A photoredox-mediated Minisci C-H alkylation reaction of <i>N</i>-heteroarenes with alkyl boronic acids is reported. A broad range of primary and secondary alkyl groups can be efficiently incorporated into various <i>N</i>-heteroarenes using [Ru(bpy)<sub>3</sub>]Cl<sub>2</sub> as photocatalyst and a...
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