Introduction of functionality, selection of topology, and enhancement of gas adsorption in multivariate metal-organic framework-177.

YB, Zhang; H, Furukawa; N, Ko; W, Nie; HJ, Park; S, Okajima; KE, Cordova; H, Deng; J, Kim; OM, Yaghi

doi:10.1021/ja512311a

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Introduction of functionality, selection of topology, and enhancement of gas adsorption in multivariate metal-organic framework-177.

Shared by NobleBlocks on Feb 17, 2015 • 12:00 AM UTC

Authors:

Zhang YB

Furukawa H

Ko N

Abstract

Metal-organic framework-177 (MOF-177) is one of the most porous materials whose structure is composed of octahedral Zn4O(-COO)6 and triangular 1,3,5-benzenetribenzoate (BTB) units to make a three-dimensional extended network based on the qom topology. This topology violates a long-standing thesis wh...

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