光反応性をもつ複核有機金属錯体
Published in Kyushu University Institutional Repository (QIR) (Kyushu University) • Dec 15, 1997
NobleIDNI3P58W68R38S12
Authors:,,
英夫 永島
Hideo Nagashima
ヒデオ ナガシマ
Abstract
Thermal or photochemical isomerization of dinuclear carbonyl species bound to conjugate π-systems is presented Typically, irradiation of a diiron carbonyl complex, (μ_2:η^3:η^5-acenaphthylene)Fe_2(CO)_5 (3), induced the haptotropic rearrangement to give the isomer 4. The product reverted to 3 by pro...
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