All‐solid‐state Li‐ion batteries based on Li 7 La 3 Zr 2 O 12 (LLZO) garnet structures require novel electrode assembly strategies to guarantee a proper Li + transfer at the electrode–electrolyte interfaces. Here, first stable cell performances are reported for Li‐garnet, c‐Li 6.25 Al 0.25 La 3 Zr 2...
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