Role of Keto Intermediates in the Hydrodeoxygenation of Phenol over Pd on Oxophilic Supports

M. de Souza, Priscilla; C. Rabelo‐Neto, Raimundo; Eduardo Pizarro Borges, Luiz; Jacobs, Gary; H. Davis, Burtron; Sooknoi, Tawan; E. Resasco, Daniel; B. Noronha, Fábio

doi:10.1021/cs501853t

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Role of Keto Intermediates in the Hydrodeoxygenation of Phenol over Pd on Oxophilic Supports

Shared by NobleBlocks on Jan 15, 2015 • 12:00 AM UTC

Authors:

Priscilla M. de Souza

Raimundo C. Rabelo‐Neto

Luiz Eduardo Pizarro Borges

Abstract

The performance of Pd catalysts supported on SiO2, Al2O3 and ZrO2 for the hydrodeoxygenation (HDO) of phenol has been compared in the gas phase, at 300 °C and 1 atm using a fixed bed reactor. While Pd supported on SiO2 and Al2O3 exhibits high selectivity to cyclohexanone, when supported on an oxophi...

Subject

Cyclohexanol

Hydrodeoxygenation

Cyclohexanone

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