Oxygen Vacancy Promoting Dimethyl Carbonate Synthesis from CO2 and Methanol over Zr-Doped CeO2 Nanorods

Liu, Bin; Li, Congming; Zhang, Guoqiang; Yao, Xuesi; S. C. Chuang, Steven; Li, Zhong

doi:10.1021/acscatal.8b00415

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Oxygen Vacancy Promoting Dimethyl Carbonate Synthesis from CO2 and Methanol over Zr-Doped CeO2 Nanorods

Published in ACS Catalysis • Oct 1, 2018

Authors:

Bin Liu

Congming Li

Guoqiang Zhang

Abstract

The synthesis of dimethyl carbonate (DMC) from CO2 and methanol by Zr-doped CeO2 nanorods with different ratios of Zr/Ce has been studied at 6.8 MPa and 140 °C. The catalysts were characterized extensively by TEM, XRD, N2 adsorption, Raman spectroscopy, UV–vis spectroscopy, XPS, CO2-TPD, and in situ...

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Nanorod

Raman spectroscopy

Catalysis

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Oxygen Vacancy Promoting Dimethyl Carbonate Synthesis from CO<sub>2</sub> and Methanol over Zr-Doped CeO<sub>2</sub> Nanorods

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