Tandem Dehydrogenation of Ammonia Borane and Hydrogenation of Nitro/Nitrile Compounds Catalyzed by Graphene-Supported NiPd Alloy Nanoparticles

Göksu, Haydar; Fae Ho, Sally; Metin, Önder; Korkmaz, Katip; Mendoza‐Garcia, Adriana; S. Gültekin, M.; Sun, Shouheng

doi:10.1021/cs500167k

Public

Tandem Dehydrogenation of Ammonia Borane and Hydrogenation of Nitro/Nitrile Compounds Catalyzed by Graphene-Supported NiPd Alloy Nanoparticles

Shared by NobleBlocks on Apr 23, 2014 • 12:00 AM UTC

Authors:

Haydar Göksu

Sally Fae Ho

Önder Metin

Abstract

We report a facile synthesis of monodisperse NiPd alloy nanoparticles (NPs) and their assembly on graphene (G) to catalyze the tandem dehydrogenation of ammonia borane (AB) and hydrogenation of R-NO2 and/or R-CN to R-NH2 in aqueous methanol solutions at room temperature. The 3.4 nm NiPd alloy NPs we...

Subject

Ammonia borane

Dehydrogenation

Oleylamine

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