α-雙亞胺及苯甲酸為架構之鈷、鎳、銅、鋅金屬液晶

Metal complexes of general formula M-3Cn based upon substituted 3,4,5-trialkoxybenzoate (3Cn, n=16, 14, 12, 10) and with Co, Ni, Cu and Zn have been prepared. Reaction of M-3Cn with α-diimine derivatives (L=3,6-PPA, 2,5-PPZ, 2,3-PPZ) leads to the dinuclear heterolytic complexes M-L-3Cn. 1H-NMR, EA, ... View More