Intricacies of Cation–Anion Combinations in Imidazolium Salt-Catalyzed Cycloaddition of CO<sub>2</sub> Into Epoxides

D. Bobbink, Félix; Vasilyev, Dmitry; Hulla, Martin; M. A. Chamam, Sami; Menoud, Florent; Laurenczy, Gábor; A. Katsyuba, Sergey; J. Dyson, Paul

doi:10.1021/acscatal.7b04389

Public

Intricacies of Cation–Anion Combinations in Imidazolium Salt-Catalyzed Cycloaddition of CO2 Into Epoxides

Published in ACS Catalysis • Feb 12, 2018

Authors:

Félix D. Bobbink

Dmitry Vasilyev

Martin Hulla

Abstract

The cycloaddition of CO2 into epoxides catalyzed by imidazolium and related salts continues to attract attention due to the industrial importance of the cyclic carbonate products. The mechanism of the imidazolium-catalyzed transformation has been proposed to require the participation of the acidic C...

Subject

Chemistry

Cycloaddition

Catalysis

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