Polyoxometalate-based cobalt-phosphate molecular catalysts for visible light-driven water oxidation.

Han, Xin-Bao; Zhang, Zhi-Ming; Zhang, Teng; Li, Yang-Guang; Lin, Wenbin; You, Wansheng; Su, Zhong-Min; Wang, En-Bo

doi:10.1021/ja412886e

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Polyoxometalate-based cobalt-phosphate molecular catalysts for visible light-driven water oxidation.

Shared by NobleBlocks on Apr 9, 2014 • 12:00 AM UTC

Authors:

Xin-Bao Han

Zhi-Ming Zhang

Teng Zhang

Abstract

A series of all-inorganic, abundant-metal-based, high-nuclearity cobalt-phosphate (Co-Pi) molecular catalysts [{Co4(OH)3(PO4)}4(SiW9O34)4](32-) (1), [{Co4(OH)3(PO4)}4(GeW9O34)4](32-) (2), [{Co4(OH)3(PO4)}4(PW9O34)4](28-) (3), and [{Co4(OH)3(PO4)}4(AsW9O34)4](28-) (4) were synthesized and shown to be...

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