,
顾玉彬
Yong Yang
黄正梁
Abstract
以用溶胶凝胶法制备的Fe/Si O2复合颗粒作为载体负载二氯二茂锆(Cp2Zr Cl2),用聚合填充法催化乙烯聚合制备了Fe/Si O2/PE复合颗粒。用扫描电镜、X射线能谱分析、红外光谱、电感耦合等离子体光谱仪、热重分析仪和激光粒度分析仪、凝胶渗透色谱等手段对复合颗粒进行了分析和表征。结果表明,Fe/Si O2复合颗粒外层Si O2包覆完整,可用作Cp2Zr Cl2的载体;Fe/Si O2/Cp2Zr Cl2催化剂体系在乙烯聚合过程中显示出较高的活性,可聚合得到Fe/Si O2/PE复合颗粒;催化活性组分在聚合过程中不会从Fe/Si O2复合颗粒上脱离,生成的聚乙烯在载体表面包覆良好;Fe/...
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