Silver-Catalyzed Decarboxylative Radical Azidation of Aliphatic Carboxylic Acids in Aqueous Solution.

C, Liu; X, Wang; Z, Li; L, Cui; C, Li

doi:10.1021/jacs.5b06821

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Silver-Catalyzed Decarboxylative Radical Azidation of Aliphatic Carboxylic Acids in Aqueous Solution.

Shared by NobleBlocks on Jul 30, 2015 • 12:00 AM UTC

Authors:

Liu C

Wang X

Li Z

Abstract

We report herein an efficient and general method for the decarboxylative azidation of aliphatic carboxylic acids. Thus, with AgNO3 as the catalyst and K2S2O8 as the oxidant, the reactions of various aliphatic carboxylic acids with tosyl azide or pyridine-3-sulfonyl azide in aqueous CH3CN solution af...

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